Collisional broadening and spectral line shape of an entire rotational band

The impact approximation is applied to the classical binary collision operator making it possible to derive an expression for the dipole correlation function for real systems in a form which is computationally tractable and contains no adjustable parameters. Trajectory calculations are performed (in order to evaluate the microscopic expression for the relaxation parameter in the correlation function) for the system CO in dense Ar gas. Comparison is made with experimental data and excellent agreement is found for certain densities when a quantum correction is included. At higher densities (i.e., ρ^(−1/3)< "the range of the potential") one approximation is not valid and comparison with experiment illustrates this point

Cross-correlation trajectory study of V-V energy transfer in HF-HF and DF-DF

Results of a fully three‐dimensional classical trajectory calculation of vibrational energy transfer are presented for the collision of HF(v=1) with HF(v=1) and its deuterium analog. A cross‐correlation method, together with quasiclassical trajectories, is introduced to relate the changes in vibrational states of the two molecules to probabilities and rate constants. Multiple collisions are found to make an important contribution to the vibrational energy transfer cross‐sections for the present potential surface. Vibrational anharmonicity is shown to decrease the energy transfer rate constant by a factor of ten, by causing the process to be further from exact resonance. Excellent agreement with experiment is obtained for the HF–HF and DF–DF systems

Coulomb Oscillations in Antidots in the Integer and Fractional Quantum Hall Regimes

We report measurements of resistance oscillations in micron-scale antidots in both the integer and fractional quantum Hall regimes. In the integer regime, we conclude that oscillations are of the Coulomb type from the scaling of magnetic field period with the number of edges bound to the antidot. Based on both gate-voltage and field periods, we find at filling factor {\nu} = 2 a tunneling charge of e and two charged edges. Generalizing this picture to the fractional regime, we find (again, based on field and gate-voltage periods) at {\nu} = 2/3 a tunneling charge of (2/3)e and a single charged edge.Comment: related papers at http://marcuslab.harvard.ed

Photovoltaic and Rectification Currents in Quantum Dots

We investigate theoretically and experimentally the statistical properties of dc current through an open quantum dot subject to ac excitation of a shape-defining gate. The symmetries of rectification current and photovoltaic current with respect to applied magnetic field are examined. Theory and experiment are found to be in good agreement throughout a broad range of frequency and ac power, ranging from adiabatic to nonadiabatic regimes.Comment: 4 pages, 3 figures; related articles at http://marcuslab.harvard.ed

Spin Amplification for Magnetic Sensors Employing Crystal Defects

Recently there have been several theoretical and experimental studies of the prospects for magnetic field sensors based on crystal defects, especially nitrogen vacancy (NV) centres in diamond. Such systems could potentially be incorporated into an AFM-like apparatus in order to map the magnetic properties of a surface at the single spin level. In this Letter we propose an augmented sensor consisting of an NV centre for readout and an `amplifier' spin system that directly senses the local magnetic field. Our calculations show that this hybrid structure has the potential to detect magnetic moments with a sensitivity and spatial resolution far beyond that of a simple NV centre, and indeed this may be the physical limit for sensors of this class

Signatures of Random Matrix Theory in the Discrete Energy Spectra of Subnanosize Metallic Clusters

Lead clusters deposited on Si(111) substrates have been studied at low temperatures using scanning tunneling microscopy and spectroscopy. The current-voltage characteristics exhibit current peaks that are irregularly spaced and varied in height. The statistics of the distribution of peak heights and spacings are in agreement with random matrix theory for several clusters. The distributions have also been studied as a function of cluster shape.Comment: 10 pages, 9 figures, to appear in Phys. Rev.