Brunnian Braids and Lie Algebras

Brunnian braids have interesting relations with homotopy groups of spheres. In this work, we study the graded Lie algebra of the descending central series related to Brunnian subgroup of the pure braid group. A presentation of this Lie algebra is obtained.Comment: 21 page

How mobile are dye adsorbates and acetonitrile molecules on the surface of TiO2 nanoparticles? A quasi-elastic neutron scattering study

Motions of molecules adsorbed to surfaces may control the rate of charge transport within monolayers in systems such as dye sensitized solar cells. We used quasi-elastic neutron scattering (QENS) to evaluate the possible dynamics of two small dye moieties, isonicotinic acid (INA) and bis-isonicotinic acid (BINA), attached to TiO2 nanoparticles via carboxylate groups. The scattering data indicate that moieties are immobile and do not rotate around the anchoring groups on timescales between around 10 ps and a few ns (corresponding to the instrumental range). This gives an upper limit for the rate at which conformational fluctuations can assist charge transport between anchored molecules. Our observations suggest that if the conformation of larger dye molecules varies with time, it does so on longer timescales and/or in parts of the molecule which are not directly connected to the anchoring group. The QENS measurements also indicate that several layers of acetonitrile solvent molecules are immobilized at the interface with the TiO2 on the measurement time scale, in reasonable agreement with recent classical molecular dynamics results

Yukawa Corrections from Four-Point Functions in Intersecting D6-Brane Models

We discuss corrections to the Yukawa matrices of the Standard Model (SM) fermions in intersecting D-brane models due to four-point interactions. Recently, an intersecting D-brane model has been found where it is possible to obtain correct masses and mixings for all quarks as well as the tau lepton. However, the masses for the first two charged leptons come close to the right values but are not quite correct. Since the electron and muon are quite light, it is likely that there are additional corrections to their masses which cannot be neglected. With this in mind, we consider contributions to the SM fermion mass matrices from four-point interactions. In an explicit model, we show that it is indeed possible to obtain the SM fermion masses and mixings which are a better match to those resulting from experimental data extrapolated at the unification scale when these corrections are included. These corrections may have broader application to other models.Comment: 24 pages, 4 figure

Darwinian Data Structure Selection

Data structure selection and tuning is laborious but can vastly improve an application's performance and memory footprint. Some data structures share a common interface and enjoy multiple implementations. We call them Darwinian Data Structures (DDS), since we can subject their implementations to survival of the fittest. We introduce ARTEMIS a multi-objective, cloud-based search-based optimisation framework that automatically finds optimal, tuned DDS modulo a test suite, then changes an application to use that DDS. ARTEMIS achieves substantial performance improvements for \emph{every} project in $5$ Java projects from DaCapo benchmark, $8$ popular projects and $30$ uniformly sampled projects from GitHub. For execution time, CPU usage, and memory consumption, ARTEMIS finds at least one solution that improves \emph{all} measures for $86\%$ ($37/43$) of the projects. The median improvement across the best solutions is $4.8\%$, $10.1\%$, $5.1\%$ for runtime, memory and CPU usage. These aggregate results understate ARTEMIS's potential impact. Some of the benchmarks it improves are libraries or utility functions. Two examples are gson, a ubiquitous Java serialization framework, and xalan, Apache's XML transformation tool. ARTEMIS improves gson by $16.5$\%, $1\%$ and $2.2\%$ for memory, runtime, and CPU; ARTEMIS improves xalan's memory consumption by $23.5$\%. \emph{Every} client of these projects will benefit from these performance improvements.Comment: 11 page