5 research outputs found

    Theory of High \tc Ferromagnetism in SrB6SrB_6 family: A case of Doped Spin-1 Mott insulator in a Valence Bond Solid Phase

    Full text link
    Doped divalent hexaborides such as Sr1−xLaxB6Sr_{1-x}La_xB_6 exhibit high \tc ferromagnetism. We isolate a degenerate pair of 2p2p-orbitals of boron with two valence electrons, invoke electron correlation and Hund coupling, to suggest that the undoped state is better viewed as a spin-1 Mott insulator; it is predicted to be a type of 3d Haldane gap phase with a spin gap ∼0.1eV\sim 0.1 eV, much smaller than the charge gap of >1.0eV > 1.0 eV seen in ARPES. The experimentally seen high \tc `ferromagnetism' is argued to be a complex magnetic order in disguise - either a canted 6-sublattice AFM (≈1200\approx 120^0) order or its quantum melted version, a chiral spin liquid state, arising from a type of double exchange mechanism.Comment: 4 pages, 2 figures; minor corrections, references adde
    corecore