Research Opportunities for Studies of Contaminant Transport in Fluvial Systems at the TIMS Branch - Steed Pond System, Savannah River Site

A workshop to identify the scientific issues associated with contamination in riparian, fluvial, and hyporheic systems was held in March 2003 at the Savannah River Site (SRS). The workshop examined the general scientific remediation challenges and research opportunities in such systems and on Tims Branch - Steed Pond, a specific uranium- and heavy-metal-contaminated riparian system at SRS. A diverse group of scientists representing a wide range of scientific disciplines came from academia, national laboratories, and research centers to develop recommendations for future ERSD research opportunities. There was agreement among the workshop participants that riparian, fluvial, and hyporheic systems represent a unique opportunity to advance science and to enable progress on DOE's environmental cleanup of contaminated sites. The participants at this workshop documented both the critical need and the great promise for research on hydrological and biogeochemical processes controlling contaminant transport and fate in contaminated surface and near-surface systems. The approach of the workshop was to assess the Tims Branch - Steed Pond system at the SRS as an appropriate site to identify research needs that support potential remediation strategies

Evaluation of Background Mercury Concentrations in the SRS Groundwater System

Mercury analyses associated with the A-01 Outfall have highlighted the importance of developing an understanding of mercury in the Savannah River Site groundwater system and associated surface water streams. This activity is critical based upon the fact that the EPA Ambient Water Quality Criteria (AWQC) for this constituent is 0.012mg/L, a level that is well below conventional detection limits of 0.1 to 0.2 mg/L. A first step in this process is obtained by utilizing the existing investment in groundwater mercury concentrations (20,242 records) maintained in the SRS geographical information management system (GIMS) database. Careful use of these data provides a technically defensible initial estimate for total recoverable mercury in background and contaminated SRS wells

Applied environmental technology development at the Savannah River Site: A retrospective on the last half of the 20th century

Fifty years ago, the Savannah River Site (SRS) was built to produce nuclear materials. These operations impacted air, soil, groundwater, ecology and the local environment. Throughout its history, SRS has addressed these contamination issues directly and has maintained a strong commitment to environmental stewardship. The site boasts many environmental firsts. Notably, SRS was the first major DOE facility to perform a baseline ecological assessment. This pioneering effort, by Ruth Patrick and the Philadelphia Academy of Sciences, was performed during SRS planning and construction in the early 1950's. This unique early example sets the stage for subsequent efforts. Since that time, the scientists and engineers at SRS have proactively identified environmental problems as they occurred and have skillfully developed elegant and efficient solutions

INDEPENDENT TECHNICAL REVIEW OF THE FOCUSED FEASIBILITY STUDY AND PROPOSED PLAN FOR DESIGNATED SOLID WASTE MANAGEMENT UNITS CONTRIBUTING TO THE SOUTHWEST GROUNDWATER PLUME AT THE PADUCAH GASEOUS DIFFUSION PLANT

The U. S. Department of Energy (DOE) is currently developing a Proposed Plan (PP) for remediation of designated sources of chlorinated solvents that contribute contamination to the Southwest (SW) Groundwater Plume at the Paducah Gaseous Diffusion Plant (PGDP), in Paducah, KY. The principal contaminants in the SW Plume are trichloroethene (TCE) and other volatile organic compounds (VOCs); these industrial solvents were used and disposed in various facilities and locations at PGDP. In the SW plume area, residual TCE sources are primarily in the fine-grained sediments of the Upper Continental Recharge System (UCRS), a partially saturated zone that delivers contaminants downward into the coarse-grained Regional Gravel Aquifer (RGA). The RGA serves as the significant lateral groundwater transport pathway for the plume. In the SW Plume area, the four main contributing TCE source units are: (1) Solid Waste Management Unit (SWMU) 1 / Oil Landfarm; (2) C-720 Building TCE Northeast Spill Site (SWMU 211A); (3) C-720 Building TCE Southeast Spill Site (SWMU 211B); and (4) C-747 Contaminated Burial Yard (SWMU 4). The PP presents the Preferred Alternatives for remediation of VOCs in the UCRS at the Oil Landfarm and the C-720 Building spill sites. The basis for the PP is documented in a Focused Feasibility Study (FFS) (DOE, 2011) and a Site Investigation Report (SI) (DOE, 2007). The SW plume is currently within the boundaries of PGDP (i.e., does not extend off-site). Nonetheless, reasonable mitigation of the multiple contaminant sources contributing to the SW plume is one of the necessary components identified in the PGDP End State Vision (DOE, 2005). Because of the importance of the proposed actions DOE assembled an Independent Technical Review (ITR) team to provide input and assistance in finalizing the PP

Dense Molecular Gas In A Young Cluster Around MWC 1080 -- Rule Of The Massive Star

We present CS $J = 2 \to 1$, $^{13}$CO $J = 1 \to 0$, and C$^{18}$O $J = 1 \to 0$, observations with the 10-element Berkeley Illinois Maryland Association (BIMA) Array toward the young cluster around the Be star MWC 1080. These observations reveal a biconical outflow cavity with size $\sim$ 0.3 and 0.05 pc for the semimajor and semiminor axis and $\sim$ 45\arcdeg position angle. These transitions trace the dense gas, which is likely the swept-up gas of the outflow cavity, rather than the remaining natal gas or the outflow gas. The gas is clumpy; thirty-two clumps are identified. The identified clumps are approximately gravitationally bound and consistent with a standard isothermal sphere density, which suggests that they are likely collapsing protostellar cores. The gas kinematics suggests that there exists velocity gradients implying effects from the inclination of the cavity and MWC 1080. The kinematics of dense gas has also been affected by either outflows or stellar winds from MWC 1080, and lower-mass clumps are possibly under stronger effects from MWC 1080 than higher-mass clumps. In addition, low-mass cluster members tend to be formed in the denser and more turbulent cores, compared to isolated low-mass star-forming cores. This results from contributions of nearby forming massive stars, such as outflows or stellar winds. Therefore, we conclude that in clusters like the MWC 1080 system, effects from massive stars dominate the star-forming environment in both the kinematics and dynamics of the natal cloud and the formation of low-mass cluster members. This study provides insights into the effects of MWC 1080 on its natal cloud, and suggests a different low-mass star forming environment in clusters compared to isolated star formation.Comment: 42 pages, 5 tables, and 13 figures, accepted for publication in Ap

TECHNICAL EVALUATION OF TEMPORAL GROUNDWATER MONITORING VARIABILITY IN MW66 AND NEARBY WELLS, PADUCAH GASEOUS DIFFUSION PLANT

Evaluation of disposal records, soil data, and spatial/temporal groundwater data from the Paducah Gaseous Diffusion Plant (PGDP) Solid Waste Management Unit (SWMU) 7 indicate that the peak contaminant concentrations measured in monitoring well (MW) 66 result from the influence of the regional PGDP NW Plume, and does not support the presence of significant vertical transport from local contaminant sources in SWMU 7. This updated evaluation supports the 2006 conceptualization which suggested the high and low concentrations in MW66 represent different flow conditions (i.e., local versus regional influences). Incorporation of the additional lines of evidence from data collected since 2006 provide the basis to link high contaminant concentrations in MW66 (peaks) to the regional 'Northwest Plume' and to the upgradient source, specifically, the C400 Building Area. The conceptual model was further refined to demonstrate that groundwater and the various contaminant plumes respond to complex site conditions in predictable ways. This type of conceptualization bounds the expected system behavior and supports development of environmental cleanup strategies, providing a basis to support decisions even if it is not feasible to completely characterize all of the 'complexities' present in the system. We recommend that the site carefully consider the potential impacts to groundwater and contaminant plume migration as they plan and implement onsite production operations, remediation efforts, and reconfiguration activities. For example, this conceptual model suggests that rerouting drainage water, constructing ponds or basin, reconfiguring cooling water systems, capping sites, decommissioning buildings, fixing (or not fixing) water leaks, and other similar actions will potentially have a 'direct' impact on the groundwater contaminant plumes. Our conclusion that the peak concentrations in MW66 are linked to the regional PGDP NW Plume does not imply that there TCE is not present in SWMU 7. The available soil and groundwater data indicate that the some of the waste disposed in this facility contacted and/or were contaminated by TCE. In our assessment, the relatively small amount of TCE associated with SWMU 7 is not contributing detectable TCE to the groundwater and does not represent a significant threat to the environment, particularly in an area where remediation and/or management of TCE in the NW plume will be required for an extended timeframe. If determined to be necessary by the PGDP team and regulators, additional TCE characterization or cleanup activities could be performed. Consistent with the limited quantity of TCE in SWMU 7, we identify a range of low cost approaches for such activities (e.g., soil gas surveys for characterization or SVE for remediation). We hope that this information is useful to the Paducah team and to their regulators and stakeholders to develop a robust environmental management path to address the groundwater and soil contamination associated with the burial ground areas