Plutonium in locations of local sources and its involvement in global circulation

This paper seeks to compare the volumetric activities of the 239+240Pu and 238Pu isotopes in the surface layer of the atmosphere in the locations of different local sources of radioactive contamination, to characterize these sources as applied to the ratio of the 238Pu and 239+240Pu isotopes, and to estimate the global industry-caused background of plutonium isotopes in the surface atmosphere. Under investigation are an NPP location (the city of Kursk), a territory contaminated as the result of the accident at the Chernobyl NPP (the city of Bryansk), the location of a radiochemical site for the radioactive material reprocessing (PA Mayak in the town of Novogorny, Chelyabinsk Oblast), and the city of Obninsk, the location of nuclear research reactors. The dynamics of the volumetric activity in the locations of interest in 1992–2015 has been reviewed, and the most contaminated areas and the areas with the smallest content of Pu isotopes in the atmosphere's surface layer have been identified. Causes have been revealed for variations in the volumetric activity levels by years and seasonally. The sources of radioactive contamination under consideration have been characterized in terms of the 238Pu–239+240Pu ratio, and the possibility for this ratio to be used to identify the release sources has been evaluated. A much smaller degree of the plutonium isotope involvement in global circulation has been shown based on results of a dedicated study into the volumetric activity of plutonium isotopes at observation points in the Russian subpolar and polar areas, the most distant ones from local sources of the atmospheric Pu release. Throughout the considered period, the volumetric activity of plutonium isotopes in all of the locations of interest was not exceeding the permissible volumetric activity in the inhaled air for the population, as specified in Radiation Safety Regulations NRB-99/2009, which is equal to 2.5 × 10–3 Bq/m3

Water-soluble bismuth(III) polynuclear tyrosinehydroximate metallamacrocyclic complex: Structural parallels to lanthanide metallacrowns

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. Recently there has been a great deal of interest and associated research into aspects of the coordination chemistry of lanthanides and bismuth—elements that show intriguing common features. This work focuses on the synthesis and characterization of a novel bismuth(III) polynuclear metallamacrocyclic complex derived from aminohydroxamic acid, in order to compare the coordination ability of Bi3+ with the similarly sized La3+ ions. A polynuclear tyrosinehydroximate Bi(OH)[15-MCCu(II)Tyrha-5](NO3)2 (1) was obtained according to the synthetic routes previously described for water-soluble Ln(III)-Cu(II) 15-MC-5 metallacrowns. Correlations between structural parameters of Bi(III) and Ln(III) complexes were analyzed. DFT calculations confirmed the similarity between molecular structures of the model bismuth(III) and lanthanum(III) tyrosinehydroximate 15-metallacrowns-5. Analysis of the electronic structures revealed, however, stronger donor-acceptor interactions between the central ion and the metallamacrocycle in the case of the lanthanum analogue. Thermochromic properties of 1 were studied