Importance of Acid–Base Equilibrium in Electrocatalytic Oxidation of Formic Acid on Platinum

This work was supported by Japanese Society for the Promotion of Science (JSPS) KAKENHI Grants Nos. 24550143 and 24750117 and MEXT Project of Integrated Research on Chemical Synthesis. M.T.M.K. gratefully acknowledges the award of Long-Term Fellowship of JSPS (No. L-11527) and Visiting Professorship of Hokkaido University. T.U. acknowledges Grants-in-Aid for Regional R&D Proposal-Based Program from Northern Advancement Center for Science & Technology of Hokkaido, Japan. J.J. acknowledges scholarship of Asian Graduate School, Hokkaido University.Peer reviewedPostprin

Learning Design: reflections on a snapshot of the current landscape

The mounting wealth of open and readily available information and the swift evolution of social, mobile and creative technologies warrant a re-conceptualisation of the role of educators: from providers of knowledge to designers of learning. This need is being addressed by a growing trend of research in Learning Design. Responding to this trend, the Art and Science of Learning Design workshop brought together leading voices in the field and provided a forum for discussing its key issues. It focused on three thematic axes: practices and methods, tools and resources, and theoretical frameworks. This paper reviews some definitions of Learning Design and then summarises the main contributions to the workshop. Drawing upon these, we identify three key challenges for Learning Design that suggest directions for future research

Aging dynamics of ferromagnetic and reentrant spin glass phases in stage-2 Cu0.80_{0.80}C0.20_{0.20}Cl2_{2} graphite intercalation compound

Aging dynamics of a reentrant ferromagnet stage-2 Cu$_{0.8}$Co$_{0.2}$Cl$_{2}$ graphite intercalation compound has been studied using DC magnetic susceptibility. This compound undergoes successive transitions at the transition temperatures $T_{c}$ ($\approx 8.7$ K) and $T_{RSG}$ ($\approx 3.3$ K). The relaxation rate $S_{ZFC}(t)$ exhibits a characteristic peak at $t_{cr}$ below $T_{c}$. The peak time $t_{cr}$ as a function of temperature $T$ shows a local maximum around 5.5 K, reflecting a frustrated nature of the ferromagnetic phase. It drastically increases with decreasing temperature below $T_{RSG}$. The spin configuration imprinted at the stop and wait process at a stop temperature $T_{s}$ ($<T_{c}$) during the field-cooled aging protocol, becomes frozen on further cooling. On reheating, the memory of the aging at $T_{s}$ is retrieved as an anomaly of the thermoremnant magnetization at $T_{s}$. These results indicate the occurrence of the aging phenomena in the ferromagnetic phase ($T_{RSG}<T<T_{c}$) as well as in the reentrant spin glass phase ($T<T_{RSG}$).Comment: 9 pages, 9 figures; submitted to Physical Review

Clinical supervision in the alcohol and other drugs sector as conducted by external supervisors under a social work framework: is it effective?

In this thesis, I explore the impact and effectiveness of clinical supervision provided by external clinical supervisors, on workers from a variety of practice backgrounds in a residential rehabilitation centre, in the AOD sector. This thesis uses the framework of social work supervision, as defined by Kadushin (1985; 2002), with the administrative, educative and supportive elements. The research focuses closely on the latter two elements. For this purpose, I employ qualitative research methods, via a triangulation of methods, being guided by Participatory Action Research (PAR) and then conducting semi-structured interviews and focus groups as well as acting as a participant observer, to gather the data. The data was analysed using grounded theory. This research was based upon a clinical supervision project that was fully funded and provided free clinical supervision by external supervisors, providing both individual and group supervision, for a period of 10 months. There were a total of 16 respondents with varied roles and training backgrounds as well as an additional six supervisors, interviewed throughout different stages of the project. The various roles undertaken by me throughout the research process provided essential viewpoints on supervision, as well as the place of boundaries and need for support. The power of such a large scale intervention is discussed and ultimately highlights and identifies the particular benefits of supervision in this research arena. This thesis places clinical supervision in the context of workforce development in the Alcohol and Other Drug (AOD) sector. Thus, while this research elucidates a number of benefits and the factors involved with this experience, the clear separation of other modalities such as training, mentoring and Critical Incident debriefing are seen as integral additional avenues of support and professional development. This research concludes also with what the difficulties and hindrances were for people to continue with regular ongoing clinical supervision, and warrants the argument for interminable supervision in this setting. This research points to an overall paucity of literature on efficacy studies, especially in the AOD context in Australia. This research significantly adds to this dearth and examines the factors unique to the AOD sector in Australia, as well as what factors make for effective supervision. The particular impact of external supervisors and group supervision are explored, which underwrites the forwarded concept of a customised supervision for this setting. By making explicit in this research what the efficacy is on those new to supervision, it provides greater clarity for future studies. A number of recommendations are proposed as result of this research. New definitions of the supportive function of supervision and of clinical supervision are forwarded, as is a new look at the evolving history of social work supervision. This thesis highlights the impact of external supervisors and the unique contribution they offer

Depth-varying rupture properties of subduction zone megathrust faults

Subduction zone plate boundary megathrust faults accommodate relative plate motions with spatially varying sliding behavior. The 2004 Sumatra-Andaman (M_w 9.2), 2010 Chile (Mw 8.8), and 2011 Tohoku (M_w 9.0) great earthquakes had similar depth variations in seismic wave radiation across their wide rupture zones – coherent teleseismic short-period radiation preferentially emanated from the deeper portion of the megathrusts whereas the largest fault displacements occurred at shallower depths but produced relatively little coherent short-period radiation. We represent these and other depth-varying seismic characteristics with four distinct failure domains extending along the megathrust from the trench to the downdip edge of the seismogenic zone. We designate the portion of the megathrust less than 15 km below the ocean surface as domain A, the region of tsunami earthquakes. From 15 to ∼35 km deep, large earthquake displacements occur over large-scale regions with only modest coherent short-period radiation, in what we designate as domain B. Rupture of smaller isolated megathrust patches dominate in domain C, which extends from ∼35 to 55 km deep. These isolated patches produce bursts of coherent short-period energy both in great ruptures and in smaller, sometimes repeating, moderate-size events. For the 2011 Tohoku earthquake, the sites of coherent teleseismic short-period radiation are close to areas where local strong ground motions originated. Domain D, found at depths of 30–45 km in subduction zones where relatively young oceanic lithosphere is being underthrust with shallow plate dip, is represented by the occurrence of low-frequency earthquakes, seismic tremor, and slow slip events in a transition zone to stable sliding or ductile flow below the seismogenic zone

Landing and catalytic characterization of individual nanoparticles on electrode surfaces

We demonstrate a novel and versatile pipet-based approach to study the landing of individual nanoparticles (NPs) on various electrode materials without any need for encapsulation or fabrication of complex substrate electrode structures, providing great flexibility with respect to electrode materials. Because of the small electrode area defined by the pipet dimensions, the background current is low, allowing for the detection of minute current signals with good time resolution. This approach was used to characterize the potential-dependent activity of Au NPs and to measure the catalytic activity of a single NP on a TEM grid, combining electrochemical and physical characterization at the single NP level for the first time. Such measurements open up the possibility of studying the relation between the size, structure and activity of catalyst particles unambiguously

Aging dynamics in reentrant ferromagnet: Cu0.2_{0.2}Co0.8_{0.8}Cl2_{2}-FeCl3_{3} graphite bi-intercalation compound

Aging dynamics of a reentrant ferromagnet Cu$_{0.2}$Co$_{0.8}$Cl$_{2}$-FeCl$_{3}$ graphite bi-intercalation compound has been studied using AC and DC magnetic susceptibility. This compound undergoes successive transitions at the transition temperatures $T_{c}$ ($= 9.7$ K) and $T_{RSG}$ ($= 3.5$ K). The relaxation rate $S(t)$ exhibits a characteristic peak at $t_{cr}$ close to a wait time $t_{w}$ below $T_{c}$, indicating that the aging phenomena occur in both the reentrant spin glass (RSG) phase below $T_{RSG}$ and the ferromagnetic (FM) phase between $T_{RSG}$ and $T_{c}$. The relaxation rate $S(t)$ ($=\text{d}\chi_{ZFC}(t)/\text{d}\ln t$) in the FM phase exhibits two peaks around $t_{w}$ and a time much shorter than $t_{w}$ under the positive $T$-shift aging, indicating a partial rejuvenation of domains. The aging state in the FM phase is fragile against a weak magnetic-field perturbation. The time ($t$) dependence of $\chi_{ZFC}(t)$ around $t \approx t_{cr}$ is well approximated by a stretched exponential relaxation: $\chi_{ZFC}(t) \approx \exp[-(t/\tau)^{1-n}]$. The exponent $n$ depends on $t_{w}$, $T$, and $H$. The relaxation time $\tau$ ($\approx t_{cr}$) exhibits a local maximum around 5 K, reflecting a chaotic nature of the FM phase. It drastically increases with decreasing temperature below $T_{RSG}$.Comment: 16 pages,16 figures, submitted to Physical Review