Microscopic analysis of multipole susceptibility of actinide dioxides: A scenario of multipole ordering in AmO2_2

By evaluating multipole susceptibility of a seven-orbital impurity Anderson model with the use of a numerical renormalization group method, we discuss possible multipole states of actinide dioxides at low temperatures. In particular, here we point out a possible scenario for multipole ordering in americium dioxide. For Am$^{4+}$ ion with five $5f$ electrons, it is considered that the ground state is $\Gamma_7^{-}$ doublet and the first excited state is $\Gamma_8^{-}$ quartet, but we remark that the $f^5$ ground state is easily converted due to the competition between spin-orbit coupling and Coulomb interactions. Then, we find that the $\Gamma_8^-$ quartet can be the ground state of AmO$_2$ even for the same crystalline electric field potential. In the case of $\Gamma_8^-$ quartet ground state, the numerical results suggest that high-order multipoles such as quadrupole and octupole can be relevant to AmO$_2$.Comment: 8 pages, 4 figures. To appear in Phys. Rev.

The magnetic structure of the zigzagzigzag chain family Nax_{x}Ca1−x_{1-x}V2_2O4_4 determined by muon-spin rotation

We present muon-spin rotation measurements on polycrystalline samples of the complete family of the antiferromagnetic (AF) $zigzag$ chain compounds, Na$_x$Ca$_{1-x}$V$_2$O$_4$. In this family, we explore the magnetic properties from the metallic NaV$_2$O$_4$ to the insulating CaV$_2$O$_4$. We find a critical $x_c(\sim0.833)$ which separates the low and high Na-concentration dependent transition temperature and its magnetic ground state. In the $x<x_c$ compounds, the magnetic ordered phase is characterized by a single homogenous phase and the formation of incommensurate spin-density-wave order. Whereas in the $x>x_c$ compounds, multiple sub-phases appear with temperature and $x$. Based on the muon data obtained in zero external magnetic field, a careful dipolar field simulation was able to reproduce the muon behavior and indicates a modulated helical incommensurate spin structure of the metallic AF phase. The incommensurate modulation period obtained by the simulation agrees with that determined by neutron diffraction.Comment: 7 pages, 7 figures, accepted for publication in PR

Probing the magnetic ground state of the molecular Dysprosium triangle

We present zero field muon spin lattice relaxation measurements of a Dysprosium triangle molecular magnet. The local magnetic fields sensed by the implanted muons indicate the coexistence of static and dynamic internal magnetic fields below $T^* ~35$ K. Bulk magnetization and heat capacity measurements show no indication of magnetic ordering below this temperature. We attribute the static fields to the slow relaxation of the magnetization in the ground state of Dy3. The fluctuation time of the dynamic part of the field is estimated to be ~0.55 $\mu$s at low temperaturesComment: 5 pages, 5 figures, accepted for publication in Phys. Rev.

Magnetism of PdNi alloys near the critical concentration for ferromagnetism

We report results of a muon spin rotation and relaxation ($\mu$SR) study of dilute Pd$_{1-x}$Ni$_x$ alloys, with emphasis on Ni concentrations $x =$ 0.0243 and 0.025. These are close to the critical value $x_\mathrm{cr}$ for the onset of ferromagnetic long-range order (LRO), which is a candidate for a quantum critical point. The 2.43 and 2.5 at.% Ni alloys exhibit similar $\mu$SR properties. Both samples are fully magnetic, with average muon local fields $\langle B^\mathrm{loc}\rangle =$ 2.0 and 3.8 mT and Curie temperatures $T_C =$ 1.0 and 2.03 K for 2.43 and 2.5 at.% Ni, respectively, at $T = 0$. The temperature dependence of $\langle B^\mathrm{loc}\rangle$ suggests ordering of Ni spin clusters rather than isolated spins. Just above $T_C$ a two-phase region is found with separate volume fractions of quasistatic short-range order (SRO) and paramagnetism. The SRO fraction decreases to zero with increasing temperature a few kelvin above $T_C$. This mixture of SRO and paramagnetism is consistent with the notion of an inhomogeneous alloy with Ni clustering. The measured values of $T_C$ extrapolate to $x_\mathrm{cr}$ = 0.0236 $\pm$ 0.0027. The dynamic muon spin relaxation in the vicinity of $T_C$ differs for the two samples: a relaxation-rate maximum at $T_C$ is observed for $x$ = 0.0243, reminiscent of critical slowing down, whereas for $x =$ 0.025 no dynamic relaxation is observed within the $\mu$SR time window. The data suggest a mean-field-like transition in this alloy.Comment: 15 pages, 15 figures, to be published in Phys. Rev.

Two dimensionality in quasi one-dimensional cobalt oxides

By means of muon spin rotation and relaxation ($\mu^+$SR) techniques, we have investigated the magnetism of quasi one-dimensional (1D) cobalt oxides $AE_{n+2}$Co$_{n+1}$O$_{3n+3}$ ($AE$=Ca, Sr and Ba, $n$=1, 2, 3, 5 and $\infty$), in which the 1D CoO$_3$ chain is surrounded by six equally spaced chains forming a triangular lattice in the $ab$-plane, using polycrystalline samples, from room temperature down to 1.8 K. For the compounds with $n$=1 - 5, transverse field $\mu^+$SR experiments showed the existence of a magnetic transition below $\sim$100 K. The onset temperature of the transition ($T_{\rm c}^{\rm on}$) was found to decrease with $n$; from 100 K for $n$=1 to 60 K for $n$=5. A damped muon spin oscillation was observed only in the sample with $n$=1 (Ca$_3$Co$_2$O$_6$), whereas only a fast relaxation obtained even at 1.8 K in the other three samples. In combination with the results of susceptibility measurements, this indicates that a two-dimensional short-range antiferromagnetic (AF) order appears below $T_{\rm c}^{\rm on}$ for all compounds with $n$=1 - 5; but quasi-static long-range AF order formed only in Ca$_3$Co$_2$O$_6$, below 25 K. For BaCoO$_3$ ($n$=$\infty$), as $T$ decreased from 300 K, 1D ferromagnetic (F) order appeared below 53 K, and a sharp 2D AF transition occurred at 15 K.Comment: 12 pages, 14 figures, and 2 table

The magnetic phase of the perovskite CaCrO3_3 studied with μ+\mu^{+}SR

We investigated the magnetic phase of the perovskite CaCrO$_3$ by using the muon spin relaxation technique accompanied by susceptibility measurements. A thermal hysteresis loop is identified with a width of about 1 K at the transition temperature. Within the time scale of the muon lifetime, a static antiferromagnetic order is revealed with distinct multiple internal fields which are experienced in the muon interstitial sites below the phase-transition temperature, $T_N=90 K$. Above $T_N$, lattice deformations are indicated by transverse-field muon-spin rotation and relaxation suggesting a magneto-elastic mechanism.Comment: 5 pages, 4 figures. Accepted for publication in PR

The Herbertsmithite Hamiltonian: μ\muSR measurements on single crystals

We present transverse field muon spin rotation/relaxation measurements on single crystals of the spin-1/2 kagome antiferromagnet Herbertsmithite. We find that the spins are more easily polarized when the field is perpendicular to the kagome plane. We demonstrate that the difference in magnetization between the different directions cannot be accounted for by Dzyaloshinksii-Moriya type interactions alone, and that anisotropic axial interaction is present.Comment: 8 pages, 3 figures, accepted to JPCM special issue on geometrically frustrated magnetis

Transport properties of moderately disordered UCu4_4Pd

We present a detailed study on the (magneto)transport properties of as-cast and heat treated material UCu$_4$Pd. We find a pronounced sample dependence of the resistivity $\rho$ of as-cast samples, and reproduce the annealing dependence of $\rho$. In our study of the Hall effect we determine a metallic carrier density for all samples, and a temperature dependence of the Hall constant which is inconsistent with the Skew scattering prediction. The magnetoresistive response is very small and characteristic for spin disorder scattering, suggesting that overall the resistivity is controlled mostly by nonmagnetic scattering processes. We discuss possible sources for the temperature and field dependence of the transport properties, in particular with respect to quantum criticality and electronic localization effects.Comment: 11 pages, 9 figures, submitted PR

Li diffusion in Lix_xCoO2_2 probed by muon-spin spectroscopy

The diffusion coefficient of Li$^+$ ions ($D_{\rm Li}$) in the battery material Li$_x$CoO$_2$ has been investigated by muon-spin relaxation ($\mu^+$SR). Based on the experiments in zero-field and weak longitudinal-fields at temperatures up to 400 K, we determined the fluctuation rate ($\nu$) of the fields on the muons due to their interaction with the nuclear moments. Combined with susceptibility data and electrostatic potential calculations, clear Li$^+$ ion diffusion was detected above $\sim150$K. The $D_{\rm Li}$ estimated from $\nu$ was in very good agreement with predictions from first-principles calculations, and we present the $\mu^+$SR technique as an % novel and optimal probe to detect $D_{\rm Li}$ for materials containing magnetic ions.Comment: 4 pages, 4 figures. accepted for publication in PR