Atomic data for S II - Toward Better Diagnostics of Chemical Evolution in High-redshift Galaxies

Absorption-line spectroscopy is a powerful tool used to estimate element abundances in the nearby as well as distant universe. The accuracy of the abundances thus derived is, naturally, limited by the accuracy of the atomic data assumed for the spectral lines. We have recently started a project to perform the new extensive atomic data calculations used for optical/UV spectral lines in the plasma modeling code Cloudy using state-of-the-art quantal calculations. Here we demonstrate our approach by focussing on S II, an ion used to estimate metallicities for Milky Way interstellar clouds as well as distant damped Lyman-alpha (DLA) and sub-DLA absorber galaxies detected in the spectra of quasars and gamma-ray bursts (GRBs). We report new extensive calculations of a large number of energy levels of S II, and the line strengths of the resulting radiative transitions. Our calculations are based on the configuration interaction approach within a numerical Hartree-Fock framework, and utilize both non-ralativistic and quasirelativistic one-electron radial orbitals. The results of these new atomic calculations are then incorporated into Cloudy and applied to a lab plasma, and a typical DLA, for illustrative purposes. The new results imply relatively modest changes (~0.04 dex) to the metallicities estimated from S II in past studies. These results will be readily applicable to other studies of S II in the Milky Way and other galaxies.Comment: Accepted for publication in The Astrophysical Journal; 34 pages, 10 figure

Atomic data for Zn II - Improving Spectral Diagnostics of Chemical Evolution in High-redshift Galaxies

Damped Lyman-alpha (DLA) and sub-DLA absorbers in quasar spectra provide the most sensitive tools for measuring element abundances of distant galaxies. Estimation of abundances from absorption lines depends sensitively on the accuracy of the atomic data used. We have started a project to produce new atomic spectroscopic parameters for optical/UV spectral lines using state-of-the-art computer codes employing very broad configuration interaction basis. Here we report our results for Zn II, an ion used widely in studies of the interstellar medium (ISM) as well as DLA/sub-DLAs. We report new calculations of many energy levels of Zn II, and the line strengths of the resulting radiative transitions. Our calculations use the configuration interaction approach within a numerical Hartree-Fock framework. We use both non-relativistic and quasi-relativistic one-electron radial orbitals. We have incorporated the results of these atomic calculations into the plasma simulation code Cloudy, and applied them to a lab plasma and examples of a DLA and a sub-DLA. Our values of the Zn II {\lambda}{\lambda} 2026, 2062 oscillator strengths are higher than previous values by 0.10 dex. Cloudy calculations for representative absorbers with the revised Zn atomic data imply ionization corrections lower than calculated before by 0.05 dex. The new results imply Zn metallicities should be lower by 0.1 dex for DLAs and by 0.13-0.15 dex for sub-DLAs than in past studies. Our results can be applied to other studies of Zn II in the Galactic and extragalactic ISM.Comment: accepted The Astrophysical Journa

Atomic Data for Zn ɪɪ: Improving Spectral Diagnostics of Chemical Evolution in High-Redshift Galaxies

Damped Lyα (DLA) and sub-DLA absorbers in quasar spectra provide the most sensitive tools for measuring the element abundances of distant galaxies. The estimation of abundances from absorption lines depends sensitively on the accuracy of the atomic data used. We have started a project to produce new atomic spectroscopic parameters for optical and UV spectral lines using state-of-the-art computer codes employing a very broad configuration interaction (CI) basis. Here we report our results for Zn ii, an ion used widely in studies of the interstellar medium (ISM) as well as DLAs and sub-DLAs. We report new calculations of many energy levels of Zn ii and the line strengths of the resulting radiative transitions. Our calculations use the CI approach within a numerical Hartree–Fock framework. We use both nonrelativistic and quasi-relativistic one-electron radial orbitals. We have incorporated the results of these atomic calculations into the plasma simulation code Cloudy and applied them to a lab plasma and examples of a DLA and a sub-DLA. Our values of the Zn ii 2026, 2062 oscillator strengths are higher than previous values by 0.10 dex. The Cloudy calculations for representative absorbers with the revised Zn atomic data imply ionization corrections lower than calculated earlier by 0.05 dex. The new results imply that Zn metallicities should be lower by 0.1 dex for DLAs and by 0.13–0.15 dex for sub-DLAs than in past studies. Our results can be applied to other studies of Zn ii in the Galactic and extragalactic ISM

Radiative Cooling in Collisionally Ionized and Photoionized Plasmas

We discuss recent improvements in the calculation of the radiative cooling in both collisionally ionized and photoionized plasmas. We are extending the spectral simulation code CLOUDY so that as much as possible of the underlying atomic data are taken from external data bases, some created by others and some developed by the CLOUDY team. This paper focuses on recent changes in the treatment of many stages of ionization of iron, and discusses its extensions to other elements. The H- and He-like ions are treated in the isoelectronic approach described previously. Fe II is a special case treated with a large model atom. Here we focus on Fe III through Fe XXIV, ions which are important contributors to the radiative cooling of hot (T ∼ 105–107 K) plasmas and for X-ray spectroscopy. We use the Chianti atomic data base to greatly expand the number of transitions in the cooling function. Chianti only includes lines that have atomic data computed by sophisticated methods. This limits the line list to lower excitation, longer wavelength, transitions. We had previously included lines from the Opacity Project data base, which tends to include higher energy, shorter wavelength, transitions. These were combined with various forms of the ‘g-bar’ approximation, a highly approximate method of estimating collision rates. For several iron ions the two data bases are almost entirely complementary. We adopt a hybrid approach in which we use Chianti where possible, supplemented by lines from the Opacity Project for shorter wavelength transitions. The total cooling including the lightest 30 elements differs from some previous calculations by significant amounts

Stout: Cloudy\u27s Atomic and Molecular Database

We describe a new atomic and molecular database we developed for use in the spectral synthesis code Cloudy. The design of Stout is driven by the data needs of Cloudy, which simulates molecular, atomic, and ionized gas with kinetic temperatures 2.8 K \u3c T \u3c1010 K and densities spanning the low-to high-density limits. The radiation field between photon energies 10−8 Ry and 100 MeV is considered, along with all atoms and ions of the lightest 30 elements, and ~102 molecules. For ease of maintenance, the data are stored in a format as close as possible to the original data sources. Few data sources include the full range of data we need. We describe how we fill in the gaps in the data or extrapolate rates beyond their tabulated range. We tabulate data sources both for the atomic spectroscopic parameters and for collision data for the next release of Cloudy. This is not intended as a review of the current status of atomic data, but rather a description of the features of the database which we will build upon

Implications of Coronal Line Emission in NGC 4696*

We announce a new facility in the spectral code cloudy that enables tracking the evolution of a cooling parcel of gas with time. For gas cooling from temperatures relevant to galaxy clusters, earlier calculations estimated the [Fe xiv] λ5303/[Fe x] λ6375 luminosity ratio, a critical diagnostic of a cooling plasma, to slightly less than unity. By contrast, our calculations predict a ratio of ∼3. We revisit recent optical coronal line observations along the X-ray cool arc around NGC 4696 by Canning et al., which detected [Fe x] λ6375, but not [Fe xiv] λ5303. We show that these observations are not consistent with predictions of cooling flow models. Differential extinction could in principle account for the observations, but it requires extinction levels (AV \u3e 3.625) incompatible with previous observations. The non-detection of [Fe xiv] implies a temperature ceiling of 2.1 million K. Assuming cylindrical geometry and transonic turbulent pressure support, we estimate the gas mass at ∼1 million M⊙. The coronal gas is cooling isochorically. We propose that the coronal gas has not condensed out of the intracluster medium, but instead is the conductive or mixing interface between the X-ray plume and the optical filaments. We present a number of emission lines that may be pursued to test this hypothesis and constrain the amount of intermediate-temperature gas in the system

Radiative Cooling in Collisionally Ionized and Photoionized Plasmas

We discuss recent improvements in the calculation of the radiative cooling in both collisionally ionized and photoionized plasmas. We are extending the spectral simulation code CLOUDY so that as much as possible of the underlying atomic data are taken from external data bases, some created by others and some developed by the CLOUDY team. This paper focuses on recent changes in the treatment of many stages of ionization of iron, and discusses its extensions to other elements. The H- and He-like ions are treated in the isoelectronic approach described previously. Fe II is a special case treated with a large model atom. Here we focus on Fe III through Fe XXIV, ions which are important contributors to the radiative cooling of hot (T ∼ 105–107 K) plasmas and for X-ray spectroscopy. We use the Chianti atomic data base to greatly expand the number of transitions in the cooling function. Chianti only includes lines that have atomic data computed by sophisticated methods. This limits the line list to lower excitation, longer wavelength, transitions. We had previously included lines from the Opacity Project data base, which tends to include higher energy, shorter wavelength, transitions. These were combined with various forms of the ‘g-bar’ approximation, a highly approximate method of estimating collision rates. For several iron ions the two data bases are almost entirely complementary. We adopt a hybrid approach in which we use Chianti where possible, supplemented by lines from the Opacity Project for shorter wavelength transitions. The total cooling including the lightest 30 elements differs from some previous calculations by significant amounts

Hydrogen Two-Photon Continuum Emission from the Horseshoe Filament in NGC 1275

Far-ultraviolet emission has been detected from a knot of Hα emission in the Horseshoe filament, far out in the NGC 1275 nebula. The flux detected relative to the brightness of the Hα line in the same spatial region is very close to that expected from hydrogen two-photon continuum emission in the particle heating model of Ferland et al. if reddening internal to the filaments is taken into account. We find no need to invoke other sources of far-ultraviolet emission such as hot stars or emission lines from C IV in intermediate-temperature gas to explain these data