Metal-to-insulator transition in anatase TiO2 thin films induced by growth rate modulation

We demonstrate control of the carrier density of single phase anatase TiO2 thin films by nearly two orders of magnitude by modulating the growth kinetics during pulsed laser deposition, under fixed thermodynamic conditions. The resistivity and the intensity of the photoluminescence spectra of these TiO2 samples, both of which correlate with the number of oxygen vacancies, are shown to depend strongly on the growth rate. A quantitative model is used to explain the carrier density changes.Comment: 13 pages 3 figure

Self-Energy Effects on the Low- to High-Energy Electronic Structure of SrVO3

The correlated electronic structure of SrVO3 has been investigated by angle-resolved photoemission spectroscopy using in-situ prepared thin films. Pronounced features of band renormalization have been observed: a sharp kink ~60 meV below the Fermi level (EF) and a broad so-called "high-energy kink" ~0.3 eV below EF as in the high-Tc cuprates although SrVO3 does not show magnetic fluctuations. We have deduced the self-energy in a wide energy range by applying the Kramers-Kronig relation to the observed spectra. The obtained self-energy clearly shows a large energy scale of ~0.7 eV which is attributed to electron-electron interaction and gives rise to the ~0.3 eV "kink" in the band dispersion as well as the incoherent peak ~1.5eV below EF. The present analysis enables us to obtain consistent picture both for the incoherent spectra and the band renormalization.Comment: 5 pages, 3 figure

Anisotropic spin-density distribution and magnetic anisotropy of strained La1−x_{1-x}Srx_xMnO3_3 thin films: Angle-dependent x-ray magnetic circular dichroism

Magnetic anisotropies of ferromagnetic thin films are induced by epitaxial strain from the substrate via strain-induced anisotropy in the orbital magnetic moment and that in the spatial distribution of spin-polarized electrons. However, the preferential orbital occupation in ferromagnetic metallic La$_{1-x}$Sr$_x$MnO$_3$ (LSMO) thin films studied by x-ray linear dichroism (XLD) has always been found out-of-plane for both tensile and compressive epitaxial strain and hence irrespective of the magnetic anisotropy. In order to resolve this mystery, we directly probed the preferential orbital occupation of spin-polarized electrons in LSMO thin films under strain by angle-dependent x-ray magnetic circular dichroism (XMCD). Anisotropy of the spin-density distribution was found to be in-plane for the tensile strain and out-of-plane for the compressive strain, consistent with the observed magnetic anisotropy. The ubiquitous out-of-plane preferential orbital occupation seen by XLD is attributed to the occupation of both spin-up and spin-down out-of-plane orbitals in the surface magnetic dead layer.Comment: 20 pages, 4 figure

Avaliação de critérios para desleitamento de bezerras leiteiras

O objetivo deste trabalho foi avaliar critérios para tomada de decisão de quando realizar o desaleitamento de bezerras leiteiras. Em experimento com delineamento de blocos ao acaso, 15 fêmeas holandesas recémnascidas foram alocadas a um dos 3 critérios de desaleitamento: consumo de concentrado de 700 g/dia durante 3 dias consecutivos; consumo de concentrado equivalente a 1,5% de seu peso ao nascer (PN) durante 3 dias consecutivos; oito semanas de vida. Os animais foram alimentados com 4 L de leite/dia até a data do desaleitamento, concentrado ad libitum até o consumo de 2 kg/d, além de água a vontade. O consumo diário de concentrado e o desempenho animal foram monitorados até 12 semanas de vida. Animais desaleitados segundo o consumo em % do PN apresentaram maior consumo de concentrado e de matéria seca durante todo o período, entretanto não houveram diferenças no ganho de peso vivo dos animais. O desaleitamento de acordo com o consumo equivalente a 1,5% do PN possibilitou uma redução de 10 dias no período de aleitamento sem afetar o desempenho animal, aumentando o custo com concentrado, sem alterar o custo total de alimentação. Os três critérios para tomada de decisão para realizar o desaleitamento podem ser utilizados sem prejuízo ao desempenho animal, sendo que a adoção de um ou de outro critério depende mais de facilidade de manejo dos animais

Built-in and induced polarization across LaAlO3_3/SrTiO3_3 heterojunctions

Ionic crystals terminated at oppositely charged polar surfaces are inherently unstable and expected to undergo surface reconstructions to maintain electrostatic stability. Essentially, an electric field that arises between oppositely charged atomic planes gives rise to a built-in potential that diverges with thickness. In ultra thin film form however the polar crystals are expected to remain stable without necessitating surface reconstructions, yet the built-in potential has eluded observation. Here we present evidence of a built-in potential across polar \lao ~thin films grown on \sto ~substrates, a system well known for the electron gas that forms at the interface. By performing electron tunneling measurements between the electron gas and a metallic gate on \lao ~we measure a built-in electric field across \lao ~of 93 meV/\AA. Additionally, capacitance measurements reveal the presence of an induced dipole moment near the interface in \sto, illuminating a unique property of \sto ~substrates. We forsee use of the ionic built-in potential as an additional tuning parameter in both existing and novel device architectures, especially as atomic control of oxide interfaces gains widespread momentum.Comment: 6 pages, 4 figures. Submitted to Nature physics on May 1st, 201