49 research outputs found
3-(6-Benzyloxy-2,2-dimethylperhydrofuro[2,3-d][1,3]dioxolan-5-yl)-5-(4-chlorophenyl)-4-nitro-2-phenyl-2,3,4,5-tetrahydroisoxazole
In the title compound, C29H29ClN2O7, the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by intermolecular C—H⋯π interactions between a benzyloxy methylene H atom and the 4-chlorophenyl ring of an adjacent molecule, and by weak non-classical intermolecular C—H⋯O hydrogen bonds. In addition, the crystal structure exhibits a Cl⋯O halogen bond of 3.111 (3) Å, with a nearly linear C—Cl⋯O angle of 160.7 (1)°
10-(2-Pyridyloxy)phenanthren-9-ol
In the title compound, C19H13NO2, the pyridyl ring makes a dihedral angle of 87.04 (6)° with the plane of the phenanthrene ring system. In the crystal, molecules are linked through weak intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions
3-(6-Benzyloxy-2,2-dimethylperhydrofuro[2,3-d][1,3]dioxol-5-yl)-5-(4-bromophenyl)-2-phenylperhydropyrrolo[3,4-d]isoxazole-4,6-dione
In the title compound, C31H29BrN2O7, the isoxazolidine ring adopts a twist conformation, while the tetrahydrofuran, dioxolone and pyrrole rings adopt envelope conformations. The structure is stabilized by intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions
N-[(2-Hydroxy-5-methoxyphenyl)(3-nitrophenyl)methyl]acetamide
In the title compound, C16H16N2O5, the methoxy group is disordered with site occupancies of 0.20 (3) and 0.80 (3). The dihedral angle between the two aromatic rings is 73.7 (2)°. The crystal structure is characterized by intermolecular N—H⋯O, O—H⋯O, C—H⋯O and C—H⋯π hydrogen bonds
N-[(2-Hydroxy-1-naphthyl)(3-nitrophenyl)methyl]acetamide
The title compound, C19H16N2O4, is of interest as a precursor to biologically active substituted quinolines and related compounds. The dihedral angle between the naphthalene ring system and the benzene ring is 81.9 (1)°. The crystal structure is stabilized by N—H⋯O intermolecular hydrogen bonds, linking the molecules into pairs around a center of symmetry. The crystal structure is further stabilized by intermolecular O—H⋯O hydrogen bonds, which link the molecules into chains running along a axis. An intramolecular C—H⋯O short contact is also present
3-(1,2-Diphenylethenyl)-2-phenyl-1H-indole
In the title compound, C28H21N, the planar pyrrole ring makes dihedral angles of 1.5 (2), 42.4 (2), 65.4 (2) and 79.7 (1)°, with the least squares planes of the four phenyl rings. The molecular structure and crystal packing are stabilized by weak inter- and intramolecular C—H⋯π interactions
catena-Poly[ammonium (cadmium-tri-μ-thiocyanato-κ4 S:N;κ2 N:S)–1,4,10,13,16-hexaoxacyclooctadecane (1/1)]
In the title compound, {(NH4)[Cd(NCS)3]·C12H24O6}n, the Cd2+ ion, the ammonium cation, one of the SCN− ligands and the macrocycle are located on mirror planes. The thiocyanate anions act as bridging ligands between the CdII ions, leading to a polymeric chain arrangement extending along [001] around a twofold screw axis. The ammonium ions are contained within the bowl of the macrocycle via extensive N—H⋯O hydrogen bonding
1-Benzyl-3-(1,2-diphenylethenyl)-1H-indole
In the title compound, C29H23N, the planar [maximum deviation from the least squares plane = 0.056 (1) Å] indole ring makes dihedral angles of 83.4 (4), 69.9 (1) and 59.9 (1)°, with the least-squares planes of three benzene rings. The molecular packing is stabilized by weak intermolecular C—H⋯π interactions
[1-(3-Nitrophenyl)-2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazin-3-ylidine]malonaldehyde
The oxazine ring in the title compound, C21H14N2O5, adopts a flattened boat conformation. The nitrophenyl ring and the naphthalene ring system enclose a dihedral angle of 89.2 (1)°. An intramolecular hydrogen bond is formed between the NH group and one of the adjacent carbonyl O atoms. In addition, the NH group forms an intermolecular hydrogen bond to a symmetry equivalent of this carbonyl O atom, connecting the molecules into centrosymmetric dimers. The structure also contains C—H⋯O intermolecular interactions
Ethyl 3′-(2,4-dichlorophenyl)-5′-hydroxy-5′-methyl-4′,5′-dihydrospiro[fluorene-9,2′(3′H)-furan]-4′-carboxylate
The furan ring and the five-membered fluorene unit in the title compound, C26H22Cl2O4, adopt envelope conformations. Intermolecular C—H⋯O interactions between symmetry-related molecules involving two C—H groups and an O atom as a bifurcated acceptor generate centrosymmetric hydrogen-bonded dimers with cyclic R
2
2(16) and R
2
2(8) ring motifs. A short C—H⋯Cl intramolecular contact occurs in the molecule