The Carriers of the Interstellar Unidentified Infrared Emission Features: Aromatic or Aliphatic?

The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometer, commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules, have been recently ascribed to coal- or kerogen-like organic nanoparticles with a mixed aromatic-aliphatic structure. However, we show in this Letter that this hypothesis is inconsistent with observations. We estimate the aliphatic fraction of the UIE carriers based on the observed intensities of the 3.4 and 6.85 micrometer emission features by attributing them exclusively to aliphatic C-H stretch and aliphatic C-H deformation vibrational modes, respectively. We derive the fraction of carbon atoms in aliphatic form to be <15%. We conclude that the UIE emitters are predominantly aromatic with aliphatic material at most a minor part of the UIE carriers. The PAH model is consistent with astronomical observations and PAHs dominate the strong UIE bands.Comment: 10 pages, 2 figures, accepted for publication in ApJ Letter

Picosecond time scale imaging of mechanical contacts

By means of an ultrafast opto-acoustic technique we study the nanoindentation of thin chromium films on sapphire substrates using a ceramic ball bearing. Acoustic pulses at 40 GHz returning from the film–indenter interface allow the film indentation profiles to be probed to sub-nanometer resolution over contact areas 25 lm in radius. The deformation of the films during loading is hereby revealed. Furthermore, thermal wave imaging of the contact at megahertz frequencies is simultaneously achieved