393 research outputs found

    Electron energy-loss spectroscopy and ab initio electronic structure of the LaOFeP superconductor

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    The electronic band structures of the LaOFeP superconductor have been calculated theoretically by the first principles method and measured experimentally by electron energy loss spectroscopy. The calculations indicate that the Fe atom in LaOFeP crystal shows a weak magnetic moment and does not form a long-range magnetic ordering. Band structure, Fermi surfaces and fluorine-doping effects are also analyzed based on the data of the density functional theory. The fine structures of the EELS data have been carefully examined in both the low loss energy region and the core losses region (O K, Fe L2,3, and La M4,5). A slight bump edge at 44 eV shows notable orientation-dependence: it can be observed in the low loss EELS spectra with q parallel to c, but becomes almost invisible in the q vertical to c spectra. Annealing experiments indicate that low oxygen pressure favors the appearance of superconductivity in LaOFeP, this fact is also confirmed by the changes of Fe L2,3 and O K excitation edges in the experimental EELS data

    LiY(SO4_4)2_2: A Superionic Material Synthesized by Superionic State Hidden in no-Superionic Literature

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    A potential superionic material LiY(SO4_4)2_2 has been excavated from the published literatures because its synthesis method and experiment data implied it exists the superionic state. We use \textit{ab initio} calculation to analyzing the differences between solid state and superionic state. We found the diffusion of Li+^+ from the lattice site to the interstitial site will change the nearest neighbor numbers of O atom from 4 to 8. In order to reduce energy, the reorientation of SO42_4^{2-} must exist accompany with the diffusion of Li+^+ so the nearest neighbor number of O will keep about 5 in the superionic state. Our work not only presents an example for discovering materials from literatures based on prior knowledge but also reveals the micromechanism of cation-anion coupled dynamics for superionic state.Comment: 18pages 5figure

    R-bUCRP: A Novel Reputation-Based Uneven Clustering Routing Protocol for Cognitive Wireless Sensor Networks

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    Energy of nodes is an important factor that affects the performance of Wireless Sensor Networks (WSNs), especially in the case of existing selfish nodes, which attracted many researchers’ attention recently. In this paper, we present a reputation-based uneven clustering routing protocol (R-bUCRP) considering both energy saving and reputation assessment. In the cluster establishment phase, we adopt an uneven clustering mechanism which controls the competitive scope of cluster head candidates to save the energy of WSNs. In the cluster heads election phase, the residual energy and reputation value are used as the indexes to select the optimal cluster head, where the reputation mechanism is introduced to support reputation assessment. Simulation results show that the proposed R-bUCRP can save node energy consumption, balance network energy distribution, and prolong network lifetime

    A Prospective Study of the Incidence of Retinopathy of Prematurity in China: Evaluation of Different Screening Criteria

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    To investigate the incidence of Retinopathy of Prematurity (ROP) in Beijing, North China, and to evaluate the effectiveness of different ROP screening criteria, we conducted a prospective cohort study in a single-neonatal intensive care unit (NICU). A total of 2997 premature infants with birth weight (BW) ≤ 2000 g and/or gestational age (GA) ≤ 34 weeks had completed ROP screening. ROP was diagnosed in 356 (11.9%) infants. The mean GA was 30.46 ± 1.98 weeks and the mean BW was 1477.35 ± 371.29 g. Of the 59 (2.0%) infants receiving treatment, the mean GA was 29.37 ± 2.10 weeks, and the mean BW was 1240.80 ± 330.71 g. The incidence of ROP declined from 14.7% in 2009 and 11.1% in 2010 to 9.5% in 2011. The United Kingdom (UK) criteria could reduce the screening number by 40.8%, and 3 infants with type I ROP needing treatment were missed, but none in 2011. The United States (US) criteria could reduce the screening number by 66.5%, and 10 infants with type I ROP needing treatment were missed, including one in 2011. So the UK criteria may be appropriate for screening of ROP in our NICU in 2011. Future multisite epidemiologic studies are required to establish suitable ROP screening criteria in China
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