Application of different growth models to "Nero di Parma" pigs

The growth curves of 280 "Nero di Parma" pigs from birth to maturity were calculated by applying nine different models (regressions from 1st to 4th degree and nonlinear regressions following the Brody, Logistic, Janoschek, Bertalannfy and Gompertz models) to 1109 individual records of body weight (BW) from two different data sets. The goodness of fit of experimental data was calculated by means of Residual Variance, Akaike Information Criterion, Residual Standard Deviation and R2. The best fit was obtained by Gompertz equation, as follows: BW(kg)= 240.2±2.4 * esp (-exp (-0.0069±0.0001*(age(d)–213.5±3.1))). Regardless to the model, all correlations between actual and estimated BW were highly significant (P<0.001): the highest correlation (0.980) was obtained by the application of the Gompertz equation. In conclusion the growth of "Nero di Parma" pigs can be well described by applying the Gompertz model to field data

Effect of sex and season of birth on Gompertz growth curve parameters in "Nero di Parma" pigs

The growth curves of “Nero di Parma” pigs were studied by applying the Gompertz equation to 1069 body weight (BW) records from 285 pigs (156 females, 129 castrated males) born in 11 outdoor and 5 indoor herds; pigs were fed commercial complete feeds offered ad libitum and, on a limited basis in the outdoor system, diets were integrated with pasture. The parameters of the Gompertz equation were compared with reference to sex and season of birth. Mature BW for castrated males (229.0 kg) was 3.5% greater than that for females (221.3 kg) (P180 kg)

The interplay of chemical structure, physical properties, and structural design as a tool to modulate the properties of melanins within mesopores

The design of modern devices that can fulfil the requirements for sustainability and renewable energy applications calls for both new materials and a better understanding of the mixing of existing materials. Among those, surely organic–inorganic hybrids are gaining increasing attention due to the wide possibility to tailor their properties by accurate structural design and materials choice. In this work, we’ll describe the tight interplay between porous Si and two melanic polymers permeating the pores. Melanins are a class of biopolymers, known to cause pigmentation in many living species, that shows very interesting potential applications in a wide variety of fields. Given the complexity of the polymerization process beyond the formation and structure, the full understanding of the melanins’ properties remains a challenging task. In this study, the use of a melanin/porous Si hybrid as a tool to characterize the polymer’s properties within mesopores gives new insights into the conduction mechanisms of melanins. We demonstrate the dramatic effect induced on these mechanisms in a confined environment by the presence of a thick interface. In previous studies, we already showed that the interactions at the interface between porous Si and eumelanin play a key role in determining the final properties of composite materials. Here, thanks to a careful monitoring of the photoconductivity properties of porous Si filled with melanins obtained by ammonia-induced solid-state polymerization (AISSP) of 5,6-dihydroxyindole (DHI) or 1,8-dihydroxynaphthalene (DHN), we investigate the effect of wet, dry, and vacuum cycles of storage from the freshly prepared samples to months-old samples. A computational study on the mobility of water molecules within a melanin polymer is also presented to complete the understanding of the experimental data. Our results demonstrate that: (a) the hydration-dependent behavior of melanins is recovered in large pores (≈ 60 nm diameter) while is almost absent in thinner pores (≈ 20 nm diameter); (b) DHN-melanin materials can generate higher photocurrents and proved to be stable for several weeks and more sensitive to the wet/dry variations

Anomalous evolution of broadband optical absorption reveals dynamic solid state reorganization during eumelanin build-up in thin films

The origin of eumelanin optical properties remains a formidable conundrum preventing a detailed understanding of the complex photo-protective role of these widespread natural pigments and the rational design of innovative bioinspired materials for optoelectronic applications. Here we report the unusual kinetic and thickness-dependent evolution of the optical properties of black eumelanin polymers generated by spontaneous aerial polymerization of 5,6-dihydroxyindole (DHI) thin films (0.1-1 μm), consistent with peculiar solid state reorganization mechanisms governing broadband absorption. The complete reversal of eumelanin UV-visible transmittance spectrum curvature on passing from 0.2 to 0.5 μm thick films, the marked increase in visible extinction coefficients with increasing film thickness and the higher UV extinction coefficients in slowly vs. rapidly generated polymers concur to support distinct dynamic regimes of solid-state molecular reorganization at the nanoscale level and to do affect the development of broadband visible absorption. Solid state control of molecular reorganization disclosed herein may delineate new rational strategies for tuning optical properties in eumelanin thin films for optoelectronic applications

Valorisation of municipal and tannery sludge via hydrothermal liquefaction: Effect of the substrate chemical composition on yield and quality of bio-crude

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La chimica delle deposizioni atmosferiche e gli inquinanti atmosferici nelle aree del programma CONECOFOR nell\u27anno 2012

Atmospheric deposition was sampled in 13 forest sites in Italy, in the open field, under tree canopy and on stemflow, and analyzed for major ions, dissolved organic carbon and total nitrogen. Ozone concentration was also measured during spring and summer. The results were compared with time series dating back to 1997