Modelling the kinetics of thermal inactivation of apple polyphenoloxidase

The enzymatic browning of fruits and vegetables caused by mechanical injury during postharvest storage or processing is initiated by the catalytic action of polyphenoloxidase (PPO). A bleaching treatment prior to processing is still considered mostly effective in inhibiting the catalytic activity of PPO, and thus controlling undesirable enzymatic browning. In this work, different mathematical routines were assessed in terms of their adequacy to describe the thermal inactivation of PPO from Golden apples over a range of temperatures from 62.5 to 72.5 ºC. The classical approach to kinetic modelling of the decay activity of apple PPO, commonly reported to follow a first-order model, employs a two-step procedure, in which the model parameters are individually obtained, by each temperature studied, using non-linear or linear regressions. Thereafter, the estimated parameters are further used to calculate their temperature dependence. Alternatively, a one-step method provides a regression fit to all experimental data sets, with the temperature dependence equation being directly built in the kinetic model. This fitting technique thus, (a) avoids the estimation of intermediate parameters and, (b) substantially increases the degrees of freedom and hence the precision of parameters’ estimates. Within this issue was further explored the logarithmic transformation of the mathematical equations used on the adequacy of the model to describe experimental data. In all cases non-weighted least-squares regression procedures were used. Both the examination and criticism of the current modelling strategies were done by assessing statistical data obtained, such as the confidence intervals of the estimates, correlation coefficients, sum of squares, and residuals normality

Quantum signatures in quadratic optomechanics

We analyze quantum effects occurring in optomechanical systems where the coupling between an optical mode and a mechanical mode is quadratic in displacement (membrane-in-the-middle geometry). We show that it is possible to observe quantum effects in these systems without achieving the single-photon strong coupling regime. We find that zero-point energy causes a mechanical frequency shift, and we propose an experimental way to measure it. Further, we show that it is possible to determine the phonon statistics from the cavity transmission, and propose a way to infer the resonator's temperature based on this feature. For completeness, we revisit the case of an isolated system and show that different types of mechanical quantum states can be created, depending on the initial cavity state. In this situation, mechanical motion undergoes collapse and revivals, and we compute the collapse and revival times, as well as the degree of squeezing.Comment: 7 pages, 6 figures, 2nd versio

Photoproduction of ρ0\rho^0 mesons in ultraperipheral heavy ion collisions at energies available at the BNL Relativistic Heavy Ion Collider (RHIC) and CERN Large Hadron Collider (LHC)

We investigate the photoproduction of $\rho$ mesons in ultraperipheral heavy ion collisions at RHIC and LHC energies in the dipole approach and within two phenomenological models based on the the Color Glass Condensate (CGC) formalism. We estimate the integrated cross section and rapidity distribution for meson production and compare our predictions with the data from the STAR collaboration. In particular, we demonstrate that the total cross section at RHIC is strongly dependent on the energy behavior of the dipole-target cross section at low energies, which is not well determined in the dipole approach. In contrast, the predictions at midrapidities at RHIC and in the full rapidity at LHC are under theoretical control and can be used to test the QCD dynamics at high energies.Comment: 6 pages, 5 figures, 1 table. Improved version to be published in Physical Review

Surface-state electron dynamics in noble metals

Theoretical investigations of surface-state electron dynamics in noble metals are reported. The dynamically screened interaction is computed, within many-body theory, by going beyond a free-electron description of the metal surface. Calculations of the inelastic linewidth of Shockley surface-state electrons and holes in these materials are also presented. While the linewidth of excited holes at the surface-state band edge (${\bf k}_\parallel=0$) is dominated by a two-dimensional decay channel, within the surface-state band itself, our calculations indicate that major contributions to the electron-electron interaction of surface-state electrons above the Fermi level come from the underlying bulk electrons.Comment: 17 pages, 7 figures, to appear in Prog. Surf. Sc

Quantiles for Counts

This paper studies the estimation of conditional quantiles of counts. Given the discreteness of the data, some smoothness has to be artificially imposed on the problem. The methods currently available to estimate quantiles of count data either assume that the counts result from the discretization of a continuous process, or are based on a smoothed objective function. However, these methods have several drawbacks. We show that it is possible to smooth the data in a way that allows inference to be performed using standard quantile regression techniques. The performance and implementation of the estimator are illustrated by simulations and an application.Asymmetric maximum likelihood, Jittering, Maximum score estimator, Quantile regression, Smoothing.