Density minimum and liquid-liquid phase transition

We present a high-resolution computer simulation study of the equation of state of ST2 water, evaluating the liquid-state properties at 2718 state points, and precisely locating the liquid-liquid critical point (LLCP) occurring in this model. We are thereby able to reveal the interconnected set of density anomalies, spinodal instabilities and response function extrema that occur in the vicinity of a LLCP for the case of a realistic, off-lattice model of a liquid with local tetrahedral order. In particular, we unambiguously identify a density minimum in the liquid state, define its relationship to other anomalies, and show that it arises due to the approach of the liquid structure to a defect-free random tetrahedral network of hydrogen bonds.Comment: 5 pages, 4 figure

Ice XII in its second regime of metastability

We present neutron powder diffraction results which give unambiguous evidence for the formation of the recently identified new crystalline ice phase[Lobban et al.,Nature, 391, 268, (1998)], labeled ice XII, at completely different conditions. Ice XII is produced here by compressing hexagonal ice I_h at T = 77, 100, 140 and 160 K up to 1.8 GPa. It can be maintained at ambient pressure in the temperature range 1.5 < T < 135 K. High resolution diffraction is carried out at T = 1.5 K and ambient pressure on ice XII and accurate structural properties are obtained from Rietveld refinement. At T = 140 and 160 K additionally ice III/IX is formed. The increasing amount of ice III/IX with increasing temperature gives an upper limit of T ~ 150 K for the successful formation of ice XII with the presented procedure.Comment: 3 Pages of RevTeX, 3 tables, 3 figures (submitted to Physical Review Letters

Instability of Myelin Tubes under Dehydration: deswelling of layered cylindrical structures

We report experimental observations of an undulational instability of myelin figures. Motivated by this, we examine theoretically the deformation and possible instability of concentric, cylindrical, multi-lamellar membrane structures. Under conditions of osmotic stress (swelling or dehydration), we find a stable, deformed state in which the layer deformation is given by \delta R ~ r^{\sqrt{B_A/(hB)}}, where B_A is the area compression modulus, B is the inter-layer compression modulus, and h is the repeat distance of layers. Also, above a finite threshold of dehydration (or osmotic stress), we find that the system becomes unstable to undulations, first with a characteristic wavelength of order \sqrt{xi d_0}, where xi is the standard smectic penetration depth and d_0 is the thickness of dehydrated region.Comment: 5 pages + 3 figures [revtex 4

Liquid-liquid equilibrium for monodisperse spherical particles

A system of identical particles interacting through an isotropic potential that allows for two preferred interparticle distances is numerically studied. When the parameters of the interaction potential are adequately chosen, the system exhibits coexistence between two different liquid phases (in addition to the usual liquid-gas coexistence). It is shown that this coexistence can occur at equilibrium, namely, in the region where the liquid is thermodynamically stable.Comment: 6 pages, 8 figures. Published versio

Pressure-induced amorphization and polyamorphism in one-dimensional single crystal TiO2 nanomaterials

The structural phase transitions of single crystal TiO2-B nanoribbons were investigated in-situ at high-pressure using the synchrotron X-ray diffraction and the Raman scattering. Our results have shown a pressure-induced amorphization (PIA) occurred in TiO2-B nanoribbons upon compression, resulting in a high density amorphous (HDA) form related to the baddeleyite structure. Upon decompression, the HDA form transforms to a low density amorphous (LDA) form while the samples still maintain their pristine nanoribbon shape. HRTEM imaging reveals that the LDA phase has an {\alpha}-PbO2 structure with short range order. We propose a homogeneous nucleation mechanism to explain the pressure-induced amorphous phase transitions in the TiO2-B nanoribbons. Our study demonstrates for the first time that PIA and polyamorphism occurred in the one-dimensional (1D) TiO2 nanomaterials and provides a new method for preparing 1D amorphous nanomaterials from crystalline nanomaterials.Comment: 4 figure

Charging axisymmetric space-times with cosmological constant

Ernst's solution generating technique for adding electromagnetic charge to axisymmetric space-times in general relativity is generalised in presence of the cosmological constant. Ernst equations for complex potentials are found and they are traced back to an affective dual complex dynamical system, whose symmetries are studied. In particular this method is able to generate charged, asymptotically (A)dS black holes from their uncharged version: as an example, it is shown explicitly how to pass from the Kerr-(A)dS to the Kerr-Newman-(A)dS metric. A new solution describing a magnetic universe in presence of the cosmological constant is also generated.Comment: 15 pages, v2: typos correcte

Physics of the liquid-liquid critical point

Within the inherent structure (IS) thermodynamic formalism introduced by Stillinger and Weber [F. H. Stillinger and T. A. Weber, Phys. Rev. A {\bf 25}, 978 (1982)] we address the basic question of the physics of the liquid-liquid transition and of density maxima observed in some complex liquids such as water by identifying, for the first time, the statistical properties of the potential energy landscape (PEL) responsible for these anomalies. We also provide evidence of the connection between density anomalies and the liquid-liquid critical point. Within the simple (and physically transparent) model discussed, density anomalies do imply the existence of a liquid-liquid transition.Comment: Physical Review Letters, in publicatio

Ernst equation and spheroidal coordinates with a cosmological constant term

We discuss solution generating techniques treating stationary and axially symmetric metrics in the presence of a cosmological constant. Using the recently found extended form of Ernst's complex equation, which takes into account the cosmological constant term, we propose an extension of spheroidal coordinates adapted to asymptotically de-Sitter and anti de-Sitter static spacetimes. In the absence of a cosmological constant we show in addition that any higher dimensional metric parametrised by a single angular momentum can be given by a 4 dimensional solution and Weyl potentials parametrising the extra Killing directions. We explicitly show how a stationary, and a static axially symmetric spacetime solution in 4 dimensions, can be {\it added} together to give a 5 dimensional stationary and axisymmetric solution.Comment: 9 pages, no figures, some additional results to gr-qc/0610091. Prepared for 12th Conference on Recent Developments in Gravity (NEB XII), Nafplio, Greece, 29 Jun - 2 Jul 200

Chargino Contributions in B→ϕKSB \to \phi K_S Asymmetry

CP asymmetry in $B \to \phi K_S$ decay is studied in a special context of supersymmetry theories, in which the charginos play an important role. We find that in addition to the gluino, chargino can also make large contributions to CP asymmetry in $B \to \phi K_S$ decay. After considering the constraints from $B \to J/psi K_S$ decay, we study three special scenarios: (a). Large mixing on left-handed charm and top squarks (LL mixing); (b). Large mixing on right-handed charm and top squarks (RR mixing); (c). Large mixing on left-handed charm and top squarks plus right-handed charm and top squarks (LL + RR mixing). We show quantitatively that because of large squark mixing within second and third generations, an $\mathcal O$(1) effect on CP violation in $B \to \phi K_S$ is possible