180 research outputs found

    catena-Poly[[trimethyl­tin(IV)]-μ-2-(2-chloro­phenyl)­acetato]

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    In the title polymeric coordination compound, [Sn(CH3)3(C8H6ClO2)]n, the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxyl­ate O atoms of the 2-chloro­phenyl­acetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 2-chloro­phenyl­acetato ligand, forming a chain structure

    Bis(5-amino-2-chloro­benzoato-κO)triphenyl­anti­mony(V)

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    In the title compound, [Sb(C6H5)3(C7H5ClNO2)2], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxyl­ate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intra­molecular C—H⋯O inter­actions occur. The mol­ecules are connected by inter­molecular N—H⋯O, N—H⋯N and C—H⋯O hydrogen-bonding inter­actions and C—H⋯π stacking inter­actions, forming a three-dimensional supra­molecular framewor

    Bis(2-amino-4-chloro­benzoato)triphenyl­anti­mony(V)

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    The title complex mol­ecule, [Sb(C6H5)3(C7H5ClNO2)2], possesses crystallographically imposed C 2 symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl­ate groups and the equatorial positions by the C atoms of the phenyl groups. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur

    Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)

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    The mol­ecule of the title compound, [Sb(C6H5)3(C7H6NO2)2], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy­benzaldehyde oximate ligands. An intra­molecular O—H⋯N inter­action is present. The crystal structure is stabilized by C—H⋯O inter­actions

    N′-[(E)-3-Pyridylmethyl­idene]benzo­hydrazide

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    The title compound, C13H11N3O, was prepared by the reaction of benzohydrazide and nicotinaldehyde. The dihedral angle between the planes of the two aromatic rings is 47.78 (9)°. The crystal structure is stabilized by inter­molecular N—H⋯N hydrogen-bonding inter­actions

    (E)-2-Meth­oxy-6-(thia­zol-2-ylimino­meth­yl)phenol

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    The title compound, C11H10N2O2S, displays an E configuration about the C=N bond. The mean planes of the thia­zole and benzene rings make a dihedral angle of 9.32 (18)°. Intra­molecular O—H⋯N hydrogen bonds are found in the crystal structure

    3-Eth­oxy-2-(1,3-thia­zol-2-yl)isoindolin-1-one

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    In the title compound, C13H12N2O2S, the dihedral angles between the isoindolone ring system and the thia­zole ring and the eth­oxy group are 6.50 (11) and 89.0 (2)°, respectively
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