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Eight-potential-well order-disorder ferroelectric model and effects of random fields
An eight-potential-well order-disorder ferroelectric model was presented and
the phase transition was studied under the mean-field approximation. It was
shown that the two-body interactions are able to account for the first-order
and the second order phase transitions. With increasing the random fields in
the system, a first-order phase transition is transformed into a second-order
phase transition, and furthermore, a second-order phase transition is
inhibited.
However, proper random fields can promote the spontaneous appearance of a
first-order phase transition by increasing the overcooled temperature. The
connections of the model with relaxors were discussed.Comment: 8 pages, 5 figures. Submitted to Applied Physics Letter
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