Structural phase transitions and their influence on Cu+ mobility in superionic ferroelastic Cu6PS5I single crystals

The structural origin of Cu+ ions conductivity in Cu6PS5I single crystals is described in terms of structural phase transitions studied by X-ray diffraction, polarizing microscope and calorimetric measurements. Below the phase transition at Tc=(144-169) K Cu6PS5I belongs to monoclinic, ferroelastic phase, space group Cc. Above Tc crystal changes the symmetry to cubic superstructure, space group F-43c (a=19.528); finally at 274K disordering of the Cu+ ions increases the symmetry to F-43m, (a=9.794). The phase transition at 274K coincides well with a strong anomaly in electrical conductivity observed in the Arrhenius plot. Diffusion paths for Cu+ ions are evidenced by means of the atomic displacement factors and split model. Influence of the copper stechiometry on the Tc is also discussed.Comment: conference pape

On the Asymptotic Sum Rate of Downlink Cellular Systems With Random User Locations.

We consider a downlink cellular communication system with a multi-antenna base station (BS). A regularized zero forcing precoder is employed at the BS to manage the inter-user interference within the cell. Using methods from random matrix theory, we derive a deterministic approximation for the achievable ergodic sum rate, taking into account the randomness from both fading and random user locations. The obtained approximation describes well the behavior of finite-sized systems and enables efficient optimization of the precoder matrix