A comprehensive assessment of potential hazard caused by organic compounds in biochar for agricultural use

Great attention has been paid to using biochar as soil conditioner and bio-accumulator. Nevertheless, biochar application in agriculture might cause a potential hazard to ecosystems, considering that toxic organic pollutants present in biochar may enter the environment. European Biochar Certificate (EBC) set certain criteria for biochar production. Achieving the EBC established values of the molar ratio of H/Corg 0.1, inhibition of Sinapis alba <30% was observed with OC/EC < 0.02. To achieve Sinapis alba inhibition <20%, these parameters should be met: volatile matter (VM) <30%; concentration of OC < 4%; aromaticity ratio AL/AR < 0.35

Environmental risks related to organic compounds from the combustion of paper briquettes in domestic boilers

Environmental risks connected with the combustion of paper/cardboard briquettes are still not sufficiently known. This paper aims to bring attention to the risks related to the utilisation of paper briquettes in local boilers and to characterise these risks by means of the identification of organic compounds in deposits from exhaust flues. The identification of the chemical compounds was performed by pyrolysis gas chromatography with mass spectrometric detection. Paper/cardboard briquettes contain 119 compounds of biogenic origin derived from major biomass components and 53 additives. Additives are used both for improving the properties of paper and in printing inks. By burning the paper briquettes, the same 53 compounds from the additive group were caught in the deposits from the flue gas pathway, occurring in the range of 1–10% of the concentration of individual compounds (additives) contained in the input fuel. Compounds that are very stable during the combustion process have an enrichment factor (EF) > 30, which corresponded to approximately 3% of the additive capture in deposits. The highest values were found for plasticisers (phthalates). Many of the primary organic compounds contained in the input raw material do not decompose during combustion and can have adverse effects on human health