Tetra­kis[μ-2-(3,4-dimeth­oxy­phen­yl)acetato]-κ3 O 1,O 1′:O 1;κ3 O 1:O 1,O 1′;κ4 O 1:O 1′-bis­{[2-(3,4-dimeth­oxy­phen­yl)acetato-κ2 O 1,O 1′](1,10-phenanthroline-κ2 N,N′)erbium(III)}

In the dimeric centrosymmetric title complex, [Er2(C10H11O4)6(C12H8N2)2], the ErIII ion is nine-coordinated by five 2-(3,4-dimeth­oxy­lphen­yl)acetic acid (DMPA) ligands via seven O atoms and two N atoms from a bis-chelating 1,10-phenanthroline (phen) ligand in a distorted tricapped trigonal-prismatic geometry. The DMPA ligands are coordinated to the ErIII ion in bis-chelate, bridging and bridging tridentate modes. Relatively weak intra­molecular C—H⋯O inter­actions reinforce the stability of the mol­ecular structure. Inter­molecular C—H⋯O inter­actions are also observed

Tetra­kis[μ-2-(3,4-dimeth­oxy­phen­yl)acetato]-κ4 O:O′;κ3 O,O′:O;κ3 O:O,O′-bis­{[2-(3,4-dimeth­oxy­phen­yl)acetato-κ2 O,O′](1,10-phenanthroline-κ2 N,N′)samarium(III)}

In the centrosymmetric dinuclear title complex, [Sm2(C10H11O4)6(C12H8N2)2], the SmIII ion is nine-coordinated by seven O atoms of five 2-(3,4-dimeth­oxy­phen­yl)acetate (DMPA) ligands and two N atoms of one bis-chelating 1,10-phenanthroline (phen) ligand, forming a distorted tricapped trigonal-prismatic environment. The DMPA ligands coordinate in bis-chelate, bridging and bridging tridentate modes. An intra­molecular C—H⋯O hydrogen bond occurs. Inter­molecular C—H⋯O inter­actions are also present in the crystal

Strong plasmonic confinement and optical force in phosphorene pairs

The plasmonic responses in the spatially separated phosphorene (single-layer black phosphorus) pairs are investigated, mainly containing the field enhancement, light confinement, and optical force. It is found that the strong anisotropic dispersion of black phosphorus gives rise to the direction-dependent symmetric and anti-symmetric plasmonic modes. Our results demonstrate that the symmetrical modes possess stronger field enhancement, higher light confinement, and larger optical force than the anti-symmetric modes in the nanoscale structures. Especially, the light confinement ratio and optical force for the symmetric mode along the armchair direction of black phosphorus can reach as high as >90% and >3000 pN/mW, respectively. These results may open a new door for the light manipulation at nanoscale and the design of black phosphorus based photonic devices

Non-Thermal X-ray Properties of Rotation Powered Pulsars and Their Wind Nebulae

We present a statistical study of the non-thermal X-ray emission of 27 young rotation powered pulsars (RPPs) and 24 pulsar wind nebulae (PWNe) by using the Chandra and the XMM-Newton observations, which with the high spatial resolutions enable us to spatially resolve pulsars from their surrounding PWNe. We obtain the X-ray luminosities and spectra separately for RPPs and PWNe, and then investigate their distribution and relation to each other as well as the relation with the pulsar rotational parameters. In the pair-correlation analysis we find that: (1) the X-ray (2-10 keV) luminosities of both pulsar and PWN (L_{psr} and L_{pwn}) display a strong correlation with pulsar spin down power Edot and characteristic age, and the scalings resulting from a simple linear fit to the data are L_{psr} \propto Edot^{0.92 \pm 0.04} and L_{pwn} \propto Edot^{1.45 \pm 0.08} (68% confidence level), respectively, however, both the fits are not statistically acceptable; (2) L_{psr} also shows a possible weak correlation with pulsar period P and period derivative Pdot, whereas L_{pwn} manifests a similar weak correlation with Pdot only; (3) The PWN photon index Gamma_{pwn} is positively correlated with L_{pwn} and L_{pwn}/Edot. We also found that the PWN X-ray luminosity is typically 1 to 10 times larger than that from the underlying pulsar, and the PWN photon indices span a range of ~1.5 to ~2. The statistic study of PWN spectral properties supports the particle wind model in which the X-ray emitting electrons are accelerated by the termination shock of the wind.Comment: 15 pages, 9 figures, 3 Tables, ApJ accepted version. Substantial revision, especially luminosity uncertainty taken into accounted and one fig added. Main conclusions unchange