The infrastructural conditions of (de-)growth: The case of the internet

Infrastructure studies represent a domain that remains significantly uncharted among degrowth scholars. This is paradoxical considering that infrastructures constitute a fundamental prerequisite for the equitable distribution of many aspects of human well-being that degrowth proponents emphasize. Nonetheless, the substantial resource and energy consumption associated with infrastructures cannot be overlooked. The internet offers an instructive case study in this sense, at its best it forges human connections and is productive of considerable societal value. The resource implications of the often-overlooked internet physical layer of data-centres and submarine cables needs to be acknowledged. Furthermore, the ways in which assumptions of perpetual growth are built into this global infrastructure via the logic layer of internet protocols and other governing mechanisms such as finance and network design need to be examined if we are to determine the extent to which such infrastructures are inherently growth dependent. In making these two arguments, we draw upon the work of both Science and Technology Studies (STS) and Large Technological System (LTS) studies on the inherent problems of large infrastructures which have thus far seen little engagement with questions of degrowth. We review the case of the internet and suggest a number of scenarios that illustrate potential roles for such infrastructures in any planned reduction of economic activity

Colossal Reversible Barocaloric Effects in Layered Hybrid Perovskite (C10H21NH3)2MnCl4 under Low Pressure Near Room Temperature

Barocaloric effects in a layered hybrid organic–inorganic compound, (C10H21NH3)2MnCl4, that are reversible and colossal under pressure changes below 0.1 GPa are reported. This barocaloric performance originates in a phase transition characterized by different features: A strong disordering of the organic chains, a very large volume change, a very large sensitivity of the transition temperature to pressure and a small hysteresis. The obtained values are unprecedented among solid-state cooling materials at such low pressure changes and demonstrate that colossal effects can be obtained in compounds other than plastic crystals. The temperature-pressure phase diagram displays a triple point indicating enantiotropy at high pressure

Taphonomic Criteria for Identifying Iberian Lynx Dens in Quaternary Deposits

For decades, taphonomists have dedicated their efforts to assessing the nature of the massive leporid accumulations recovered at archaeological sites in the northwestern Mediterranean region. Their interest lying in the fact that the European rabbit constituted a critical part of human subsistence during the late Pleistocene and early Holocene. However, rabbits are also a key prey in the food webs of Mediterranean ecosystems and the base of the diet for several specialist predators, including the Iberian lynx (Lynx pardinus). For this reason, the origin of rabbit accumulations in northwestern Mediterranean sites has proved a veritable conundrum. Here, we present the zooarchaeological and taphonomic study of more than 3000 faunal and 140 coprolite remains recovered in layer IIIa of Cova del Gegant (Catalonia, Spain). Our analysis indicates that this layer served primarily as a den for the Iberian lynx. The lynxes modified and accumulated rabbit remains and also died at the site creating an accumulation dominated by the two taxa. However, other agents and processes, including human, intervened in the final configuration of the assemblage. Our study contributes to characterizing the Iberian lynx fossil accumulation differentiating between the faunal assemblages accumulated by lynxes and hominins

Satellites and central galaxies in SDSS: The influence of interactions on their properties

We use SDSS-DR14 to construct a sample of galaxy systems consisting of a central object and two satellites. We adopt projected distance and radial velocity difference criteria and impose an isolation criterion to avoid membership in larger structures. We also classify the interaction between the members of each system through a visual inspection of galaxy images, finding ${sim}80{{ m per cent}}$ of the systems lack evidence of interactions whilst the remaining ${sim}20{{ m per cent}}$ involve some kind of interaction, as inferred from their observed distorted morphology. We have considered separately, samples of satellites and central galaxies, and each of these samples were tested against suitable control sets to analyse the results. We find that central galaxies showing signs of interactions present evidence of enhanced star formation activity and younger stellar populations. As a counterpart, satellite samples show these galaxies presenting older stellar populations with a lower star formation rate than the control sample. The observed trends correlate with the stellar mass content of the galaxies and with the projected distance between the members involved in the interaction. The most massive systems are less affected since they show no star formation excess, possibly due to their more evolved stage and less gas available to form new stars. Our results suggest that it is arguably a transfer of material during interactions, with satellites acting as donors to the central galaxy. As a consequence of the interactions, satellite stellar population ages rapidly and new bursts of star formation may frequently occur in the central galaxy.Fil: Mesa, Valeria Alejandra. Universidad de La Serena; Chile. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; ArgentinaFil: Alonso, Sol. Universidad Nacional de San Juan. Facultad de Ciencias Exactas, Físicas y Naturales. Departamento de Geofísica y Astronomía; ArgentinaFil: Coldwell Lloveras, Georgina Vanesa. Universidad Nacional de San Juan. Facultad de Ciencias Exactas, Físicas y Naturales. Departamento de Geofísica y Astronomía; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Juan; ArgentinaFil: Garcia Lambas, Diego Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Astronomía Teórica y Experimental. Universidad Nacional de Córdoba. Observatorio Astronómico de Córdoba. Instituto de Astronomía Teórica y Experimental; ArgentinaFil: Nilo Castellon, J. L. Universidad de La Serena; Chil

Socioeconomic Status, Psychosocial Factors, Race and Nocturnal Blood Pressure Dipping in a Hispanic Cohort

BACKGROUND Little information is available about the relationship of socioeconomic status (SES) to blunted nocturnal ambulatory blood pressure (ABP) dipping among Hispanics and whether this relationship differs by race. We sought to characterize ABP nondipping and its determinants in a sample of Hispanics. METHODS We enrolled 180 Hispanic participants not on antihypertensive medications. SES was defined by years of educational attainment. All participants underwent 24-hour ABP monitoring. A decrease of <10% in the ratio between average awake and average asleep systolic BP was considered nondipping. RESULTS The mean age of the cohort was 67.1 ± 8.7, mean educational level was 9.4 ± 4.4 years, and 58.9% of the cohort was female. The cohort was comprised of 78.3% Caribbean Hispanics with the rest from Mexico and Central/South America; 41.4% self-identified as white Hispanic, 34.4% self-identified as black Hispanic, and 24.4% did not racially self- identify. The percentage of nondippers was 57.8%. Educational attainment (10.5 years vs. 8.6 years; P <0.01) was significantly higher among dippers than nondippers. In multivariable analyses, each 1-year increase in education was associated with a 9% reduction in the likelihood of being a nondipper (odds ratio [OR], 0.91; 95% confidence interval [CI], 0.84–0.98; P = 0.01). There were significantly greater odds of being a nondipper for black Hispanics than for white Hispanics (OR, 2.83, 95% CI, 1.29–6.23; P = 0.005). Higher SES was significantly protective of nondipping in white Hispanics but not black Hispanics. CONCLUSIONS These results document a substantial prevalence of nondipping in a cohort of predominantly normotensive Hispanics. Dipping status varied significantly by race. Lower SES is significantly associated with nondipping status, and race potentially impacts on this relation

Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol.

There is currently great interest in replacing the harmful volatile hydrofluorocarbon fluids used in refrigeration and air-conditioning with solid materials that display magnetocaloric, electrocaloric or mechanocaloric effects. However, the field-driven thermal changes in all of these caloric materials fall short with respect to their fluid counterparts. Here we show that plastic crystals of neopentylglycol (CH3)2C(CH2OH)2 display extremely large pressure-driven thermal changes near room temperature due to molecular reconfiguration, that these changes outperform those observed in any type of caloric material, and that these changes are comparable with those exploited commercially in hydrofluorocarbons. Our discovery of colossal barocaloric effects in a plastic crystal should bring barocaloric materials to the forefront of research and development in order to achieve safe environmentally friendly cooling without compromising performance

Allocation of Ambipolar Charges on an Organic Diradical with a Vinylene–Phenylenediyne Bridge

Two redox and magnetically active perchlorotriphenylmethyl (•PTM) radical units have been connected as end-capping groups to a bis(phenylene)diyne chain through vinylene linkers. Negative and positive charged species have been generated, and the influence of the bridge on their stabilization is discussed. Partial reduction of the electron-withdrawing •PTM radicals results in a class-II mixed-valence system with the negative charge located on the terminal PTM units, proving the efficiency of the conjugated chain for the electron transport between the two terminal sites. Counterintuitively, the oxidation process does not occur along the electron-rich bridge but on the vinylene units. The •PTM radicals play a key role in the stabilization of the cationic species, promoting the generation of quinoidal ring segments