The type N Karlhede bound is sharp

We present a family of four-dimensional Lorentzian manifolds whose invariant classification requires the seventh covariant derivative of the curvature tensor. The spacetimes in questions are null radiation, type N solutions on an anti-de Sitter background. The large order of the bound is due to the fact that these spacetimes are properly $CH_2$, i.e., curvature homogeneous of order 2 but non-homogeneous. This means that tetrad components of $R, \nabla R, \nabla^{(2)}R$ are constant, and that essential coordinates first appear as components of $\nabla^{(3)}R$. Covariant derivatives of orders 4,5,6 yield one additional invariant each, and $\nabla^{(7)}R$ is needed for invariant classification. Thus, our class proves that the bound of 7 on the order of the covariant derivative, first established by Karlhede, is sharp. Our finding corrects an outstanding assertion that invariant classification of four-dimensional Lorentzian manifolds requires at most $\nabla^{(6)}R$.Comment: 7 pages, typos corrected, added citation and acknowledgemen

Electrons in Dry DNA from Density Functional Calculations

The electronic structure of an infinite poly-guanine - poly-cytosine DNA molecule in its dry A-helix structure is studied by means of density-functional calculations. An extensive study of 30 nucleic base pairs is performed to validate the method. The electronic energy bands of DNA close to the Fermi level are then analyzed in order to clarify the electron transport properties in this particularly simple DNA realization, probably the best suited candidate for conduction. The energy scale found for the relevant band widths, as compared with the energy fluctuations of vibrational or genetic-sequence origin, makes highly implausible the coherent transport of electrons in this system. The possibility of diffusive transport with sub-nanometer mean free paths is, however, still open. Information for model Hamiltonians for conduction is provided.Comment: 8 pages, 4 figure