Phase behaviour of macromolecular liquid crystlline materials: computational studies at the molecular level

Molecular simulations provide an increasingly useful insight into the static and dynamic characteristics of materials. In this thesis molecular simulations of macro-molecular liquid crystalline materials are reported. The first liquid crystalline material that has been investigated is a side chain liquid crystal polymer (SCLCP). In this study semi-atomistic molecular dynamics simulations have been conducted at a range of temperatures and an aligning potential has been applied to mimic the effect of a magnetic field. In cooling the SCLCP from an isotropic melt, microphase separation was observed yielding a domain structure. The application of a magnetic field to this structure aligns the domains producing a stable smectic mesophase. This is the first study in which mesophases have been observed using an off-lattice model of a SCLCP. The second material that has been investigated is a dendrimer with terminal mesogenic functionalization. Here, a multi-scale approach has been taken with Monte Carlo studies of a single dendrimer molecule in the gas phase at the atomistic level, semi-atomistic molecular dynamics of a single molecule in liquid crystalline solvents and a coarse-grained molecular dynamics study of the dendrimer in the bulk. The coarse-grained model has been developed and parameterized using the results of the atomistic and semi-atomistic work. The single molecule studies showed that the liquid crystalline dendrimer was able to change its structure by conformational changes in the flexible chains that link the mesogenic groups to the core. Structural change was seen under the application of a mean field ordering potential in the gas phase, and in the presence of liquid crystalline solvents. No liquid crystalline phases were observed for the bulk phase studies of the coarse-grained model. However, when the length of the mesogenic units was increased there was some evidence for microphase separation in these systems

2nd Generation ELT Performance Specification Development

NASA Search And Rescue is supporting RTCA SC-229 with research and recommendations for performance specifications for the 2nd generation of emergency locator transmitters. Areas for improvement and methods for collecting data will be presented

Micromechanical tuning elements in a 620-GHz monolithic integrated circuit

While monolithic integrated-circuit technology promises a practical means for realizing reliable reproducible planar millimeter and submillimeter-wave circuits, conventional planar circuits do not allow for critical post-fabrication optimization of performance. A 620-GHz quasi-optical monolithic detector circuit is used here to demonstrate the performance of two integrated micromechanical planar tuning elements. This is the first reported demonstration of integrated micromechanical tuning at submillimeter wavelengths. The tuning elements, called sliding planar backshorts (SPBs), are used to adjust the electrical length of planar transmission-line tuning stubs to vary the power delivered between a substrate-lens coupled planar antenna and a thin-film bismuth detector over a range of nearly 15 dB. The circuit performance agrees with theoretical calculations and microwave measurements of a -0.06-dB reflection coefficient made for a scale model of the integrated tuners. The demonstrated tuning range for the SPB tuners indicates that they can be valuable for characterizing components in developmental circuits and for optimizing the in-use performance of various millimeter and submillimeter-wave integrated circuits

Emergency Locator Transmitter System Performance During Three Full-Scale General Aviation Crash Tests

Full-scale crash tests were conducted on three Cessna 172 aircraft at NASA Langley Research Center's Landing and Impact Research facility during the summer of 2015. The purpose of the three tests was to evaluate the performance of commercially available Emergency Locator Transmitter (ELT) systems and support development of enhanced installation guidance. ELTs are used to provide location information to Search and Rescue (SAR) organizations in the event of an aviation distress situation, such as a crash. The crash tests simulated three differing severe but survivable crash conditions, in which it is expected that the onboard occupants have a reasonable chance of surviving the accident and would require assistance from SAR personnel. The first simulated an emergency landing onto a rigid surface, while the second and third simulated controlled flight into terrain. Multiple ELT systems were installed on each airplane according to federal regulations. The majority of the ELT systems performed nominally. In the systems which did not activate, post-test disassembly and inspection offered guidance for non-activation cause in some cases, while in others, no specific cause could be found. In a subset of installations purposely disregarding best practice guidelines, failure of the ELT-to-antenna cabling connections were found. Recommendations for enhanced installation guidance of ELT systems will be made to the Radio Technical Commission for Aeronautics (RTCA) Special Committee 229 for consideration for adoption in a future release of ELT minimum operational performance specifications. These recommendations will be based on the data gathered during this test series as well as a larger series of crash simulations using computer models that will be calibrated based on these dat

Sediment and fluvial particulate carbon flux from an eroding peatland catchment

Erosion and the associated loss of carbon is a major environmental concern in many peatlands and remains difficult to accurately quantify beyond the plot scale. Erosion was measured in an upland blanket peatland catchment (0.017 km2) in northern England using Structure‐from‐Motion (SfM) photogrammetry, sediment traps and stream sediment sampling at different spatial scales. A net median topographic change of –27 mm yr–1 was recorded by SfM over the 12‐month monitoring period for the entire surveyed area (598 m2). Within the entire surveyed area there were six nested catchments where both SfM and sediment traps were used to measure erosion. Substantial amounts of peat were captured in sediment traps during summer storm events after two months of dry weather where desiccation of the peat surface occurred. The magnitude of topographic change for the six nested catchments determined by SfM (mean value: 5.3 mm, standard deviation: 5.2 mm) was very different to the areal average derived from sediment traps (mean value: –0.3 mm, standard deviation: 0.1 mm). Thus direct interpolation of peat erosion from local net topographic change into sediment yield at the catchment outlet appears problematic. Peat loss measured at the hillslope scale was not representative of that at the catchment scale. Stream sediment sampling at the outlet of the research catchment (0.017 km2) suggested that the yields of suspended sediment and particulate organic carbon were 926.3 t km–2 yr–1 and 340.9 t km–2 yr–1 respectively, with highest losses occurring during the autumn. Both freeze–thaw during winter and desiccation during long periods of dry weather in spring and summer were identified as important peat weathering processes during the study. Such weathering was a key enabler of subsequent fluvial peat loss from the catchment

Child relationships in the middle grades

Thesis (Ed.M.)--Boston Universit

Noise auto-correlation spectroscopy with coherent Raman scattering

Ultrafast lasers have become one of the most powerful tools in coherent nonlinear optical spectroscopy. Short pulses enable direct observation of fast molecular dynamics, whereas broad spectral bandwidth offers ways of controlling nonlinear optical processes by means of quantum interferences. Special care is usually taken to preserve the coherence of laser pulses as it determines the accuracy of a spectroscopic measurement. Here we present a new approach to coherent Raman spectroscopy based on deliberately introduced noise, which increases the spectral resolution, robustness and efficiency. We probe laser induced molecular vibrations using a broadband laser pulse with intentionally randomized amplitude and phase. The vibrational resonances result in and are identified through the appearance of intensity correlations in the noisy spectrum of coherently scattered photons. Spectral resolution is neither limited by the pulse bandwidth, nor sensitive to the quality of the temporal and spectral profile of the pulses. This is particularly attractive for the applications in microscopy, biological imaging and remote sensing, where dispersion and scattering properties of the medium often undermine the applicability of ultrafast lasers. The proposed method combines the efficiency and resolution of a coherent process with the robustness of incoherent light. As we demonstrate here, it can be implemented by simply destroying the coherence of a laser pulse, and without any elaborate temporal scanning or spectral shaping commonly required by the frequency-resolved spectroscopic methods with ultrashort pulses.Comment: To appear in Nature Physic

A versatile protocol for Stille−Migita cross coupling reactions

The combination of catalytic amounts of [Pd(PPh3)4], copper thiophene-2-carboxylate (CuTC) and [Ph2PO2][NBu4] allowed a series of exigent Stille–Migita reactions to be performed with high yields; as the protocol is fluoride free, a variety of O-silyl and C-silyl groups remained intact

The declining representativeness of the British party system, and why it matters

In a recent article, Michael Laver has explained ‘Why Vote-Seeking Parties May Make Voters Miserable’. His model shows that, while ideological convergence may boost congruence between governments and the median voter, it can reduce congruence between the party system and the electorate as a whole. Specifically, convergence can increase the mean distance between voters and their nearest party. In this article we show that this captures the reality of today’s British party system. Policy scale placements in British Election Studies from 1987 to 2010 confirm that the pronounced convergence during the past decade has left the Conservatives and Labour closer together than would be optimal in terms of minimising the policy distance between the average voter and the nearest major party. We go on to demonstrate that this comes at a cost. Respondents who perceive themselves as further away from one of the major parties in the system tend to score lower on satisfaction with democracy. In short, vote-seeking parties have left the British party system less representative of the ideological diversity in the electorate, and thus made at least some British voters miserable

Monolithic millimeter-wave two-dimensional horn imaging arrays

A monolithic two-dimensional horn imaging array has been fabricated for millimeter wavelengths. In this configuration, a dipole is suspended in an etched pyramidal cavity on a 1-μm silicon-oxynitride membrane. This approach leaves room for low-frequency connections and processing electronics. The theoretical pattern is calculated by approximating the horn structure by a cascade of rectangular-waveguide sections. The boundary conditions are matched at each of the waveguide sections and at the aperture of the horn. Patterns at 93 and 242 GHz agree well with theory. Horn aperture efficiencies of 44±4%, including mismatch and resistive losses, have been measured. A detailed breakdown of the losses is presented. The coupling efficiency to various f-number imaging systems is investigated, and a coupling efficiency of 24% for an f0.7 imaging system (including spillover, taper, mismatch and resistive losses) has been measured. Possible application areas include imaging arrays for remote sensing, plasma diagnostics, radiometry and superconducting tunnel-junction receivers for radio astronomy