57 research outputs found
N′-[(E)-3-Pyridylmethylidene]benzohydrazide
The title compound, C13H11N3O, was prepared by the reaction of benzohydrazide and nicotinaldehyde. The dihedral angle between the planes of the two aromatic rings is 47.78 (9)°. The crystal structure is stabilized by intermolecular N—H⋯N hydrogen-bonding interactions
catena-Poly[[trimethyltin(IV)]-μ-2-(2-chlorophenyl)acetato]
In the title polymeric coordination compound, [Sn(CH3)3(C8H6ClO2)]n, the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxylate O atoms of the 2-chlorophenylacetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 2-chlorophenylacetato ligand, forming a chain structure
μ-2-Aminoterephthalato-κ2 O 1:O 4-bis[triphenyltin(IV)]
The title compound, [Sn2(C6H5)6(C8H5NO4)], contains two triphenyltin groups bridged by a 2-aminoterephthalate ligand. The two SnIV centers have similar distorted tetrahedral coordination geometries. Each SnIV atom is bonded to three phenyl C atoms and one O atom from a carboxylate group. The other O atom of the carboxylate group has a weak interaction with the Sn atom. The amino group is disordered over two sites, with site-occupancy factors of 0.779 (11) and 0.221 (11). Intramolecular N—H⋯O hydrogen bonds are observed
(E)-2-Methoxy-6-(thiazol-2-yliminomethyl)phenol
The title compound, C11H10N2O2S, displays an E configuration about the C=N bond. The mean planes of the thiazole and benzene rings make a dihedral angle of 9.32 (18)°. Intramolecular O—H⋯N hydrogen bonds are found in the crystal structure
3-[(3-Oxo-1,3-dihydroisobenzofuran-1-yl)amino]benzoic acid
In the title compound, C15H11NO4, the dihedral angle formed by the benzene ring and isobenzofuran ring system is 67.82 (5) Å. The crystal structure is stabilized by intermolecular O—H⋯O and N—H⋯O hydrogen-bonding interactions
3,3′-Oxybi[isobenzofuran-1(3H)-one]
The title compound, C16H10O5, consists of two isobenzofuran-1(3H)-one moieties which are linked by a bridging O atom. The two halves of the molecule display approximate non-crystallographic mirror symmetry. The dihedral angle between the two isobenzofuran-1(3H)-one ring systems is 53.18 (6) Å. Two chiral carbon centres are observed in the compound, but their absolute configurations could not be determined. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link molecules into zigzag chains along c. Additional C—H⋯O interactions connect adjacent chains
catena-Poly[[trimethyltin(IV)]-μ-2,5-difluorobenzoato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH3)3(C7H3F2O2)]n, the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the carboxylate O atoms in the axial positions and the equatorial positions occupied by the methyl groups. The two Sn—O bond lengths are 2.225 (5) and 2.410 (6) Å
Octabutylbis{(E)-2-[4-(2-hydroxybenzylideneamino)phenyl]acetato}di-μ2-methoxo-di-μ3-oxido-tetratin(IV)
The title compound, [Sn4(C4H9)8(C15H12NO3)2(CH3O)2O2], is a centrosymmetric dimer and displays a ladder type structural motif. There are four SnIV centres which can be divided into two sorts, viz. two endocyclic and two exocyclic. The endo- and exocyclic SnIV centres are linked by bidentate deprotonated methanol and μ3-O atoms. Each exocyclic SnIV centre is also coordinated by a monodentate 2-[4-(2-hydroxybenzylideneamino)phenyl]acetate ligand. Parts of the butyl groups were found to be disordered over two sets of sites
3-Ethoxy-2-(1,3-thiazol-2-yl)isoindolin-1-one
In the title compound, C13H12N2O2S, the dihedral angles between the isoindolone ring system and the thiazole ring and the ethoxy group are 6.50 (11) and 89.0 (2)°, respectively
catena-Poly[[trimethyltin(IV)]-μ-2,4,6-trichlorobenzoato]
In the title compound, [Sn(CH3)3(C7H2Cl3O2)]n, the tin(IV) atom exhibits a slightly distorted trigonal-bipyramidal geometry with two O atoms of symmetry-related carboxylate groups in the axial positions and three methyl groups in the equatorial positions. In the crystal structure, the metal atoms are linked by carboxylate bridges into polymeric chains extending along the b axis
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