Detachment work of prolate spheroidal particles from fluid droplets: role of viscous dissipation

The force–displacement curve for removal of an elongated solid particle from the surface of liquid droplets or gas bubbles is calculated and compared to our previous reported results for spherical particles. The surface adsorption energy for prolate particles is known to be larger than those of spheres. We show that in fact the minimum possible work done upon removal of an elongated particle from surface can be less than that for a sphere. This result is obtained when the dissipation of interfacial energy, stored in the fluid film, attaching the particles to the surface during their displacement, is properly accounted for. This dissipation is unavoidable, even if the particles are removed infinitely slowly. Once the particle actually leaves the surface, the formed liquid bridge relaxes thus dissipating any stored interfacial energy as the surface returns to its original undistorted state. The difference between the work of removal of a particle from surface and its adsorption energy is seen to become increasingly larger with smaller particle to droplet size ratios. For example, for a size ratio of 1:100, the work of removal is 1.93 times greater than the adsorption energy. However, we also find that for any given size ratio, there is a value of particle aspect ratio for which the work of removal of particles (combined dissipated and adsorbed energy) attains its minimum value

Multi-scale interaction of flow and the artery wall

We discuss, from the perspective of basic science, the physical and biological processes which underlie atherosclerotic (plaque) initiation at the vascular endothelium, identifying their widely separated spatial and temporal scales which participate. We draw on current, related models of vessel wall evolution, paying particular attention to the role of flow, and proceed to propose, then validate (in practical, qualitative terms, at least) a multiply coupled, multi-scale modeling strategy, which, eventually, aims at a quantitative, patient-specific understanding of the coupling between the flow and the endothelial state

Quantum thermodynamics at critical points during melting and solidification processes

We systematically explore and show the existence of finite-temperature continuous quantum phase transition (CTQPT) at a critical point, namely, during solidification or melting such that the first-order thermal phase transition is a special case within CTQPT. Infact, CTQPT is related to chemical reaction where quantum fluctuation (due to wavefunction transformation) is caused by thermal energy and it can occur maximally for temperatures much higher than zero Kelvin. To extract the quantity related to CTQPT, we use the ionization energy theory and the energy-level spacing renormalization group method to derive the energy-level spacing entropy, renormalized Bose-Einstein distribution and the time-dependent specific heat capacity. This work unambiguously shows that the quantum phase transition applies for any finite temperatures.Comment: To be published in Indian Journal of Physics (Kolkata

Liquid marble-derived solid-liquid hybrid superparticles for CO2 capture.

The design of effective CO2 capture materials is an ongoing challenge. Here we report a concept to overcome current limitations associated with both liquid and solid CO2 capture materials by exploiting a solid-liquid hybrid superparticle (SLHSP). The fabrication of SLHSP involves assembly of hydrophobic silica nanoparticles on the liquid marble surface, and co-assembly of hydrophilic silica nanoparticles and tetraethylenepentamine within the interior of the liquid marble. The strong interfacial adsorption force and the strong interactions between amine and silica are identified to be key elements for high robustness. The developed SLHSPs exhibit excellent CO2 sorption capacity, high sorption rate, long-term stability and reduced amine loss in industrially preferred fixed bed setups. The outstanding performances are attributed to the unique structure which hierarchically organizes the liquid and solid at microscales