295 research outputs found
Effect of Aminobenzene Concentrations on the Corrosion Inhibition of Mild Steel in Sulphuric Acid
The inhibiting action of aminobenzene concentration against the corrosion of mild steel in dilute sulphuric acid contaminated with 5% sodium chloride was studied using weight-loss method, calculated corrosion rates from the obtained weight loss data, potentiodynamic polarization measurements and metallographic macrographs. Results show aminobenzene has strong inhibitory effects with inhibitor efficiency increasing with increase in inhibitor concentration at ambient temperature. Maximum efficiency of 99.83% was obtained at 20% concentration of aminobenzene due to adhesion of the inhibitive precipitates through physisorption on the mild steel. This is further justified by the graphs of weight- loss and corrosion rate against exposure which illustrates the corrosion inhibition performance of the inhibitor. Results obtained from potentiodynamic experiments had good correlation with those of the gravimetric methods. The obtained macrographs could also be correlated with the gravimetric method dat
Effects of Nicotiana tobaccum extract additive on the quality of electroplating of zinc on mild steel.
Experimental investigations have been performed to determine the effects of nicotiana tobaccum (tobacco)
extract additive on the electrodeposition of zinc on mild steel in acid chloride solution. The
experiments were performed under different plating time, different additive concentrations and fi xed pH
conditions. Zinc electrodeposition on mild steel was performed using a DC â supply at defi ned operating
parameters. The surface of the plated steel was examined using scanning electron microscopy (SEM);
and Energy Dispersive Spectroscopy (EDS) for the surface elemental composition analysis. Different
surface characteristics were obtained depending upon the concentration of the additive and the plating
time. The corrosion resistance of the plated surface was also determined by a gravimetric method. The
quality of the electro-deposition of zinc was good as indicated by the microstructural morphology of the
plated surface except for the few porosities observed. The electrodeposition process was sensitive to the
changes in the additive concentration and plating time. Any variation in the plating parameter produced
an entirely new and different surface morphology
Effect of P-Phenylediamine on the Corrosion of Austenitic Stainless Steel Type 304 in Hydrochloric Acid
The effect of P-Phenylediamine on the corrosion behaviour of 304 stainless steel in 3M Hydrochloric acid solution contaminated with 3.5% sodium chloride was investigated using weight loss and potentiostatic polarization techniques. Corrosion parameters such as anodic and cathodic Tafel slope constants, corrosion potential, corrosion current, corrosion current densities, surface coverage and inhibition efficiency were calculated. The polarization measurements indicated that the inhibitors are of mixed type and inhibit corrosion by adsorption on the surface of steel due to the presence of more than one active centre in the inhibitor molecule. The inhibition effect ranged from 38.1% to 81.9% maximum at a concentration of between 0.125% to 1% before dropping sharply to between 9% and 4% at 1.25% to 1.5% concentration. The adsorption obeyed Langmuir adsorption isotherm up to 1% inhibitor concentration
Electrochemical studies of mild steel corrosion inhibition in sulfuric acid chloride by aniline
The corrosion behavior of mild steel in dilute hydrochloric acid under
the inhibiting action of various concentrations of aniline was studied using the
weight loss and linear polarization resistance technique. The efficiency of the
inhibitor increased with the increase in the inhibitor concentration. The results
obtained reveal that aniline performed effectively as a corrosion inhibitor. The
adsorption mechanism indicates mixed molecular interaction from values of Gibbs
free energy. The values of the inhibition efficiency calculated from the two tech-
niques are in reasonably good agreement. The adsorption of the inhibiting com-
pound was found to obey Langmuir, Frumkin and Freudlich adsorption isotherms.
The mechanism of inhibition was discussed in the light of the chemical structure of
the inhibiting compound and their adsorption on steel surfaces in relation to the
potentiodynamic parameters
Inhibition Effect of N, N'-Dimethylaminoethanol on the Corrosion of Austenitic Stainless Steel Type 304
The effect of N,N'-dimethylaminoethanol on the corrosion of austenitic stainless steel type 304 in 3M
H2SO4 has been studied by weight-loss method and linear polarization measurement in different
concentrations of the compound. The inhibition efficiencies of the inhibitor compound on the corrosion of
the stainless steel were evaluated through assessment of the anodic and cathodic polarization curves of
the alloy, the spontaneity of the electrochemical process, inhibition mechanism and adsorption isotherm.
The inhibitor efficiency increased with increase in the inhibitor concentration. Results obtained reveal that
the inhibitor performed effectively on the stainless steel providing good protection against pitting and
uniform corrosion in the chloride containing acidic solutions. The compound act through physiochemical
mechanism on the stainless steel surface and obeyed Langmuir adsorption isotherm. The values of the
inhibition efficiency calculated from the two techniques are in reasonably good agreement. Polarization
studies showed that the compounds behave as mixed type inhibitor in the aggressive media
Inhibition Effect of Extracts of Carica Papaya and Camellia Sinensis Leaves on the Corrosion of Duplex (α ÎČ) Brass in 1M Nitric Acid
The effect of C. Papaya (pawpaw) leaves and C. Sinensis (tea) extracts as an organic âgreenâ inhibitor on the corrosion of α ÎČ (duplex) brass (65-35% Cu-Zn alloy) in 1MHNO3 (nitric acid) was studied at ambient temperature. Weight loss/corrosion rate and potential measurement techniques were used for the experimental work. The tea extract was obtained from the green tea leaves. The results obtained showed effective corrosion inhibition of the extracts on the brass test specimens in the 1M nitric acid used. The different combined extracts concentrations also gave good corrosion inhibition performance. They also exhibited effective corrosion reactions synergism. The test specimen (duplex brass) gave some appreciable corrosion resistance in the test environmen
Corrosion Inhibition of Thiourea and Thiadiazole Derivatives : A Review
The continuous search for better corrosion inhibitors, due to vast differences in the media encountered in industry remains a focal point in corrosion control. The use of organic compounds to inhibit corrosion has assumed great significance due to their application in preventing corrosion under various corrosive environments. These compounds have great potential to inhibit aqueous corrosion due to film formation by adsorption on the metal surface. This paper reviews the inhibitive effect of thiourea and thiadiazole derivatives. This group of organosulphur and heterocyclic compounds and derivatives has important theoretical and practical applications, but their inhibition mechanism is not fully understood, despite extensive study. The effect of these compounds on the corrosion of metallic alloys was evaluated through assessment of various journals and experimental techniques. The corrosion rate was found to be a function of different variables. Due attention was paid to the systematic study of inhibitor action of derivatives with much emphasis on the functional groups of the molecular structure. From the comprehensive discourse presented, it is concluded that the derivatives fulfill the basic requirements for consideration as an efficient corrosion inhibito
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