Myrrha primary heat exchanger tube rupture: Phenomenology and evolution

In the framework of MYRRHA Project, a pool-type experimental and material testing irradiation facility operated with Lead Bismuth Eutectic (LBE) coolant and able to operate in both sub-critical and critical mode is designed to be built in Mol, Belgium, in SCK\u2022CEN domain. In addition to the material testing function, targets of the MYRRHA reactor are to prove the feasibility of the ADS technology as Minor Actinides (MAs) burner and to act as a demonstrative plant for future Gen-IV heavy metal cooled reactors. SCK\u2022CEN entered the pre-licensing phase for the MYRRHA reactor. In order to provide the safety authority all the required data, a complete safety analysis must be performed, studying the transients defined by the list of postulating initiating events. In particular, an accident with potential serious consequences is the Primary Heat Exchanger Tube Rupture (PHXTR), involving the sudden release of single phase or two-phase water from a tube break in a hot liquid metal pool. This accident evolution is strongly characterized by the design of the MYRRHA Primary Heat eXchanger (PHX) and its direct surroundings in the reactor vessel and by the thermal-hydraulical conditions of the MYRRHA primary and secondary cooling system. In the first phase of a PHXTR accident, the water in the Secondary Cooling System (SCS) is released in the Primary System (PS) pool in regime of choked flow due to the pressure difference. Being the water released in an overheated, low-pressure environment, a flashing with potential sudden specific volume increase is expected. The heat transfer phenomena leading to the phase change velocity depend by the actual number of bubbles released in the hot liquid metal pool, function of the actual break size and shape. Its characterization is important for the definition of the overall specific volume increase and for the estimation of the water mass fraction redirected through the Primary Pump in the reactor Lower Plenum, with the risk of void insertion in the core and consequent reactivity excursion. A simplified calculation model to evaluate the history of any given bubble distribution generated by any water flow rate through any break has been set up. The main purpose is to describe the evolution of the main system state variables during the accidental event, by checking the potential insurgency of any reactor safety issue due to pressure peaks or core void insertions

A low-cost internal standard loader for solid-phase sorbing tools

Solid-phase sorption is widely used for the analysis of gaseous specimens as it allows at the same time to preconcentrate target analytes and store samples for relatively long periods. The addition of internal standards (ISs) in the analytical workflow can greatly reduce the variability of the analyses and improve the reliability of the protocols. In this work, we describe the development and testing of a portable system for the reliable production of gaseous mixture of( 8)D-Toluene in a 1L Silonite canister as well as its reproducible loading into solid-phase sorbing tools as ISs. The portable system was tested using needle trap microextraction, solid-phase extraction, and thin-film microextraction techniques commonly employed for the analysis of gaseous samples. Even though our specific interest is in breath analysis, the system can also be used for the collection of any kind of gaseous specimen. A microcontroller allows the fine control of the sampling flow by a digital mass flow controller. Flow rate and sample volume could be set either through a rotary encoder mounted onto the control board or through a dedicated android app. The variability of the airflow is in the range 5-200 ml min(-1) and it is lower than 1%, whereas the variability of the IS (D-8-Toluene) concentration dispensed over time by the loader measured by selected-ion flow-tube mass spectrometry (MS) is <3%. This combination resulted in intra- and inter-day precision of the amount loaded in the sorbent tools lower than 15%. No carry-over was detected in the loader after the delivery of the D-8-Toluene measured by gas chromatography-MS. The 8D-Toluene concentration in the canister was stable for up to three weeks at room temperature

Bio-based benzoxazines synthesized in a deep eutectic solvent: A greener approach toward vesicular nanosystems

A green synthesis of benzoxazines, based upon reaction of cardanol with formaldehyde and primary amines, is achieved in high yields using choline chloride-urea mixture as deep eutectic solvent. Then, it is demonstrated how the cardanol-based benxoxazines can be employed as only component for the preparation of a nanovesicular systems

Combining electrodermal activity analysis and dynamic causal modeling to investigate the visual-odor multimodal integration during face perception

Objective. This study presents a novel methodological approach for incorporating information related to the peripheral sympathetic response into the investigation of neural dynamics. Particularly, we explore how hedonic contextual olfactory stimuli influence the processing of neutral faces in terms of sympathetic response, event-related potentials and effective connectivity analysis. The objective is to investigate how the emotional valence of odors influences the cortical connectivity underlying face processing and the role of face-induced sympathetic arousal in this visual-olfactory multimodal integration. Approach. To this aim, we combine electrodermal activity (EDA) analysis and dynamic causal modeling to examine changes in cortico-cortical interactions. Results. The results reveal that stimuli arising sympathetic EDA responses are associated with a more negative N170 amplitude, which may be a marker of heightened arousal in response to faces. Hedonic odors, on the other hand, lead to a more negative N1 component and a reduced the vertex positive potential when they are unpleasant or pleasant. Concerning connectivity, unpleasant odors strengthen the forward connection from the inferior temporal gyrus (ITG) to the middle temporal gyrus, which is involved in processing changeable facial features. Conversely, the occurrence of sympathetic responses after a stimulus is correlated with an inhibition of this same connection and an enhancement of the backward connection from ITG to the fusiform face gyrus. Significance. These findings suggest that unpleasant odors may enhance the interpretation of emotional expressions and mental states, while faces capable of eliciting sympathetic arousal prioritize identity processing

Determination of carbonyl compounds in exhaled breath by on-sorbent derivatization coupled with thermal desorption and gas chromatography-tandem mass spectrometry

A reliable method for the determination of carbonyl compounds in exhaled breath based on on-sorbent derivatization coupled with thermal desorption and gas chromatography-tandem mass spectrometry is described. The analytical performances were optimized for a mixture of C2-C9 aldehydes and C3-C9 ketones, particularly interesting for clinical applications, by using an internal standard and applying a 2^3 full factorial design. A volume of sample (250 ml) was loaded at 50 ml min-1 into a Tenax GR sorbent tube containing 130 nmol of O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride. All compounds showed a limit of detection lower than 200 pptv. The yield of the derivatization procedure was normalized by adding to the sample a known amount of 6D-acetone as an internal standard. This allowed halving the relative standard deviation to 10% and 15% for the mono-and di-carbonyl compounds, respectively, thus improving reliability. The optimized method was applied to the determination of carbonyl compounds in 12 breath samples collected from four patients suffering from heart failure during hospitalization

An algebraic classification of entangled states

We provide a classification of entangled states that uses new discrete entanglement invariants. The invariants are defined by algebraic properties of linear maps associated with the states. We prove a theorem on a correspondence between the invariants and sets of equivalent classes of entangled states. The new method works for an arbitrary finite number of finite-dimensional state subspaces. As an application of the method, we considered a large selection of cases of three subspaces of various dimensions. We also obtain an entanglement classification of four qubits, where we find 27 fundamental sets of classes.Comment: published versio

Analysis of radiatively stable entanglement in a system of two dipole-interacting three-level atoms

We explore the possibilities of creating radiatively stable entangled states of two three-level dipole-interacting atoms in a $\Lambda$ configuration by means of laser biharmonic continuous driving or pulses. We propose three schemes for generation of entangled states which involve only the lower states of the $\Lambda$ system, not vulnerable to radiative decay. Two of them employ coherent dynamics to achieve entanglement in the system, whereas the third one uses optical pumping, i.e., an essentially incoherent process.Comment: Replaced with the final version; 14 pages, 6 figures; to appear in Phys. Rev. A, vol. 61 (2000