Electronic states of epitaxial thin films of La0.9Sn0.1MnO3 and La0.9Ca0.1MnO3

Structure, transport properties, and electronic structure of epitaxial thin films La0.9Sn0.1MnO3 and La0.9Ca0.1MnO3 have been experimentally studied. According to the Hall-effect measurement, La0.9Sn0.1MnO3 is an n-type conductor in the metallic state due to the substitution of Sn for La. X-ray photoelectron spectroscopy spectra revealed a shift of the Fermi level and the Mn ionic core level of La0.9Sn0.1MnO3 in comparison with La0.9Ca0.1MnO3. The difference between the Mn-2p spectra of La0.9Sn0.1MnO3 and La0.9Ca0.1MnO3 implies that Mn ions in the former are at a Mn2+/Mn3+ mixed-valence state, which is significantly different from the divalent-element-doped manganese oxides, where the Mn ions are in the mixed-valence state of Mn3+/Mn4+.published_or_final_versio

A design methodology for smart LED lighting systems powered by weakly regulated renewable power grids

The increasing use of intermittent renewable energy sources to decarbonize electric power generation is expected to introduce dynamic instability to the mains. This situation is of particular concern for mini-grids or isolated grids in which wind and/or solar power sources are the dominant or the sole power sources. In this paper, we utilize the photo-electro-thermal theory to develop a design methodology for LED lighting systems for weakly regulated voltage sources, with the objectives of minimizing the fluctuation of the human luminous perception and adopting reliable LED driver with long lifetime and robustness against extreme weather conditions. The proposed LED system, practically verified in a 10 kVA small power grid driven by an ac voltage source and a wind energy simulator, can be considered as a smart load with its load demand following the power generation. A typical swing of 40 V in the mains will cause only 15% actual light variation in a 132 W LED system when compared with 40% change in 150 W high-pressure-sodium lamp system. The design methodology enables future large-scale LED systems to be designed as a new generation of smart loads that can adapt to the voltage and power fluctuations arising from the intermittent nature of renewable energy sources. © 2011 IEEE.published_or_final_versio

Mössbauer hyperfine parameters of iron species in the course of Geobacter-mediated magnetite mineralization

Amorphous ferric iron species (ferrihydrite or akaganeite of <5 nm in size) is the only known solid ferric iron oxide that can be reductively transformed by dissimilatory iron-reducing bacteria to magnetite completely. The lepidocrocite crystallite can be transformed into magnetite in the presence of abiotic Fe(II) at elevated pH or biogenic Fe(II) with particular growth conditions. The reduction of lepidocrocite by dissimilatory iron-reducing bacteria has been widely investigated showing varying results. Vali et al. (Proc Natl Acad Sci USA 101:16121-16126, 2004) captured a unique biologically mediated mineralization pathway where the amorphous hydrous ferric oxide transformed to lepidocrocite was followed by the complete reduction of lepidocrocite to single-domain magnetite. Here, we report the 57Fe Mössbauer hyperfine parameters of the time-course samples reported in Vali et al. (Proc Natl Acad Sci USA 101:16121-16126, 2004). Both the quadrupole splittings and linewidths of Fe(III) ions decrease consistently with the change of aqueous Fe(II) and transformations of mineral phases, showing the Fe(II)-mediated gradual regulation of the distorted coordination polyhedrons of Fe 3+ during the biomineralization process. The aqueous Fe(II) catalyzes the transformations of Fe(III) minerals but does not enter the mineral structures until the mineralization of magnetite. The simulated abiotic reaction between Fe(II) and lepidocrocite in pH-buffered, anaerobic media shows the simultaneous formation of green rust and its gradual transformation to magnetite plus a small fraction of goethite. We suggested that the dynamics of Fe(II) supply is a critical factor for the mineral transformation in the dissimilatory iron-reducing cultures. © 2011 The Author(s).published_or_final_versionSpringer Open Choice, 21 Feb 201

ADRC-based model predictive current control for PMSMs fed by three-phase four-switch inverters

© 2016 IEEE.A novel automatic disturbances rejection control (ADRC)-based model predictive current control (MPCC) strategy is developed for permanent magnet synchronous motors (PMSMs) fed by three-phase four-switch inverters, an after-fault-topology for fault-tolerant three-phase six-switch inverters. The mathematical model of a PMSM fed by a three-phase four-switch inverter is built firstly. Then the ADRC and MPCC are respectively designed, with the former being used to realize disturbance estimation and disturbance compensation while the latter being used to reduce stator current ripple and improve the quality of the torque and speed control. The resultant ADRC-based MPCC PMSM fed by an unhealthy inverter has fault-tolerant effective with dynamical performance very close to an ADRC-based MPCC PMSM fed by a healthy inverter. On the other hand, compared with PI-based MPCC PMSM fed by an unhealthy inverter, it possesses better dynamical response behavior and stronger robustness as well as smaller THD index of three-phase stator current in the presence of variation of load torque. The simulation results validate the feasibility and effectiveness of the proposed scheme

Stem cell transplantation therapies in Parkinson’s disease

2002-2003 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe

Musical Interfaces: Visualization and Reconstruction of Music with a Microfluidic Two-Phase Flow

Detection of sound wave in fluids can hardly be realized because of the lack of approaches to visualize the very minute sound-induced fluid motion. In this paper, we demonstrate the first direct visualization of music in the form of ripples at a microfluidic aqueous-aqueous interface with an ultra-low interfacial tension. The interfaces respond to sound of different frequency and amplitude robustly with sufficiently precise time resolution for the recording of musical notes and even subsequent reconstruction with high fidelity. Our work shows the possibility of sensing and transmitting vibrations as tiny as those induced by sound. This robust control of the interfacial dynamics enables a platform for investigating the mechanical properties of microstructures and for studying frequency-dependent phenomena, for example, in biological systems.published_or_final_versio