PVD black coating for decorative applications

PVD coatings have gained considerable attention as decorative coatings because they combine decorative with protective properties. Within the frame of this work, a black PVD coating based on chromium, carbon and oxygen was developed in a semi-industrial coating machine with four magnetrons and continuous substrate rotation. Based on the optical properties of CrxCyOz, the optical properties of the coating can be used in the design of the coating. EDX measurements point to an average composition of Cr0.35O0.53C0.12 for coatings with the most interesting optical properties. XPS measurements show that the chemical state of the constituting elements changes throughout the coating thickness. CrxCyOz shows a strong columnar growth whichmay give origin to a rough surface structure. This effect, depending on the coating thickness, allows the deposition of black coatings with a variation of strong specular reflection (“piano black”) and diffuse reflection (“matt”) for a coating thickness variation between 1 and 5 m. The diffusive reflection increased from almost 2% to 6% for the thicker samples whereby the specular reflection decreased from about 20% to almost 0 of the samples with a thin coating and samples with a coating thickness close to 5 m. Within the frame of this work, we also determined the functional properties of adherence and surface energy, which show that the coating can be used in demanding applications without an additional protective topcoat.This research was funded by Agência Nacional de Inovação within the frame of the project GREENCOAT Green Vacuum Coatings—Metalização Ecológica de Plásticos POCI-01-0247-FEDER042785. One of the authors (Nadia Arrousse) appreciates a fellow ship grant within the project

Structural characterization of μc-Si:H films produced by R.F. magnetron sputtering

Microcrystalline silicon thin films were produced by R.F. magnetron sputtering. The microstructure of these films has been studied by X-ray diffraction, transmission electron microscopy (TEM) and Raman spectroscopy. Average values of crystalline size and strain obtained by the different tecnhiques used are critically compared and the reasons for the differences are discussed

Corrosion of TiN, (TiAl)N and CrN hard coatings produced by magnetron sputtering

Metallic components like moulds, dies and machinery can be subjected to intensive degradation during plastic transformation processes, namely when working with fibre filler materials and plastics which release F, S or Cl during transformation. The degradation is attributed to the combined erosive and abrasive wear by the filler material and corrosive attack of agents. This degradation reduces the lifetime of the components considerably and has a direct impact on process productivity and surface finish of the final products. Nitride-based hard coatings like TiN, (TiAl)N, BN, etc. have proved their capability to increase tool lifetime when exposed to abrasive and corrosive environments found in plastic transformation processes halogenated polymers, acrylics, polyesters, fibre reinforced plastics, etc.. Within the frame of this work we produced TiN, (TiAl)N, CrN hard coatings, with and without a metallic interlayer, by dc and rf reactive magnetron sputtering, with a thickness of about 2 μm. The aqueous corrosion behaviour of the coatings was studied in saline and acidic environments by potentiodynamic and open circuit potential (OCP) measurements. The oxidation resistance during annealing in air was also studied. In saline NaCl 9% and acid HCl 3.4%environments we found that a metallic interlayer of Ti or Cr in the case of TiN– TiAl N-coated samples and CrN-coated samples, respectively, generally improve the corrosion resistance. Best results for all tested nitride coated samples were obtained for the Ti Al N coating. The OCP vs. Saturated Calomel Electrode (SCE) (60 min) measurements indicated that most samples were nobler than the un-coated substrate. The mentioned potentials depend on the deposition conditions and the film microstructure. Most of the coatings lose some of their protective capabilities after an high temperature annealing. In contrast to the Ti-based hard coatings, the corrosion resistance of CrN is improved by a 800ºC annealing treatment in air

Microcrystalline silicon thin films prepared by RF reactive magnetron sputter deposition

Hydrogenated microcrystalline silicon (microc-Si:H) thin films with Cu as a dopant material (about 2 wt.%) were deposited by RF planar magnetron sputtering in an argon/hydrogen plasma. The composition and microstructure of the films were analysed by SEM, ERD/RBS, X-ray diffraction and Raman spectroscopy. These techniques revealed a columnar film structure, each column consisting of several small (nano) crystals with a lateral dimension up to 10nm. The crystals are oriented, generally with the (111) plane parallel to the sample surface. The hydrogen content of the thin films is about 27-33 at.%. Low deposition rates and low sputter gas pressures favour crystallisation and grain growth. The behaviour can be understood in terms of the diffusion or relaxation length of the deposited Si-atoms

Safeguarding cork’s beauty and longevity: innovations in deposition of protective thin films

Cork is a sustainable natural material widely used as a wine stopper. However, some other uses, such as wall coverings, flooring, bags and shoes, face UV damage. To mitigate this issue, we explored the deposition of TiO2 and ZnO thin films via magnetron sputtering on glass and cork substrates. Both films displayed uniformity and the lack of any discernible cracks or voids, remained transparent in the visible region, and offered UV protection. Thus, TiO2 and ZnO blocked UV light with a wavelength of up to 310 nm (Eg = 4 eV) and 370 nm (Eg = 3.3 eV), respectively. Exposure tests, under a sun simulator lamp, revealed that the uncoated cork showed noticeable color changes, even when located under a glass substrate. The TiO2 coating did not prevent cork discoloration, while ZnO prevented it. This study highlights ZnO thin films as a durable solution to safeguard cork materials from UV damage and extend their usability.This research was funded by “the Portuguese Foundation for Science and Technology (FCT) in the framework of the project PTDC/CTM-REF/0155/2020

Optical characterization of TiAlN/TiAlON/SiO2 absorber for solar selective applications

Characterization of a TiAlN/TiAlON/SiO2 tandem absorber is reported in this contribution. The first two layers were deposited by magnetron sputtering and the third layer was prepared by plasma enhanced chemical vapour deposition (PECVD). The optimization was performed by determining the optical constants of individual layers by first measuring spectral transmittance and reflectance of the individual layers. Subsequently the measuring spectra were fitted using the SCOUT software and dielectric function of each layer was determined. The three layer stack absorber on copper was then designed using those optical properties. The thickness of the individual layers was optimized until a solar absorptance of 95.5% was obtained resulting in a total thickness of about 215 nm (65 nm/51 nm/100 nm for the individual layers, respectively). A thermal emittance of 5% for an absorber temperature of 100 °C was obtained by analyzing the measuring data from a FTIR spectrometer with integrating sphere. During continuous thermal annealing at 278 °C for 600 h the absorptance decreased by 0.4%Savo Sola

Characterization of TiAlSiN/TiAlSiON/SiO2 optical stack designed by modelling calculations for solar selective applications

Preparation and characterization of TiAlSiN/TiAlSiON/SiO2 solar selective absorber is reported in this contribution. All layers were deposited in a continuous mode using a industrial equipment, the nitride and oxynitride were prepared by reactive magnetron sputtering and the SiO2 layer by Plasma Enhanced Chemical Vapour Deposition. The optical constants of individual layers were calculated by modelling of spectral transmittance and reflectance of the individual layers. The three layer stack absorber was then designed using those optical properties. The thickness of the individual layers was optimized until a solar absorptance of 96% was obtained resulting in a total thickness of about 200 nm, deposited in copper and extruded aluminium absorbers. An emissivity of 5 % for an absorber temperature of 100 ºC was obtained by analyzing the measuring data from a FTIR spectrometer with integrating sphere. After test duration of 600 h, the samples subjected to a thermal annealing at 278 ºC in air showed a performance criterion (PC) below 4% for, while the samples in the humidity tests showed a PC below 2 %.Savo Sola

Application of composite coatings as protection/contacting layers for metallic highchromium- content SOFC interconnect material

Oxidation of the surface of metallic chromium oxide forming metallic interconnect (MIC) can cause up to one third of the total SOFC stack degradation during the long-time operation at elevated (750 - 850 °C) temperatures. The application of protective coatings is the most effective method not only for reduction of the growth of oxide scales but also for prevention of evaporation of Cr-containing species from MIC and of the poisoning of the air electrode. Two approaches to form the protective layers on the surface of CFY interconnect material with high chromium content (~ 94 %) have been tested. The CuNiMn-spinel (CNM) coatings were deposited using the wet powder spraying (WPS) of the slurries. As an alternative approach physical vapour deposition (PVD) method was used to apply thin metallic films on the surface of MIC and to form the protection layer by in-situ oxidation under the stack relevant conditions. The experiments were carried out at first using the model samples of different geometries to evaluate the properies and efficiency of the coatings. Composite pastes with addition of perovskite powders were also tested, because the CNM layers densify at SOFC operating conditions and shrinkage during long-term operation can cause the decrease of the contact area between the components and accelerate the degradation of the stack performance. The experiments have shown that the perovskite additive can efficiently reduce the shrinkage compared to the pure CNM material and match it well to the shrikage of other stack components. Moreover, the perovskite additive do not deteriorate the electrical properties of the composite since the perovskites have electrical conductivity comparable to CNM. The PVD coatings were tested in combination with CNM containing contacting layers applied by screen printing to reduce the chromium release rate. The experiments have shown a good compatibility and mechanical stability between the contacting layer and PVD protective coating during operation and thermal cycling. The materials and composites have been characterized by scanning electron microscopy (SEM/EDX), optical dilatometry and electrical conductivity measurements. Finally, the most promising material combinations obtained for model samples were transferred to SOFC stacks MK35x and evaluated under real operation condition.Federal Ministry for Economic Affairs and Energy (BMWi) for funding of these researches (support code 03ET6120A)

Solar selective absorbers based on Al2O3:W cermets and AlSiN/AlSiON layers

Solar selective coatings based on double Al2O3:W cermet layers and AlSiN/AlSiON bilayer structures were prepared by magnetron sputtering. Both were deposited on stainless steel substrates using a metallic tungsten (W) layer as back reflector. The coating stacks were completed by an antireflection (AR) layer composed of Al2O3, SiO2, or AlSiOx. Spectrophotometer measurements, X-Ray diffraction, Scanning electron microscopy, Energy Dispersive X-Ray Spectroscopy and Rutherford Backscattering Spectrometry were used to characterize the optical properties, crystalline structure, morphology and composition of these coatings. The spectral optical constants of the single layers were calculated from the reflectance and transmittance measurements and used to design the optical stack. The coatings exhibit a solar absorptance of 93%-95% and an emissivity of 7%-10% (at 400 ºC). The coatings also exhibit excellent thermal stability, with small changes in the optical properties of the coating during heat-treatments at 400 ºC in air for 2500 h and at 580 ºC in vacuum for 850 h. The coating based on the AlSiN/AlSiON bilayer structure was obtained with an Al:Si ratio of 2.5:1. These coatings revealed similar performance as the one obtained with coatings based on Al2O3:W cermet layers.The authors acknowledge the funding from the Finnish Funding Agency for Technology and Innovation, Tekes, and from FEDER funds through the “Programa Operacional Factores de Competitividade – COMPETE” and from national funds by FCT- “Fundação para a Ciência e a Tecnologia”, under project no. PEst-C/FIS/UI0607/2011.info:eu-repo/semantics/publishedVersio