The oxidative coupling of methane and the oxidative dehydrogenation of ethane over a niobium promoted lithium doped magnesium oxide catalyst

The promoting effect of niobium in a Li/MgO catalyst for the oxidative coupling of methane (OCM) and for the oxidative dehydrogenation of ethane (ODHE) has been studied in some detail. It has been found that a Li/Nb/MgO catalyst with 16 wt % niobium showed the highest activity for the C2 production in the OCM reaction; the activity at 600 °C was ten times that of the Li/MgO catalyst at the same temperature. The Li/Nb/MgO catalyst was also slightly more active for the ODHE reaction than was the Li/MgO catalyst. However, the Li/Nb/MgO catalyst produced considerably more carbon dioxide in the both reactions. Structural investigation of the catalyst showed that the addition of niobium to the Li/MgO catalyst increased the surface area and gave an increase in the lithium content of the calcined catalysts. Two niobium phases, LiNbO3 and Li3NbO4, were formed; it is shown that the first of these probably causes the increased activity. Ageing experiments showed that the activity of the catalyst was lost if the catalyst was used above 720 °C, the melting point of the lithium carbonate phase. The catalyst showed a decrease of surface area after ageing and a sharp decrease of the amount of the two niobium phases. The addition of carbon dioxide to the feed could not prevent the deactivation of the Li/Nb/MgO catalyst

Polydimethylsiloxane (PDMS)-based microfluidic channel with integrated commercial pressure sensors

The precise characterisation of boiling in microchannels is essential for the optimisation of applications requiring two phase cooling. In this paper polydimethylsiloxane (PDMS) is employed to make microchannels for characterising microboiling. In particular the material properties of PDMS facilitate rapid prototyping and its optical transparency provides the capability to directly view any fluid flow. The production of microchannels is complicated by the need to integrate custom made sensors. This paper presents a PDMS microfluidic device with integrated commercial pressure sensors, which have been used to perform a detailed characterisation of microboiling phenomena. The proposed approach of integrating commercial pressure sensors into the channel also has potential applications in a range of other microsystems

Extrusion properties of a Zr-based bulk metallic glass

The extrusion behavior of Zr41.2Ti13.8Cu12.5Ni10Be22.5 metallic glasses in the supercooled liquid region was investigated. Good extrusion formability was observed under low strain rates at temperatures higher than 395 &deg;C. The metallic glasses were fully extruded without crystallization and failure within the range of T=395&ndash;415 &deg;C under strain rates from 5&times;10&minus;3 s&minus;1 to 5&times;10&minus;2 s&minus;1, and the deformation behavior of the metallic glasses during the extrusion was found to be in a Newtonian viscous flow mode by a strain rate sensitivity of 1.0.<br /

Depairing field, onset temperature and the nature of the transition in cuprates

The depairing (upper critical) field $H_{c2}$ in hole-doped cuprates has been inferred from magnetization curves $M$-$H$ measured by torque magnetometry in fields $H$ up to 45 T. We discuss the implications of the results for the pair binding energy, the Nernst onset temperature, fluctuations and the nature of the Meissner transition at $T_c$.Comment: 4 pages, 5 figs., proc. M2S-HTSC-VIII, Dresden 2006, Physica (in press

1/f Noise in Electron Glasses

We show that 1/f noise is produced in a 3D electron glass by charge fluctuations due to electrons hopping between isolated sites and a percolating network at low temperatures. The low frequency noise spectrum goes as \omega^{-\alpha} with \alpha slightly larger than 1. This result together with the temperature dependence of \alpha and the noise amplitude are in good agreement with the recent experiments. These results hold true both with a flat, noninteracting density of states and with a density of states that includes Coulomb interactions. In the latter case, the density of states has a Coulomb gap that fills in with increasing temperature. For a large Coulomb gap width, this density of states gives a dc conductivity with a hopping exponent of approximately 0.75 which has been observed in recent experiments. For a small Coulomb gap width, the hopping exponent approximately 0.5.Comment: 8 pages, Latex, 6 encapsulated postscript figures, to be published in Phys. Rev.

O(αs) O(\alpha_s) corrections to polarized top decay into a charged Higgs t(↑)→H++b t(\uparrow) \to H^+ + b

We calculate the $O(\alpha_s)$ radiative corrections to polarized top quark decay into a charged Higgs boson and a massive bottom quark in two variants of the two-Higgs-doublet model. The radiative corrections to the polarization asymmetry of the decay may become as large as $25$. We provide analytical formulae for the unpolarized and polarized rates for $m_b \neq 0$ and for $m_b = 0$. For $m_b = 0$ our closed-form expressions for the unpolarized and polarized rates become rather compact.Comment: 24 pages, 5 figures in the text, content modified, comments added, appendices added, references updated, replaced with published versio

Attractor Solution of Phantom Field

In light of recent study on the dark energy models that manifest an equation of state $w<-1$, we investigate the cosmological evolution of phantom field in a specific potential, exponential potential in this paper. The phase plane analysis show that the there is a late time attractor solution in this model, which address the similar issues as that of fine tuning problems in conventional quintessence models. The equation of state $w$ is determined by the attractor solution which is dependent on the $\lambda$ parameter in the potential. We also show that this model is stable for our present observable universe.Comment: 9 pages, 3 ps figures; typos corrected, references updated, this is the final version to match the published versio

High Dimensional Integer Ambiguity Resolution: A First Comparison between LAMBDA and Bernese

The LAMBDA method for integer least-squares ambiguity resolution has been widely used in a great variety of Global Navigation Satellite System (GNSS) applications. The popularity of this method stems from its numerical efficiency and its guaranteed optimality in the sense of maximising the success probability of integer ambiguity estimation. In the past two decades, the LAMBDA method has been typically used in cases where the number of ambiguities is less than several tens. With the advent of denser network processing and the availability of multi-frequency, multi-GNSS systems, it is important to understand LAMBDA’s performance in high dimensional spaces. In this contribution, we will address this issue using real GPS data based on the Bernese software. We have embedded the LAMBDA method into the Bernese software and compared their ambiguity resolution performances.Twelve day dual frequency GPS data with a sampling interval of 30 s was used in the experiment, which was collected from a network of 19 stations in the Perth area of Western Australia with an average baseline length of 380 km. Different experimental scenarios were examined and tested with different observation spans, which represent the different ambiguity dimensions. The results showed that LAMBDA is still efficient even when the number of ambiguities is more than 100, and that the baseline repeatability obtained with the ambiguities resolved from the LAMBDA method agreed well with that of Bernese. Therefore, for future dense network processing, the easy-to-use LAMBDA method should be considered as an alternative to baseline-per-baseline methods as those used in e.g. the Bernese software

Particle Motion Around Tachyon Monopole

Recently, Li and Liu have studied global monoole of tachyon in a four dimensional static space-time. We analyze the motion of massless and massive particles around tachyon monopole. Interestingly, for the bending of light rays due to tachyon monopole instead of getting angle of deficit we find angle of surplus. Also we find that the tachyon monopole exerts an attractive gravitational force towards matter.Comment: 14 pages, 7 figure