15,311 research outputs found

    Toward a unified interpretation of quark and lepton mixing from flavor and CP symmetries

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    We discussed the scenario that a discrete flavor group combined with CP symmetry is broken to Z2×CPZ_2\times CP in both neutrino and charged lepton sectors. All lepton mixing angles and CP violation phases are predicted to depend on two free parameters θl\theta_{l} and θν\theta_{\nu} varying in the range of [0,π)[0, \pi). As an example, we comprehensively study the lepton mixing patterns which can be derived from the flavor group Δ(6n2)\Delta(6n^2) and CP symmetry. Three kinds of phenomenologically viable lepton mixing matrices are obtained up to row and column permutations. We further extend this approach to the quark sector. The precisely measured quark mixing angles and CP invariant can be accommodated for certain values of the free parameters θu\theta_{u} and θd\theta_{d}. A simultaneous description of quark and lepton flavor mixing structures can be achieved from a common flavor group Δ(6n2)\Delta(6n^2) and CP, and accordingly the smallest value of the group index nn is n=7n=7.Comment: 40 pages, 8 figure

    A supramolecular radical cation: folding-enhanced electrostatic effect for promoting radical-mediated oxidation.

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    We report a supramolecular strategy to promote radical-mediated Fenton oxidation by the rational design of a folded host-guest complex based on cucurbit[8]uril (CB[8]). In the supramolecular complex between CB[8] and a derivative of 1,4-diketopyrrolo[3,4-c]pyrrole (DPP), the carbonyl groups of CB[8] and the DPP moiety are brought together through the formation of a folded conformation. In this way, the electrostatic effect of the carbonyl groups of CB[8] is fully applied to highly improve the reactivity of the DPP radical cation, which is the key intermediate of Fenton oxidation. As a result, the Fenton oxidation is extraordinarily accelerated by over 100 times. It is anticipated that this strategy could be applied to other radical reactions and enrich the field of supramolecular radical chemistry in radical polymerization, photocatalysis, and organic radical battery and holds potential in supramolecular catalysis and biocatalysis

    Spectrum-based deep neural networks for fraud detection

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    In this paper, we focus on fraud detection on a signed graph with only a small set of labeled training data. We propose a novel framework that combines deep neural networks and spectral graph analysis. In particular, we use the node projection (called as spectral coordinate) in the low dimensional spectral space of the graph's adjacency matrix as input of deep neural networks. Spectral coordinates in the spectral space capture the most useful topology information of the network. Due to the small dimension of spectral coordinates (compared with the dimension of the adjacency matrix derived from a graph), training deep neural networks becomes feasible. We develop and evaluate two neural networks, deep autoencoder and convolutional neural network, in our fraud detection framework. Experimental results on a real signed graph show that our spectrum based deep neural networks are effective in fraud detection
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