1-(4-Nitrobenzoyl)-3-(4-nitrophenyl)thiourea acetone hemisolvate

In the title compound, C14H10N4O5S·0.5C3H6O, the nitrobenzoyl and nitrophenyl groups have trans and cis configurations, respectively, with respect to the thiourea S atom. The molecular conformation is stabilized by intramolecular N—H...O and C—H...S hydrogen bonds. The acetone solvent molecule possesses a crystallographically imposed twofold axis. In the crystal packing, thiourea molecules are linked by intermolecular C—H...O hydrogen-bond interactions to form chains running parallel to the c axis. The chains are further bridged via N—H...O and C—H...O hydrogen bonds involving the acetone molecules

Monitoring of Discolored Trees Caused by Pine Wilt Disease Based on Unsupervised Learning with Decision Fusion Using UAV Images

Pine wilt disease (PWD) has caused severe damage to ecosystems worldwide. Monitoring PWD is urgent due to its rapid spread. Unsupervised methods are more suitable for the monitoring needs of PWD, as they have the advantages of being fast and not limited by samples. We propose an unsupervised method with decision fusion that combines adaptive threshold and Lab spatial clustering. The method avoids the sample problem, and fuses the strengths of different algorithms. First, the modified ExG-ExR index is proposed for adaptive threshold segmentation to obtain an initial result. Then, k-means and Fuzzy C-means in Lab color space are established for an iterative calculation to achieve two initial results. The final result is obtained from the three initial extraction results by the majority voting rule. Experimental results on unmanned aerial vehicle images in the Laoshan area of Qingdao show that this method has high accuracy and strong robustness, with the average accuracy and F1-score reaching 91.35% and 0.8373, respectively. The method can help provide helpful information for effective control and tactical management of PWD