Dynamical and quasistatic structural relaxation paths in Pd_(40)Ni_(40)P_(20) glass

By sequential heat treatment of a Pd_(40)Ni_(40)P_(20) metallic glass at temperatures and durations for which α-relaxation is not possible, dynamic, and quasistatic relaxation paths below the glass transition are identified via ex situ ultrasonic measurements following each heat treatment. The dynamic relaxation paths are associated with hopping between nonequilibrium potential energy states of the glass, while the quasistatic relaxation path is associated with reversible β-relaxation events toward quasiequilibrium states. These quasiequilibrium states are identified with secondary potential energy minima that exist within the inherent energy minimum of the glass, thereby supporting the concept of the sub-basin/metabasin organization of the potential-energy landscape

Amorphous thin film growth: theory compared with experiment

Experimental results on amorphous ZrAlCu thin film growth and the dynamics of the surface morphology as predicted from a minimal nonlinear stochastic deposition equation are analysed and compared. Key points of this study are (i) an estimation procedure for coefficients entering into the growth equation and (ii) a detailed analysis and interpretation of the time evolution of the correlation length and the surface roughness. The results corroborate the usefulness of the deposition equation as a tool for studying amorphous growth processes.Comment: 7 pages including 5 figure

Fundamental Link between β Relaxation, Excess Wings, and Cage-Breaking in Metallic Glasses

In glassy materials, the Johari–Goldstein secondary (β) relaxation is crucial to many properties as it is directly related to local atomic motions. However, a long-standing puzzle remains elusive: why some glasses exhibit β relaxations as pronounced peaks while others present as unobvious excess wings? Using microsecond atomistic simulation of two model metallic glasses (MGs), we demonstrate that such a difference is associated with the number of string-like collective atomic jumps. Relative to that of excess wings, we find that MGs having pronounced β relaxations contain larger numbers of such jumps. Structurally, they are promoted by the higher tendency of cage-breaking events of their neighbors. Our results provide atomistic insights for different signatures of the β relaxation that could be helpful for understanding the low-temperature dynamics and properties of MGs