13 research outputs found

    Magnetometry Based on Nonlinear Magneto-Optical Rotation with Amplitude-Modulated Light

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    We report on an all-optical magnetometric technique based on nonlinear magneto-optical rotation with amplitude-modulated light. The method enables sensitive magnetic-field measurements in a broad dynamic range. We demonstrate the sensitivity of 4.3×1094.3\times10^{-9} G/Hz\sqrt{\text{Hz}} at 10 mG and the magnetic field tracking in a range of 40 mG. The fundamental limits of the method sensitivity and factors determining current performance of the magnetometer are discussed.Comment: Submitted to Journal of Applied Physics 8 pages, 8 figure

    Presentation of the ISRM mine closure state of the art report

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    International audienceIn 2005, Prof. Nielen Van der Merwe, at that time President of the ISRM, initiated a commission to facilitate the constitution of an international network of experts involved in mine closure and post-mining management. Eight experts coming from different countries have been deeply involved in this ISRM 'mine closure commission', for four years. Closure of mining operations does not lead to the complete elimination of risks likely to affect the surface above old mine workings. Therefore, disorders potentially harmful for people and goods may develop, sometimes just after the closure but also, in some cases, long time after. The first mandate of the commission has been dedicated to the elaboration of a state-ofthe- art report presenting, at an international scale, the mine closure problem (context, main risks of disorders, major hazard assessment methods and treatment techniques). The present paper presents an outline of this ISRM report that members may download on the ISRM website

    All-optical atomic magnetometers based on nonlinear magneto-optical rotation with amplitude modulated light

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    We demonstrate a magnetometric technique based on nonlinear magneto-optical rotation using amplitude modulated light. The magnetometers can be operated in either open-loop (typical nonlinear magneto-optical rotation with amplitude-modulated light) or closed-loop (self-oscillating) modes. The latter mode is particularly well suited for conditions where the magnetic field is changing by large amounts over a relatively short timescale.Comment: 8 pages, 6 figures, Submitted to Proc. of SPIE, Proceedings of XIVth International School on Quantum Electronics, Sunny Beach, Bulgaria 200

    Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature

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    Two-dimensional hybrid organic–inorganic lead halides perovskite-type compounds have attracted immense scientific interest due to their remarkable optoelectronic properties and tailorable crystal structures. In this work, we present a new layered hybrid lead halide, namely [CH(NH2)2][C(NH2)3]PbI4, wherein puckered lead-iodide layers are separated by two small and stable organic cations: formamidinium, CH(NH2)2+, and guanidinium, C(NH2)3+. This perovskite is thermally stable up to 255 °C, exhibits room-temperature photoluminescence in the red region with a quantum yield of 3.5%, and is photoconductive. This study highlights a vast structural diversity that exists in the compositional space typically used in perovskite photovoltaics.ISSN:0002-7863ISSN:1520-512

    Guanidinium and Mixed Cesium-Guanidinium Tin(II) Bromides: Effects of Quantum Confinement and Out-of-Plane Octahedral Tilting

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    Hybrid organic–inorganic main-group metal halide compounds are the subject of intense research owing to their unique optoelectronic characteristics. In this work, we report the synthesis, structure, and electronic and optical properties of a family of hybrid tin (II) bromide compounds comprising guanidinium [G, C(NH2)3+] and mixed cesium–guanidinium cations: G2SnBr4, CsGSnBr4, and Cs2GSn2Br7. G2SnBr4 has a one-dimensional structure that consists of chains of corner-sharing [SnBr5]2– square pyramids and G cations situated in between the chains. Cs+ exhibits a pronounced structure-directing effect where a mixture of Cs+ and G cations forms mono- and bilayered two-dimensional perovskites: CsGSnBr4 and Cs2GSn2Br7. Furthermore, the flat shapes of the guanidinium cations induce anisotropic out-of-plane tilts of the [SnBr6]4– octahedra in the CsGSnBr4 and Cs2GSn2Br7 compounds. In G2SnBr4, the Sn lone pair is highly stereoactive and favors non-octahedral, that is, square pyramidal coordination of Sn(II). G2SnBr4 exhibits bright broad-band emission from self-trapped excitonic states, owing to its soft lattice and electronic localization. This emission in G2SnBr4 is characterized by a photoluminescence (PL) quantum yield of 2% at room temperature (RT; 75 ± 5% at 77 K) and a fast PL lifetime of 18 ns at room temperature.ISSN:0897-475
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