Fabrication of Nb\u3csub\u3e3\u3c/sub\u3eSn by Magnetron Sputtering for Superconducting Radiofrequency Application

Particle accelerators are considered as an important device that has wide applications in cancer treatment, sterilizing waste, preserving foods, ion implantation in semiconductor industry, and in production of isotopes for medical applications. Superconducting radiofrequency (SRF) cavities are the building blocks of a linear particle accelerator. Current particle accelerators use niobium (Nb) superconductors as the sheet material to fabricate a single SRF cavity for particle acceleration. With better superconducting properties (critical temperature Tc ~ 18.3 K, superheating field Hsh~ 400 mT), Nb3Sn is considered a potential candidate in SRF technology. Magnetron sputtering is a promising deposition method to fabricate Nb3Sn thin films inside SRF cavities. Superconducting Nb3Sn films were fabricated on Nb and sapphire substrates by magnetron sputtering from a single stoichiometric Nb3Sn target, by multilayer sputtering of Nb and Sn followed by annealing, and by co-sputtering of Nb and Sn followed by annealing. The variation of morphological and superconducting properties was investigated for different substrate temperatures, annealing temperatures, annealing durations, and thicknesses. The film properties were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), and energy dispersive X-ray spectroscopy (EDS). The films had crystalline Nb3Sn structure without any presence of poor superconducting Nb6Sn5 and NbSn2 phases. The highest Tc of the films fabricated from the stoichiometric target, multilayer sputtering and co-sputtering were 17.44, 17.93, and 17.66 K respectively. Finally, a cylindrical sputter coater with two identical magnetrons was designed and commissioned to fabricate Nb3Sn films inside a 2.6 GHz SRF cavity. The magnetrons were installed facing opposite to each other in a custom designed vacuum chamber and multilayers of Nb and Sn films on 1 cm2 Nb substrates replicating the beam tubes and equator locations of the cavity and the coated multilayered films were annealed at 950 °C for 3 h. The XRD of the as deposited and annealed films confirmed the formation of Nb3Sn after the annealing. The dissertation discusses the fabrication process, characterized results of the fabricated films, the design of the cylindrical sputter coater and the preliminary data obtained from the sputter coater

Design of ballasted railway track foundations using numerical modelling with special reference to high speed trains

A new design method for ballasted railway track foundations was developed based on improved empirical models and sophisticated three-dimensional finite element numerical analyses. The method was developed in the form of simple design charts for use by practitioners. The results obtained from the method were found to be in an excellent agreement with the field observations, and the method is expected to provide a significant contribution to the current railway tack design code of practice

Lubrication Performance of Vegetable Oils Modified with Halloysite Clay Nanotubes (HNT) as Lubricant Additives

Vegetable oil-based nano-lubricants are a great alternative to petroleum-based lubricants because of their less adverse impact on the environment. This work evaluates the tribological performance of sunflower, corn, and peanut oils modified with halloysite clay nanotubes (Al2Si2O2(OH)2nH2O) as lubricant additives at different concentrations. To analyze the tribological performance of the nano-lubricants, a block-on-ring tribometer was used following the ASTM G-077-17 standard procedure. Characterization of HNT was carried out by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), and Thermogravimetric Analysis (TGA). The effect of the HNT on the lubrication performance of the newly developed vegetable oil-based nano-lubricants was evaluated, and the experimental data of wear, friction, and temperature was analyzed. The results concluded that sunflower, peanut, and corn oils modified with Halloysite Clay Nanotubes could be a great alternative to mineral and synthetic lubricants

ACTIVATION SCAVENGING OF AEROSOL : EFFECT OF TURBULENCE AND AEROSOL-COMPOSITION

The interaction of aerosol particles with solar radiation significantly contributes to the global radiation balance. The magnitude of this aerosol-radiation interaction, among other parameters, depends on different aerosol properties, including how readily these particles would act as cloud condensation nuclei (CCN). These properties are governed by the formation and scavenging processes of aerosol. This dissertation explores some of these scavenging processes. Favorable humidity and preexisting aerosol particles acting as CCN are the sine qua non conditions to form cloud droplets in Earth’s atmosphere. Forming cloud droplets (known as activation), meanwhile, acts as a wet scavenging mechanism for those CCN. Given the required humidity, size, and chemical composition of an aerosol particle, determine its probability to activate. Through targeted experiments in a cloudy, turbulent environment in Michigan Tech’s Π chamber, we show that turbulent fluctuation blurs correspondence between activation and a particle’s size and chemical composition. We also show that turbulence enhances the activation efficiency and can mimic the effect of heterogeneity in the size and chemical composition of the aerosol particles. In the absence of clouds, we discuss how turbulence affects the dry scavenging of aerosol particles. Finally, we propose an operational protocol to improve the temporal resolution of an instrument that counts the number of CCN present in an environment as a function of supersaturation (i.e., relative humidity \u3e 100%

A mechanistic approach For predicting the effect of various factors on partitioning between free and bound chlorides in concrete

The chloride-induced corrosion of reinforcing steel in concrete structures has become a widespread durability problem throughout the world. When concrete structures come in contact with chloride sources, the chloride ions will diffuse through the body of the concrete and ultimately reach the steel. Not all of the chloride ions which penetrate the concrete remain free in the pore solution. Some of the ions become bound to the hydration products in a chemical reaction to form calcium chloroaluminate hydrate (Friedel' salt). It is also well known that only the portion of the chloride ions that remains free is responsible for causing damage to the concrete structures by corroding steel rebar. Thus, the chloride binding capacity of the cementitious matrix plays a major role in controlling chlorides ingress and, consequently, the corrosion of steel reinforcement in concrete. The chloride binding capacity is affected by cement composition, environmental factors, and by the source of the chlorides ( vs. ). To quantify the durability of new and existing structures, a clear understanding of the mechanisms of chloride penetration into the concrete cover is required. Currently, most of the models available in the published literature for calculating free chloride ions in concrete use Fick’s law for chloride transport and chloride binding isotherms to account for bound chlorides. Binding isotherms are cement and environment specific. Thus, the existing models cannot be used for all types of cement and variable general environmental exposure conditions such as temperatures, pH levels, and chloride sources. A general mechanistic approach that can overcome those limitations is proposed in this thesis based on the concepts of ion-exchange theory for an accurate determination of chloride ingress in concrete under variable environmental conditions. Some of the model input parameters, such as exchange capacity and the equilibrium constant for the exchange reaction, were not easy to determine directly from experiments and were determined through an inverse modeling procedure. Verification experiments were carried out by varying different environmental parameters and making comparisons with the simulated results using the corresponding parameters. The experimental results showed that the proposed procedure is able to predict the amount of free chlorides in concrete, including predictions of chloride binding as a function of pH, temperature, chloride sources, and the presence of other ions such as carbonate. The proposed model was also used to clarify some unresolved issues such as the effect of chloride sources on binding and the effect of pH on the release of bound chlorides in the presence of carbonation

Coccygectomy can be a option for coccydynia which is refractory to medical treatment

The aim of this study was to evaluate the clinical outcome of coccygectomy those who were refractory to conservative treatment. Twenty patients (5 males, 15 females) underwent total coccygectomy when coccygodynia did not responding to medical treatment July 2013 to September 2018. All the patients timely attended with non-traumatic (n = 12) and traumatic (n = 8) cause with mean follow-up visits of 24 months (range 18-28 months). The outcome pain intensity was evaluated by visual analogue scale (VAS) in sitting position and during daily activities. Three patients had infection which improved after antibiotic therapy. The VAS improved from 6.4 ± 0.9 to 2.1 ± 0.9 for sitting and from 5.8 ± 0.9 to 1.6 ± 0.6 for daily activities. Improvement in pain and daily activities were significant at the final follow-up. Ninety percent patients were satisfied with the operation

Desynchrony induced by higher-order interactions in triplex metapopulations

In a predator-prey metapopulation, the two traits are adversely related: synchronization and persistence. A decrease in synchrony apparently leads to an increase in persistence and, therefore, necessitates the study of desynchrony in a metapopulation. In this article, we study predator-prey patches that communicate with one another while being interconnected through distinct dispersal structures in the layers of a three-layer multiplex network. We investigate the synchronization phenomenon among the patches of the outer layers by introducing higher-order interactions (specifically three-body interactions) in the middle layer. We observe a decrease in the synchronous behavior or, alternatively, an increase in desynchrony due to the inclusion of group interactions among the patches of the middle layer. The advancement of desynchrony becomes more prominent with increasing strength and numbers of three-way interactions in the middle layer. We analytically validated our numerical results by performing the stability analysis of the referred synchronous solution using the master stability function approach. Additionally, we verify our findings by taking into account two distinct predator-prey models and dispersal topologies, which ultimately assert that the findings are generalizable across various models and dispersal structures.Comment: 12 Pages, 10 figures. Accepted for publication in Physical Review E, 202