38 research outputs found
Axial light emission and Ar metastable densities in a parallel plate dc micro discharge in steady state and transient regimes
Axial emission profiles in a parallel plate dc micro discharge (feedgas:
argon; discharge gap d=1mm; pressure p=10Torr) were studied by means of time
resolved imaging with a fast ICCD camera. Additionally, volt-ampere (V-A)
characteristics were recorded and Ar* metastable densities were measured by
tunable diode laser absorption spectroscopy (TDLAS). Axial emission profiles in
the steady state regime are similar to corresponding profiles in standard size
discharges (d=1cm, p=1Torr). For some discharge conditions relaxation
oscillations are present when the micro discharge switches periodically between
low current Townsend-like mode and normal glow. At the same time the axial
emission profile shows transient behavior, starting with peak distribution at
the anode, which gradually moves towards the cathode during the normal glow.
The development of argon metastable densities highly correlates with the
oscillating discharge current. Gas temperatures in the low current
Townsend-like mode (T= 320-400K) and the high current glow mode (T=469-526K)
were determined by the broadening of the recorded spectral profiles as a
function of the discharge current.Comment: submitted to Plasma Sources Sci. Techno
Fatty acid composition of maize germ oil from high-oil hybrids wet-milling processing
Maize germ was obtained by wet-milling laboratory processing of domestic high-oil maize hybrids. After separation, the germ was subjected to extraction of maize oil. Fatty acid composition of maize germ oil was determined by gas chromatography. The results showed very high levels of unsaturated fatty acids and a constant sum of oleic and linoleic acids in oils of different maize hybrids
Oscillation modes of dc microdischarges with parallel-plate geometry
Two different oscillation modes in microdischarge with parallel-plate
geometry has been observed: relaxation oscillations with frequency range
between 1.23 and 2.1 kHz and free-running oscillations with 7 kHz frequency.
The oscillation modes are induced by increasing power supply voltage or
discharge current. For a given power supply voltage, there is a spontaneous
transition from one to other oscillation mode and vice versa. Before the
transition from relaxation to free-running oscillations, the spontaneous
increase of oscillation frequency of relaxation oscillations form 1.3 kHz to
2.1 kHz is measured. Fourier Transform Spectra of relaxation oscillations
reveal chaotic behaviour of microdischarge. Volt-Ampere characteristics
associated with relaxation oscillations describes periodical transition between
low current, diffuse discharge and normal glow. However, free-running
oscillations appear in subnormal glow only.Comment: Submitted to: New Journal of Physic
Spatiotemporal profile of emission from oscillating dc micro discharges
The axial light distributions in parallel-plate dc microdischarges in argon
show similar behavior to large scale discharges. Between the low-current
Townsend mode and the high current glow mode exists a large region of currents
where different oscillations appear and the dynamic Volt-Ampere characteristic
shows hysteresis behavior. During the oscillations the maximum peak intensity
moves closer to the cathode, which is characteristic for the abnormal glow
regime even though the average current is considerably smaller.Comment: submitted to: IEEE Trans. Plasma Sci., Spec. Issue on Images in
Plasma Sc
A Monte Carlo simulation of ion transport at finite temperatures
We have developed a Monte Carlo simulation for ion transport in hot
background gases, which is an alternative way of solving the corresponding
Boltzmann equation that determines the distribution function of ions. We
consider the limit of low ion densities when the distribution function of the
background gas remains unchanged due to collision with ions. A special
attention has been paid to properly treat the thermal motion of the host gas
particles and their influence on ions, which is very important at low electric
fields, when the mean ion energy is comparable to the thermal energy of the
host gas. We found the conditional probability distribution of gas velocities
that correspond to an ion of specific velocity which collides with a gas
particle. Also, we have derived exact analytical formulas for piecewise
calculation of the collision frequency integrals. We address the cases when the
background gas is monocomponent and when it is a mixture of different gases.
The developed techniques described here are required for Monte Carlo
simulations of ion transport and for hybrid models of non-equilibrium plasmas.
The range of energies where it is necessary to apply the technique has been
defined. The results we obtained are in excellent agreement with the existing
ones obtained by complementary methods. Having verified our algorithm, we were
able to produce calculations for Ar ions in Ar and propose them as a new
benchmark for thermal effects. The developed method is widely applicable for
solving the Boltzmann equation that appears in many different contexts in
physics.Comment: 14 page
Extraction of Palladium- [4-(2-Thiazolylazo)Resorcinol] Complexes and Spectrophotometric Determination of Palladium
The extraction of palladium(II) as a red camples with 4-(2- -thiazolylazo)resarciinol (TAR = H2R) by tetraphenylphasphanium chloride in chloroform was studied. Quantitative extraction was achieved in the pH region between 2 and 10. By extraction at pH 2 and by spectrophotometric measurements of the red complex in the organic phase, a sensitive and selective method for palladium determination was evaluated. An anionic complex [PdRCl]" was predominantly extracted over a wide pH range forming ion associates with tetraphenylphasphomium cation 0Lax = 525 . nm, s = 2.4 X 104 1 mol1 cm"1). The extracted complexes were studied in solution and by characterization of the isolated solid compound
Extraction of Palladium- [4-(2-Thiazolylazo)Resorcinol] Complexes and Spectrophotometric Determination of Palladium
The extraction of palladium(II) as a red camples with 4-(2- -thiazolylazo)resarciinol (TAR = H2R) by tetraphenylphasphanium chloride in chloroform was studied. Quantitative extraction was achieved in the pH region between 2 and 10. By extraction at pH 2 and by spectrophotometric measurements of the red complex in the organic phase, a sensitive and selective method for palladium determination was evaluated. An anionic complex [PdRCl]" was predominantly extracted over a wide pH range forming ion associates with tetraphenylphasphomium cation 0Lax = 525 . nm, s = 2.4 X 104 1 mol1 cm"1). The extracted complexes were studied in solution and by characterization of the isolated solid compound