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Molybdenum and Tungsten Structural Differences are Dependent on ndz2/(n + 1)Ñ• Mixing: Comparisons of (silox)3MX/R (M = Mo, W; silox = tBu3SiO)
Article discussing molybdenum and tungsten structural differences being dependent on ndz2/(n + 1)s mixing and a comparison of (silox)3MX/R (M = Mo, W; silox - tBu3SiO)
Isospecific Polymerization of Racemic Epoxides: a Catalyst System for the Synthesis of Highly Isotactic Polyethers
A highly active bimetallic cobalt catalyst system is reported for the polymerization of racemic terminal epoxides to yield isotactic polyethers.We acknowledge the NSF (CHE-0809778) and the King Abdullah University of Science and Technology (KAUST; Award No. KUS-C1-018-02) for support of this research. The authors are grateful for the help of T. Mourey at Kodak for polymer molecular weight determinatio
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