12 research outputs found

    Theoretical study of the influence of the morphology in polymer-based devices functioning

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    It is well known that the morphology of polymer-based optoelectronic devices can influence their efficiency, since the ways that polymer chains pack inside the active layer can influence not only the charge transport but also the optic properties of the device. By using a mesoscopic model we carried out computer experiments to study the influence of the polymer morphology on the processes of charge injection, transport, recombination and collection by the electrodes opposite to those where the injection of bipolar charge carriers take place. Our results show that for polymer layers where the conjugated segments have perpendicular and random orientation relative to the electrodes surface, the competition between charge collection and charge recombination is affected when the average conjugation length of the polymer strands increase. This effect is more pronounced with the increase of the potential barrier at polymer/electrode interfaces that limit charge injection and increase charge collection. For these molecular arrangements the intra-molecular charge transport plays a major role in device performance, being this effect negligible when the polymer molecules have their axis parallel to the electrodes. Although the polymer morphology modelled in this work is far from real, we believe that our model can give some insights on the role of the microstructure on the functioning of polymer-based devices.European Community Fund (FEDER)Fundação para a CiĂȘncia e a Tecnologia (FCT) – Programa Operacional “CiĂȘncia , Tecnologia, Inovação” – POCTI/CTM/41574/2001, CONC-REEQ/443/EEI/2005 e SFRH/BD/22143/200

    Theoretical study of electric field-dependent polaron-type mobility in conjugated polymers

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    We have used a self-consistent quantum molecular dynamics approach to calculate the mobility of both positive and negative polaron-type carriers on solated chains of poly(p-phenylene vinylene) (PPV) and some of its derivatives and the dependence of their mobility on the applied electric field. Our results suggest that polaron-type mobility along most of these polymer chains has a clear dependence on the electric field which is quite different from the result derived for bulk PPV-based materials.Fundação para a CiĂȘncia e a Tecnologia (FCT) Programa Operacional “CiĂȘncia , Tecnologia, Inovação” – POCTI/CTM/41574/2001, CONC-REEQ/443/EEI/2001 e SFRH/BD/11231/200

    Mesoscopic modelling of 2-CN-PPV/PPV polymer LED

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    Although optoelectronic devices made of polymers are very attractive ones (low cost, easy to make), problems related to charge transport, exciton quenching, among others, can be an obstacle for their performance. The use of heterojunctions made of two polymers can be a strategy for improving the efficiency of polymer light emitting diodes (PLEDs) at low bias. Here we present a theoretical study of the influence of bilayer structure in a PLED made of PPV and 2-CN-PPV, by adopting a mesoscopic approach. Our results show that the presence of the polymer/polymer interface improves charge injection and leads to a confinement of charges near it, which will increase the number recombination events in the middle of the device compared to the equivalent single-layer PLEDs.Fundação para a CiĂȘncia e a Tecnologia (FCT) Programa Operacional “CiĂȘncia , Tecnologia, Inovação” POCTI/CTM/41574/2001, CONC-REEQ/443/EEI/2001 e SFRH/BD/22143/200

    Text-driven video acceleration:A weakly-supervised reinforcement learning method

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    The growth of videos in our digital age and the users' limited time raise the demand for processing untrimmed videos to produce shorter versions conveying the same information. Despite the remarkable progress that summarization methods have made, most of them can only select a few frames or skims, creating visual gaps and breaking the video context. This paper presents a novel weakly-supervised methodology based on a reinforcement learning formulation to accelerate instructional videos using text. A novel joint reward function guides our agent to select which frames to remove and reduce the input video to a target length without creating gaps in the final video. We also propose the Extended Visually-guided Document Attention Network (VDAN+), which can generate a highly discriminative embedding space to represent both textual and visual data. Our experiments show that our method achieves the best performance in Precision, Recall, and F1 Score against the baselines while effectively controlling the video's output length. IEE

    First principles study of point defects in titanium oxycarbide

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    We have performed first principles density functional theory calculations to study the formation energy of point defects in TiC, TiO and TiCO compounds. The formation energy of isolated vacancies were obtained for different equilibrium conditions. For binary compounds, we have also calculated the formation energy of antisite defects. It was found that the defect formation energies strongly depend on the chemical environment. Our results show that C vacancies are easily formed in TiC and TiCO. For the TiO compound, Ti vacancies are highly probable to occur and O vacancies are also easily formed under titanium rich atmosphere.Fundação para a CiĂȘncia e a Tecnologia (FCT) – Programa Operacional “CiĂȘncia , Tecnologia, Inovação” – CONC-REEQ/443/EEI/2005, POCTI/CTM/69362/200

    Theory of processes at surfaces and interfaces

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    SIGLEAvailable from British Library Document Supply Centre- DSC:D170747 / BLDSC - British Library Document Supply CentreGBUnited Kingdo

    The mesoscopic modeling of laser ablation

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