119 research outputs found
Heterogeneous spin state in the field-induced phase of volborthite as seen via 51V nuclear magnetic resonance
We report results of 51V NMR in the field-induced phase of volborthite
Cu3V2O7(OH)dot2H2O, a spin-1/2 antiferromagnet on a distorted kagome lattice.
In magnetic fields above 4.5 T, two types of V sites with different spin-echo
decay rates are observed. The hyperfine field at the fast decaying sites has a
distribution, while it is more homogeneous at the slowly decaying sites. Our
results indicate a heterogeneous state consisting of two spatially alternating
Cu spin systems, one of which exhibits anomalous spin fluctuations contrasting
with the other showing a conventional static order.Comment: 5 pages, 4 figure
Spin-1/2 Triangular Lattice with Orbital Degeneracy in a Metallic Oxide Ag2NiO2
A novel metallic and magnetic transition metal oxide Ag2NiO2 is studied by
means of resistivity, magnetic susceptibility, specific heat and X-ray
diffraction. The crystal structure is characterized by alternating stacking of
a Ni3+O2 layer and a (Ag2)+ layer, the former realizing a spin-1/2 triangular
lattice with eg orbital degeneracy and the latter providing itinerant
electrons. It is found that the NiO2 layer exhibits orbital ordering at Ts =
260 K and antiferromagnetic spin ordering at TN = 56 K. Moreover, a moderately
large mass enhancement is found for the itinerant electrons, suggesting a
significant contribution from the nearly localized Ni 3d state to the Ag 5s
state that forms a broad band.Comment: 9 pages, 5 figures, to be published in Rapid Communications, Phys.
Rev.
Phase Diagram and Spin Dynamics in Volborthite with a Distorted Kagome Lattice
We report 51V-NMR study on a high-quality powder sample of volborthite
Cu3V2O7(OH)2/2H2O, a spin-1/2 Heisenberg antiferromagnet on a distorted kagome
lattice formed by isosceles triangles. In the magnetic fields below 4.5 T, a
sharp peak in the nuclear spin-lattice relaxation rate 1/T1 accompanied with
line broadening revealed a magnetic transition near 1 K. The low temperature
phase shows anomalies such as a Lorentzian line shape, a 1/T1 propto T behavior
indicating dense low energy excitations, and a large spin-echo decay rate 1/T2
pointing to unusually slow fluctuations. Another magnetic phase appears above
4.5 T with less anomalous spectral shape and dynamics.Comment: 4 pages, 4 figure
NMR Observation of Rattling Phonons in the Pyrochlore Superconductor KOs2O6
We report nuclear magnetic resonance studies on the beta-pyrochlore oxide
superconductor KOs2O6. The nuclear relaxation at the K sites is entirely caused
by fluctuations of electric field gradient, which we ascribe to highly
anharmonic low frequency oscillation (rattling) of K ions. A phenomenological
analysis shows a crossover from overdamped to underdamped behavior of the
rattling phonons with decreasing temperature and its sudden sharpening below
the superconducting transition temperature Tc. Absence of the Hebel-Slichter
peak in the relaxation rate at the O sites below Tc also indicates strong
electron-phonon coupling.Comment: 4 pages, 3 figure
A Possible Phase Transition in beta-pyrochlore Compounds
We investigate a lattice of interacting anharmonic oscillators by using a
mean field theory and exact diagonalization. We construct an effective
five-state hopping model with intersite repulsions as a model for
beta-pyrochlore AOs_2O_6(A=K, Rb or Cs). We obtain the first order phase
transition line from large to small oscillation amplitude phases as temperature
decreases. We also discuss the possibility of a phase with local electric
polarizations. Our theory can explain the origin of the mysterious first order
transition in KOs_2O_6.Comment: 4 pages, 4 figures, submitted to J. Phys. Soc. Jp
Vesignieite BaCu3V2O8(OH)2 as a Candidate Spin-1/2 Kagome Antiferromagnet
A polycrystalline sample of vesignieite BaCu3V2O8(OH)2 comprising a nearly
ideal kagome lattice composed of Cu2+ ions carrying spin 1/2 has been
synthesized and studied by magnetization and heat capacity measurements.
Magnetic susceptibility shows a neither long range order, a spin glass
transition nor a spin gap down to 2 K, in spite of a moderately strong
antiferromagnetic interaction of J/kB = 53 K between nearest-neighbor spins. A
broad peak observed at a temperature corresponding to 0.4J in intrinsic
magnetic susceptibility indicates a marked development of the short-range
order. The ground state of vesignieite is probably a gapless spin liquid or is
accompanied by a very small gap less than J/30.Comment: 4 pages, 5 figure
Green's function of fully anharmonic lattice vibration
Motivated by the discovery of superconductivity in beta-pyrochlore oxides, we
study property of rattling motion coupled with conduction electrons. We derive
the general expression of the Green's function of fully anharmonic lattice
vibration within the accuracy of the second order perturbation of electron-ion
interaction by introducing self-energy, vertex-correction, and normalization
factor for each transition. Using the expression, we discuss the characteristic
properties of the spectral function in the entire range from weakly anharmonic
potential to double-well case, and calculate NMR relaxation rate due to the two
phonon Raman process
Phonon Dynamics and Multipolar Isomorphic Transition in beta-pyrochlore KOs2O6
We investigate with a microscopic model anharmonic K-cation oscillation
observed by neutron experiments in beta-pyrochlore superconductor KOs2O6, which
also shows a mysterious first-order structural transition at Tp=7.5 K. We have
identified a set of microscopic model parameters that successfully reproduce
the observed temperature dependence and the superconducting transition
temperature. Considering changes in the parameters at Tp, we can explain
puzzling experimental results about electron-phonon coupling and neutron data.
Our analysis demonstrates that the first-order transition is multipolar
transition driven by the octupolar component of K-cation oscillations. The
octupole moment does not change the symmetry and is characteristic to
noncentrosymmetric K-cation potential.Comment: 5 pages, 4 figures, submitted to J. Phys. Soc. Jp
Spin-1/2 kagome compounds: volborthite vs herbertsmithite
Two kagome compounds, volborthite Cu3V2O7(OH)2-2H2O and herbertsmithite
ZnCu3(OH)6Cl2, are compared in order to derive information about the intrinsic
properties of the spin-1/2 kagome antiferromagnet. Volborthite shows a broad
maximum at T ~ J / 4 and the approach at T = 0 to a large finite value of the
bulk magnetic susceptibility chi_bulk as well as the local susceptibility
chi_local from NMR measurements. These must be intrinsic properties for the
spin-1/2 kagome antiferromagnet, as similar behavior has also been reported in
chi_local for herbertsmithite [Olariu A et al. 2008 Phys. Rev. Lett., 100
087202]. Impurity effects that may significantly influence the bulk properties
are discussed.Comment: 8 pages, to be published in J. Phys.: Conf. Series; Proc. of HFM200
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