High-pressure behavior of intermediate scapolite : compressibility, structure deformation and phase transition

Scapolites are common volatile-bearing minerals in metamorphic rocks. In this study, the high-pressure behavior of an intermediate member of the scapolite solid solution series (Me47), chemical formula (Na1.86Ca1.86K0.23Fe0.01)(Al4.36Si7.64)O24[Cl0.48(CO3)0.48(SO4)0.01], has been investigated up to 17.79 GPa, by means of in situ single-crystal synchrotron X-ray diffraction. The isothermal elastic behavior of the studied scapolite has been described by a III-order Birch\u2013Murnaghan equation of state, which provided the following refined parameters: V0 = 1110.6(7) \uc53, KV0 = 70(2) GPa (\u3b2V0 = 0.0143(4) GPa 121) and KV\u2032 = 4.8(7). The refined bulk modulus is intermediate between those previously reported for Me17 and Me68 scapolite samples, confirming that the bulk compressibility among the solid solution increases with the Na content. A discussion on the P-induced structure deformation mechanisms of tetragonal scapolite at the atomic scale is provided, along with the implications of the reported results for the modeling of scapolite stability. In addition, a single-crystal to single-crystal phase transition, which is displacive in character, has been observed toward a triclinic polymorph at 9.87 GPa. The high-pressure triclinic polymorph was found to be stable up to the highest pressure investigated

Analogue Gravity and ultrashort laser pulse filamentation

Ultrashort laser pulse filaments in dispersive nonlinear Kerr media induce a moving refractive index perturbation which modifies the space-time geometry as seen by co-propagating light rays. We study the analogue geometry induced by the filament and show that one of the most evident features of filamentation, namely conical emission, may be precisely reconstructed from the geodesics. We highlight the existence of favorable conditions for the study of analogue black hole kinematics and Hawking type radiation.Comment: 4 pages, revised versio

Establishing Multi-User MIMO Communications Automatically Using Retrodirective Arrays

Communications in the mmWave and THz bands will be a key technological pillar for next-generation wireless networks. However, the increase in frequency results in an increase in path loss, which must be compensated for by using large antenna arrays. This introduces challenging issues due to power consumption, signalling overhead for channel estimation, hardware complexity, and slow beamforming and beam alignment schemes, which are in contrast with the requirements of next-generation wireless networks. In this paper, we propose the adoption of a retro-directive antenna array (RAA) at the user equipment (UE) side, where the signal sent by the base station (BS) is reflected towards the source after being conjugated and phase-modulated according to the UE data. By making use of modified Power Methods for the computation of the eigenvectors of the resulting round-trip channel, it is shown that, in single and multi-user multiple-input multiple-output (MIMO) scenarios, ultra-low complexity UEs can establish parallel communication links automatically with the BS in a very short time. This is done in a blind way, also by tracking fast channel variations while communicating, without the need for ADC chains at the UE as well as without explicit channel estimation and time-consuming beamforming and beam alignment schemes

Understanding the social norms of cooling in Chinese offices: Predominance, professionalism, and peer respect

Challenging the international spread of highly energy-consuming air-conditioning technologies, this research explores how cooling demand is supported by the local emergence of relevant social norms. This paper presents the results of an interview study focused on the cooling norms currently found inside corporate offices in two large cities in southern China. Building on existing, mostly quantitative, studies of office cooling in areas of China with hot summers, and with a focus on how social norms shape everyday actions, the accounts of 17 financial sector workers are examined through a thematic analysis. Three themes are discussed: how air conditioning was perceived to dominate, how expectations concerning professional self-image were negotiated, and how respect for colleagues at different levels influenced personal cooling in the workplace. Together they point to the potential of novel strategies for promoting more sustainable office cooling in China and suggest the value of further research on dynamic cooling norms

High-pressure behavior of synthetic mordenite-Na: an in situ single-crystal synchrotron X-ray diffraction study

The high-pressure behavior of a synthetic mordenite- Na (space group: Cmcm or Cmc21) was studied by in situ single-crystal synchrotron X-ray diffraction with a diamond anvil cell up to 9.22(7) GPa. A phase transition, likely displacive in character, occurred between 1.68(7) and 2.70(8) GPa, from a C-centered to a primitive space group: possibly Pbnm, Pbnn or Pbn21. Fitting of the experimental data with III-BM equations of state allowed to describe the elastic behavior of the high-pressure polymorph with a primitive lattice. A very high volume compressibility [KV0 = 25(2) GPa, \u3b2V0 = 1/KV0 = 0.040(3) GPa\u20131; KV\u2032 = ( 02KV/ 02P)T = 2.0(3)], coupled with a remarkable elastic anisotropy (\u3b2b > > \u3b2c > \u3b2a), was found. Interestingly, the low-P and high-P polymorphs show the same anisotropic compressional scheme. A structure collapse was not observed up to 9.22(7) GPa, even though a strong decrease of the number of observed reflections at the highest pressures suggests an impending amorphization. The structure refinements performed at room-P, 0.98(2) and 1.68(7) GPa allowed to describe, at a first approximation, the mechanisms that govern the framework deformation in the low-P regime: the bulk compression is strongly accommodated by the increase of the ellipticity of the large 12-membered ring channels running along [001]

Poly(Alkylene 2,5-thiophenedicarboxylate) polyesters: A new class of bio-based high-performance polymers for sustainable packaging

In the present study, 100% bio-based polyesters of 2,5-thiophenedicarboxylic acid were synthesized via two-stage melt polycondensation using glycols containing 3 to 6 methylene groups. The so-prepared samples were characterised from the molecular point of view and processed into free-standing thin films. Afterward, both the purified powders and the films were subjected to structural and thermal characterisation. In the case of thin films, mechanical response and barrier properties to O2 and CO2 were also evaluated. From the results obtained, it emerged that the length of glycolic sub-units is an effective tool to modulate the chain mobility and, in turn, the kind and amount of ordered phases developed in the samples. In addition to the usual amorphous and 3D crystalline phases, in all the samples investigated it was possible to evidence a further phase characterised by a lower degree of order (mesophase) than the crystalline one, whose amount is strictly related to the glycol sub-unit length. The relative fraction of all these phases is responsible for the different mechanical and barrier performances. Last, but not least, a comparison between thiophene-based homopolymers and their furan-based homologues was carried out

Electrospun Membranes of Poly(butylene succinate) and Poly(butylene/2-butyl,2-ethyl-propylene succinate)

Poly(butylene succinate) (PBS) and poly(butylene/2-butyl,2-ethyl-propylene succinate) (PBSBEPS) membranes are prepared by electrospinning technique. In recent years, interest in biodegradable aliphatic polyesters, including PBS and its copolymers, is increasing as they have potential applications in various sectors such as mulching films, food packaging, tissue engineering, and drug delivery. In this work, the synthesized polymers are dissolved in different solvents, namely acetone, chloroform (CHCl3), methanol, dichloromethane (DCM), and dimethylformamide in order to obtain the best solvent system. These solutions are then electrospun at room temperature to produce micron-sized fibers. The variables examined in determining the optimal solution and electrospinning conditions are the solvent system used, the concentration of PBS and PBS-based random copolymer, applied voltage, flow rate, humidity, and the distance between the needle tip and the collector, all of which have a meaningful effect on the fiber morphology. Among the various solvents used, the DCM and the less toxic CHCl3 result in fewer bead defects among fibers. Besides, an increase in PBS and PBS-based random copolymer concentration determines the reduction of bead defects, which from 12 to 14 wt% results in bead-free uniform fibers, when suitable processing parameters are set. Promising results, which can pave the way for the production of membranes loaded with appropriate anticancer molecules for targeted biomedical applications, are obtained