33 research outputs found
Pakistani Sisyphean Heroes in Taufiq Rafat’s Foothold
The protagonist of Foothold, Saleem, wanders off into the wilderness to seek faith like Buddha. He does not give up his quest as he returns home to his family and friends, and learns that faith can be found and practised amongst his community. A close reading of the text proves that Saleem bears the qualities of a Sisyphean Hero as outlined by Albert Camus. Other characters have also been subjected to a similar scrutiny to prove whether they are Sisyphean Heroes or not. Furthermore, the close reading of Foothold renders an insight into the generation of the Sixties who experienced decolonization and felt like misfits in their own environment. Saleem is acutely affected by the process of decolonization and hence, he is deeply puzzled with the institutionalized religion in Pakistan. To shape the theoretical framework of this research, The Myth of Sisyphus and Other Essays, The Stranger, and A Happy Death have been used. As there is a dearth of criticism on Foothold therefore, the interpretations for this research have been derived from Camus’ works. This research will be beneficial to those researchers who wish to study the application of Camus’ works in a postcolonial setting. Moreover, the scope of this project extends to Sufism, Mysticism, and Imagism
N-Phenyl-6-(1H-pyrazol-1-yl)pyridazin-3-amine
The molecule of title compound, C13H11N5, is essentially planar (r.m.s. deviation = 0.0440 Å) and an intramolecular C—H⋯N hydrogen bond generates an S(6) motif. In the crystal, molecules are connected into chains by intermolecular N—H⋯N and C—H⋯N hydrogen bonds. In addition, π–π stacking interactions are observed between the pyrazole and pyridazine rings [interplanar distance = 3.6859 (10) Å]
3-Chloro-6-[(E)-2-(1-phenylethylidene)hydrazinyl]pyridazine
Two independent molecules are present in the asymmetric unit of the title compound, C12H11ClN4, (Z′ = 2): the dihedral angles between the phenyl and pyridizine rings are 8.35 (10) and 37.64 (6)°. In the crystal, the two molecules form inversion dimers with R
2
2(8) ring motifs through intermolecular N—H⋯N hydrogen bonds. The crystal structure is stabilized by π–π interactions between the pyridazine rings of symmetry-related molecules. In one of the independent molecules, the centroid–centroid separations are 3.6927 (13) and 3.7961 (13) Å, whereas in the other, the separations are 3.6909 (13) and 3.9059 (13) Å
3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine
The asymmetric unit of the title compound, C9H11ClN4, contains two virtually planar molecules that differ in conformation about the bond connecting the hydrazine and pyridazine units. The 3-chloro-6-hydrazinylpyridazine and cyclopentane groups are oriented at dihedral angles of 4.5 (3) and 8.8 (4)° in the two molecules. In the crystal, the molecules form a one dimensional polymeric structure extending along the a axis via N—H⋯N hydrogen bonds. The crystal stucired was an inversion twin [ratio of the twin domains = 0.73 (9):0.27 (9)]
3-[(2E)-2-(Butan-2-ylidene)hydrazinyl]-6-chloropyridazine
The asymmetric unit of the title compound, C8H11ClN4, contains two independent molecules (A and B) with slightly different conformations: the dihedral angles between the 3-chloro-6-hydrazinylpyridazine units and butyl side chains are 4.5 (2) and 11.98 (16)°. In the crystal, the A and B molecules are linked by a pair of N—H⋯N hydogen bonds, generating an R
2
2(8) loop
3-Chloro-6-(1H-pyrazol-1-yl)pyridazine
The title compound, C7H5ClN4, is almost planar (r.m.s. deviation = 0.022 Å). The dihedral angle between the aromatic rings is 2.82 (5)°. The packing results in polymeric chains extending along the a axis. In the crystal, molecules are connected to each other through intermolecular C—H⋯N hydrogen bonds, resulting in R
2
2(10) ring motifs
3-Chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine
In the title compound, C9H9ClN4, the dihedral angle between the aromatic rings is 6.25 (9)°. The whole molecule is approximately planar (r.m.s. deviation = 0.070 Å). In the crystal, π–π interactions between the centroids of the pyridazine rings [separation = 3.5904 (10) Å] occur
6-Chloro-N-(2-methoxyphenyl)pyridazin-3-amine
The asymmetric unit of the title compound, C11H10ClN3O, contains two geometrically different molecules, A and B, in both of which the pyridazine rings are essentially planar with r.m.s. deviations of 0.0137 and 0.0056Å, respectively. In molecule A, the dihedral angle between the pyridazine and benzene rings is 6.5 (2)°, whereas in molecule B it is 27.93 (7)°. In molecule B, an intramolecular N—H⋯O hydrogen bond forms an S(5) ring motif. In both molecules, S(6) ring motifs are present due to non-classical C—H⋯N hydrogen bonds. The π–π interactions between the pyridazine rings of A molecules [3.4740 (13) Å] and B molecules [3.4786 (17) Å] have very similar centroid–centroid separations. π–π Interactions also occur between the benzene rings of B molecules with a centroid–centroid separation of 3.676 (2) Å and a slippage of 1.02 Å. In the crystal, the molecules are linked into chains extending along [010] by C—H⋯N and C—H⋯Cl interactions
N-(4-Methylphenyl)-6-(pyrazol-1-yl)pyridazin-3-amine
In the title compound, C14H13N5, the pyrazole ring is disordered over two orientations in a 0.571 (10):0.429 (10) ratio and the dihedral angle between the pyridazine ring and the benzene ring is 28.07 (10)°. In the crystal, pairs of N—H⋯N and C—H⋯N hydrogen bonds link the molecules into dimers, with the aid of a crystallographic twofold axis. The packing is consolidated by further C—H⋯N bonds and weak C—H⋯π interactions