70 research outputs found

    Asymmetric hydrosilylation of prochiral ketones catalyzed by nanocrystalline copper(II) oxide

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    Asymmetric hydrosilylation of aryl alkyl ketones to afford chiral secondary alcohols with good yields and excellent enantioselectivity is realized by using nanocrystalline copper(II) oxide and BINAP in the presence of organosilanes as the stoichiometric reducing agents
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