73 research outputs found
Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts
Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO2) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg2+, Mn2+, Co2+, Ni2+, Zn2+) and Cu2+/Cu+ with increasing fO2 between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO2 implies a reciprocal relationship between a(Fe2+O) and a(Fe3+O1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO2 in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO2 in silicic, but less so in mafic bulk systems.Open Access This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
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Pervasive melt percolation reactions in ultra-depleted refractory harzburgites at the Mid-Atlantic Ridge, 15° 20′N : ODP Hole 1274A
Author Posting. © The Authors, 2006. This is the author's version of the work. It is posted here by permission of Springer for personal use, not for redistribution. The definitive version was published in Contributions to Mineralogy and Petrology 153 (2007): 303-319, doi:10.1007/s00410-006-0148-6.ODP Leg 209 Site 1274 mantle peridotites are highly refractory in terms of lack of residual
clinopyroxene, olivine Mg# (up to 0.92) and spinel Cr# (~0.5), suggesting high degree of partial
melting (>20%). Detailed studies of their microstructures show that they have extensively
reacted with a pervading intergranular melt prior to cooling in the lithosphere, leading to
crystallization of olivine, clinopyroxene and spinel at the expense of orthopyroxene. The least
reacted harzburgites are too rich in orthopyroxene to be simple residues of low-pressure (spinel
field) partial melting. Cu-rich sulfides that precipitated with the clinopyroxenes indicate that
the intergranular melt was generated by no more than 12% melting of a MORB mantle or by
more extensive melting of a clinopyroxene-rich lithology. Rare olivine-rich lherzolitic domains,
characterized by relics of coarse clinopyroxenes intergrown with magmatic sulfides, support
the second interpretation. Further, coarse and intergranular clinopyroxenes are highly depleted
in REE, Zr and Ti. A two-stage partial melting/melt-rock reaction history is proposed, in which
initial mantle underwent depletion and refertilization after an earlier high pressure (garnet field)
melting event before upwelling and remelting beneath the present-day ridge. The ultra-depleted
compositions were acquired through melt re-equilibration with residual harzburgites.Funding for this
research was provided by Centre National de la Recherche Scientifique-Institut National des
Sciences de l’Univers (Programme Dynamique et Evolution de la Terre Interne)
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