Excitated state properties of 20-chloro-chlorophyll a

The excited-state and lasing properties of 20-chloro-chlorophyll a in ether solution were compared to those of chlorophyll a. Desactivation parameters and cross-sections were obtained from non-linear absorption spectroscopy in combination with a physico-mathematical methods package. The Cl substituent at C-20 (1) increases both intersystem crossing and internal conversion, (2) produces a blue-shift of the S1 absorption spectrum, and (3) leads to pronounced photochemistry

Evaluating chiral symmetry restoration through the use of sum rules

We pursue the idea of assessing chiral restoration via in-medium modifications of hadronic spectral functions of chiral partners. The usefulness of sum rules in this endeavor is illustrated, focusing on the vector and axial-vector channels. We first present an update on constructing quantitative results for pertinent vacuum spectral functions. These spectral functions serve as a basis upon which the in-medium spectral functions can be constructed. A striking feature of our analysis of the vacuum spectral functions is the need to include excited resonances, dictated by satisfying the Weinberg-type sum rules. This includes excited states in both the vector and axial-vector channels. Preliminary results for the finite temperature vector spectral function are presented. Based on a rho spectral function tested in dilepton data which develops a shoulder at low energies, we find that the rho' peak flattens off. The flattening may be a sign of chiral restoration, though a study of the finite temperature axial-vector spectral function remains to be carried out.Comment: 9 pages, conference proceedings from Resonance Workshop at UT Austin, March 5-7 201

MesonNet Workshop on Meson Transition Form Factors

The mini-proceedings of the Workshop on Meson Transition Form Factors held in Cracow from May 29th to 30th, 2012 introduce the meson transition form factor project with special emphasis on the interrelations between the various form factors (on-shell, single off-shell, double off-shell). Short summaries of the talks presented at the workshop follow.Comment: 69 pages, 14 figures; all talks can be found at https://sites.google.com/site/mesonnetwork/home/activities/form-factor-workshop-2012; v2: workshop link updated (as the page had to be moved to a commercial server), table 6 correcte

Pressure-induced changes of the vibrational modes of spin-crossover complexes studied by nuclear resonance scattering of synchrotron radiation

Nuclear inelastic scattering (NIS) spectra were recorded for the spin-crossover complexes STP and ETP (STP = [Fe(1,1,1-trisf[N-(2-pyridylmethyl)-N-methylamino]methylg- ethane)](ClO4)2 and ETP = [Fe(1,1,1-trisf[N-(2-pyridylmethyl)-N-methylamino]methylg-butane)](ClO4)2) at 30 K and at room temperature and also at ambient pressure and applied pressure (up to 2.6 GPa). Spin transition from the high-spin (HS) to the low-spin (LS) state was observed by lowering temperature and also by applying pressure at room temperature and has been assigned to the hardening of iron-bond stretching modes due to the smaller volume in the LS isomer

Strong coupling constants of bottom and charmed mesons with scalar, pseudoscalar and axial vector kaons

The strong coupling constants, $g_{D_{s}DK_0^*}$, $g_{B_{s}BK_0^*}$, $g_{D^{\ast}_{s}D K}$, $g_{B^{\ast}_{s}BK}$, $g_{D^{\ast}_{s}D K_1}$ and $g_{B^{\ast}_{s}BK_1}$, where $K_0^*$, $K$ and $K_1$ are scalar, pseudoscalar and axial vector kaon mesons, respectively are calculated in the framework of three-point QCD sum rules. In particular, the correlation functions of the considered vertices when both $B(D)$ and $K_0^*(K)(K_1)$ mesons are off-shell are evaluated. In the case of $K_1$, which is either $K_1(1270)$ or $K_1(1400)$, the mixing between these two states are also taken into account. A comparison of the obtained result with the existing prediction on $g_{D^{\ast}_{s}D K}$ as the only coupling constant among the considered vertices, previously calculated in the literature, is also made.Comment: 20 Pages, 3 Figures and 8 Table

QCD sum rule analysis for light vector and axial-vector mesons in vacuum and nuclear matter

Extending previous work we study the constraints of QCD sum rules on mass and width of light vector and axial-vector mesons in vacuum and in a medium with finite nuclear density. For the latter case especially the effect of nuclear pions leading to vector-axial-vector mixing is included in the analysis.Comment: RevTeX, 32 pages, 10 eps figure

Valence and magnetic instabilities in Sm compounds at high pressures

We report on the study of the response to high pressures of the electronic and magnetic properties of several Sm-based compounds, which span at ambient pressure the whole range of stable charge states between the divalent and the trivalent. Our nuclear forward scattering of synchrotron radiation and specific heat investigations show that in both golden SmS and SmB6 the pressure-induced insulator to metal transitions (at 2 and about 4-7 GPa, respectively) are associated with the onset of long-range magnetic order, stable up to at least 19 and 26 GPa, respectively. This long-range magnetic order, which is characteristic of Sm(3+), appears already for a Sm valence near 2.7. Contrary to these compounds, metallic Sm, which is trivalent at ambient pressure, undergoes a series of pressure-induced structural phase transitions which are associated with a progressive decrease of the ordered 4f moment.Comment: 15 pages (including 7 figures) submitted to J. Phys.: Condens. Matte