25 research outputs found
Not gate in a cis-trans photoisomerization model
We numerically study the implementation of a NOT gate by laser pulses in a
model molecular system presenting two electronic surfaces coupled by non
adiabatic interactions. The two states of the bit are the fundamental states of
the cis-trans isomers of the molecule. The gate is classical in the sense that
it involves a one-qubit flip so that the encoding of the outputs is based on
population analysis which does not take the phases into account. This gate can
also be viewed as a double photo-switch process with the property that the same
electric field controls the two isomerizations. As an example, we consider
one-dimensional cuts in a model of the retinal in rhodopsin already proposed in
the literature. The laser pulses are computed by the Multi Target Optimal
Control Theory with chirped pulses as trial fields. Very high fidelities are
obtained. We also examine the stability of the control when the system is
coupled to a bath of oscillators modelled by an Ohmic spectral density. The
bath correlation time scale being smaller than the pulse duration the dynamics
is carried out in the Markovian approximation.Comment: 29 pages, 7 figure
Quantum Driven Dissipative Parametric Oscillator in a Blackbody Radiation Field
We consider the general open system problem of a charged quantum oscillator
confined in a harmonic trap, whose frequency can be arbitrarily modulated in
time, that interacts with both an incoherent quantized (blackbody) radiation
field and with an arbitrary coherent laser field. We assume that the oscillator
is initially in thermodynamic equilibrium with its environment, a
non-factorized initial density matrix of the system and the environment, and
that at the modulation of the frequency, the coupling to the incoherent
and the coherent radiation are switched on. The subsequent dynamics, induced by
the presence of the blackbody radiation and the laser field, is studied in the
framework of the influence functional approach. This approach allows
incorporating, in \emph{analytic closed formulae}, the non-Markovian character
of the oscillator-environment interaction at any temperature as well the
non-Markovian character of the blackbody radiation and its zero-point
fluctuations. Expressions for the time evolution of the covariance matrix
elements of the quantum fluctuations and the reduced density-operator are
obtained.Comment: 11 pages. It matches the published versio
Coherent Control of Isotope Separation in HD+ Photodissociation by Strong Fields
The photodissociation of the HD+ molecular ion in intense short- pulsed
linearly polarized laser fields is studied using a time- dependent wave-packet
approach where molecular rotation is fully included. We show that applying a
coherent superposition of the fundamental radiation with its second harmonic
can lead to asymmetries in the fragment angular distributions, with significant
differences between the hydrogen and deuterium distributions in the long
wavelength domain where the permanent dipole is most efficient. This effect is
used to induce an appreciable isotope separation.Comment: Physical Review Letters, 1995 (in press). 4 pages in revtex format, 3
uuencoded figures. Full postcript version available at:
http://chemphys.weizmann.ac.il/~charron/prl.ps or
ftp://scipion.ppm.u-psud.fr/coherent.control/prl.p