Alternative derivation of Mie theory with electromagnetic potentials for diffuse particles

Mie's theory of light scattering on spherical particles is being increasingly used in nanophotonics, and these demanding applications have laid bare some shortcomings of Mie theory in its standard formulation. One problem that deserves special attention is the electron spill-out in small metallic nanoparticles, which invalidates the assumption of an abrupt interface. Here we present an alternative derivation of Mie theory without this assumption. To avoid the usual electromagnetic boundary conditions suitable for a hard-wall interface, we set up equations for the electromagnetic potentials instead of the electric and magnetic field. We show that in the limit of a hard-wall interface, the results of the standard Mie theory are recovered. Additionally, a numerical solution scheme is proposed for the equations for the vector potential and the scalar potential. Analysis of the optical cross sections of soft-interface nanospheres shows that the absorption increases and occurs at lower frequencies as compared to hard-walled nanospheres. This effect is rather dramatic in large spheres with large spill-out, due to the disappearance of high-frequency resonance peaks

Evaluation of Selected Performance Properties of Nanoclay-Modified Asphalt Binders

Asphalt binders are often modified with additives such as acid, polymer, or a combination of multiple additives to achieve improved performance to sustain heavy loads and adverse weather conditions. According to some previous researches, nanoclay can be a good alternative of currently practiced Styrene-Butadiene-Styrene (SBS) modification, and the former is expected to reduce the overall cost of the asphalt binder. Three types of nanoclay (Cloisite 10A, 11B, and 15A) were blended with asphalt binders prepared from two different sources (Arabian Crude and Canadian Crude). A blending protocol has been developed to blend nanoclay with the base binders. Mechanical properties including viscosity, rutting parameter have undergone significant changes after the nanoclay modification. It was also observed that nanoclay modified binders offer different moisture susceptibility while bonding with different aggregates; the nanoclay modified asphalt binder exhibits better bonding with gravel than sandstone. Mechanistic properties such as viscosity and rutting parameter are found to be highly correlated with the chemical compositions. Binders from the Canadian crude showed more colloidal stability than binders from the Arabian crude after nanoclay modification

Cloud-Based Routing Resource Allocation in Cognitive Radio Networks

Wi-Fi Direct technology is enabled to support multiple services to be done via Wi-Fi connection. It provides the most efficient method to develop ad-hoc community among mobile devices for connecting quickly with one another without needing an access to the network. It allows communicating at common Wi-Fi rates for various applications including document exchange and online connection. This one-stop WiFi Direct application is able to connect a device to a single device at a time, i.e., only peer to peer communication is allowed within one hop. Hence, multi-device communication within multi-hop distance in a trusty Cognitive Radio (CR) network environment is in demand. This paper presents the development of an Android-based application with optimum cloud routing service to transfer files or chatting via Wi-Fi Direct technology in CR network. A system is developed using smartphones (with developed applications) and nodes with WI-FI connection. An indirect multi-hop routing approach is created if more devices transfer files simultaneously from hop to hop. After login and initializing, a device discovers the neighboring nodes first and then connects those (as necessary) to transfer a file or start chatting. The very moment a connection is established, a log file is generated in internal memory and save a backup copy in cloud containing necessary networking information of the client devices. The aim of these backup log files is for forensic investigation for intrusion detection/prevention and secured communications. Then the chatting or file transfer is carried out between the connected devices either in single or multi-hop routes. Results show that the system’s efficiency is around 92%. It shows that multi-device, multi-hop Wi-Fi Direct services can be implemented using Android devices with Eclipse Java programming in CR networks

Interference issues and mitigation method in WSN 2.4GHz ISM band: A survey

Current lifestyles promote the development and advancement in wireless technologies, especially in Wireless Sensor Networks (WSN) due to its several benefits.WSN offers a low cost, low data rate, flexible routing, longer lifetime, and low-energy consumption suitable for unmanned and long term monitoring.Among huge WSN applications, some key applications are smart houses, environmental monitoring, military applications, and other monitoring applications.As a result, ubiquitous increase in the number of wireless devices occupying the 2.4GHz frequency band.This causes a dense wireless connection followed by interference problem to WSN in the 2.4GHz frequency band. WSN is most affected by the interference issue because it has a lower data rate and transmission power compared to WLAN.Despite efforts made by researchers, to the author's knowledge, the interference issue is still a major problem in wireless networks.This paper aims to review the coexistence and interference issues of existing wireless technologies in the 2.4GHz Industrial, Scientific and Medical (ISM) band.Keywords— Coexistence, Frequency Spectrum, IEEE 802.15.4, Interference, WSN, 2.4GHz ISM ban

Cognitive Radio Based Optimal Channel Sensing for Resource Allocation in Communications

Cognitive Radio (CR) is the cutting-edge wireless technology that is used to solve the spectrum saturation problem. In cognitive radio, Secondary Users (SUs) use Primary User’s (PU’s) spectrum (licensed band) during PU’s absence. Cognitive radio provides more flexibility in terms of spectrum utilization but the spectrum sensing efficiency need to be improved to make sure that the PUs are not interrupted while they are active. This paper presents the test-bed development of a CR network using Android-based smartphones for optimal sensing and data transmission. An energy detector based sensing method is proposed and used here since the energy detector does not require the information of the PU. The CR features have been implemented in Android phone using the Eclipse Java programming. The test-bed experimental set up was done using Android-based smartphones and Wi-Fi Access Point (AP). Two spectrum, Wi-Fi and Bluetooth were used to verify the sensing and detection efficiency. Results show that the proposed sensing and detection scheme efficiency is about 83%

Hierarchically Porous Gd3+-Doped CeO2 Nanostructures for the Remarkable Enhancement of Optical and Magnetic Properties

Rare earth ion-doped CeO2 has attracted more and more attention because of its special electrical, optical, magnetic, or catalytic properties. In this paper, a facile electrochemical deposition route was reported for the direct growth of the porous Gd-doped CeO2. The formation process of Gd-doped CeO2 composites was investigated. The obtained deposits were characterized by SEM, EDS, XRD, and XPS. The porous Gd3+- doped CeO2 (10 at% Gd) displays a typical type I adsorption isotherm and yields a large specific surface area of 135 m2/g. As Gd3+ ions were doped into CeO2 lattice, the absorption spectrum of Gd3+-doped CeO2 nanocrystals exhibited a red shift compared with porous CeO2 nanocrystals and bulk CeO2, and the luminescence of Gd3+-doped CeO2 deposits was remarkably enhanced due to the presence of more oxygen vacancies. In addition, the strong magnetic properties of Gd-doped CeO2 (10 at% Gd) were observed, which may be caused by Gd3+ ions or more oxygen defects in deposits. In addition, the catalytic activity of porous Gd-doped CeO2 toward CO oxidation was studied

Surgical management and outcome of newly diagnosed glioblastoma without contrast enhancement (<i>low-grade appearance</i>):a report of the RANO <i>resect </i>group

BackgroundResection of the contrast-enhancing (CE) tumor represents the standard of care in newly diagnosed glioblastoma. However, some tumors ultimately diagnosed as glioblastoma lack contrast enhancement and have a ‘low-grade appearance’ on imaging (non-CE glioblastoma). We aimed to (a) volumetrically define the value of non-CE tumor resection in the absence of contrast enhancement, and to (b) delineate outcome differences between glioblastoma patients with and without contrast enhancement.MethodsThe RANO resect group retrospectively compiled a global, eight-center cohort of patients with newly diagnosed glioblastoma per WHO 2021 classification. The associations between postoperative tumor volumes and outcome were analyzed. Propensity score-matched analyses were constructed to compare glioblastomas with and without contrast enhancement.ResultsAmong 1323 newly diagnosed IDH-wildtype glioblastomas, we identified 98 patients (7.4%) without contrast enhancement. In such patients, smaller postoperative tumor volumes were associated with more favorable outcome. There was an exponential increase in risk for death with larger residual non-CE tumor. Accordingly, extensive resection was associated with improved survival compared to lesion biopsy. These findings were retained on a multivariable analysis adjusting for demographic and clinical markers. Compared to CE glioblastoma, patients with non-CE glioblastoma had a more favorable clinical profile and superior outcome as confirmed in propensity score analyses by matching the patients with non-CE glioblastoma to patients with CE glioblastoma using a large set of clinical variables.ConclusionsThe absence of contrast enhancement characterizes a less aggressive clinical phenotype of IDH-wildtype glioblastomas. Maximal resection of non-CE tumors has prognostic implications and translates into favorable outcome

Implant removal associated complications in children with limb fractures due to trauma

Surger

A Simple, Inexpensive Device for Nucleic Acid Amplification without Electricity—Toward Instrument-Free Molecular Diagnostics in Low-Resource Settings

Molecular assays targeted to nucleic acid (NA) markers are becoming increasingly important to medical diagnostics. However, these are typically confined to wealthy, developed countries; or, to the national reference laboratories of developing-world countries. There are many infectious diseases that are endemic in low-resource settings (LRS) where the lack of simple, instrument-free, NA diagnostic tests is a critical barrier to timely treatment. One of the primary barriers to the practicality and availability of NA assays in LRS has been the complexity and power requirements of polymerase chain reaction (PCR) instrumentation (another is sample preparation).In this article, we investigate the hypothesis that an electricity-free heater based on exothermic chemical reactions and engineered phase change materials can successfully incubate isothermal NA amplification assays. We assess the heater's equivalence to commercially available PCR instruments through the characterization of the temperature profiles produced, and a minimal method comparison. Versions of the prototype for several different isothermal techniques are presented.We demonstrate that an electricity-free heater based on exothermic chemical reactions and engineered phase change materials can successfully incubate isothermal NA amplification assays, and that the results of those assays are not significantly different from ones incubated in parallel in commercially available PCR instruments. These results clearly suggest the potential of the non-instrumented nucleic acid amplification (NINA) heater for molecular diagnostics in LRS. When combined with other innovations in development that eliminate power requirements for sample preparation, cold reagent storage, and readout, the NINA heater will comprise part of a kit that should enable electricity-free NA testing for many important analytes