An investigation on the mechanics of homogeneous expansion in gas-fluidized beds

The Richardson and Zaki (1954, Sedimentation and fluidization. Trans. Inst. Chem. Eng. 32, pp. 35–53.) equation has been used extensively to investigate the expansion profiles of homogeneous gas-fluidized beds. The experimental value of the parameter n appearing in the equation indicates how significantly interparticle forces affect the expansion of these beds, revealing the relative importance of these forces with respect to the fluid dynamic ones. In this work, we modeled the stable expansion of gas-fluidized beds of different diameter, accounting for enduring contacts among particles and wall effects. We solved the model numerically to obtain the bed expansion profiles, back-calculating from them the values of the parameter n. For all the cases considered, we observed that the values of n are higher than those obtained by purely fluid dynamic correlations, such as those advanced by Richardson and Zaki, and Rowe (1987, A convenient empirical equation for estimation of the Richardson and Zaki exponent. Chem. Eng. Sci. 42, pp. 2795.). This effect was more pronounced in beds of smaller diameter. To validate our model, we carried out fluidization and defluidization experiments, analyzing the results by means of the Richardson and Zaki equation. We obtained a reasonable agreement between numerical and experimental findings; this suggests that enduring contacts among particles, which are manifestations of cohesiveness, affect homogeneous bed expansion. This effect is amplified by wall friction

Life cycle assessment of nanocellulose-reinforced advanced fibre composites

The research and development of nanocellulose-reinforced polymer composites have dramatically increased in the recent years due to the possibility of exploiting the high tensile stiffness and strength of nanocellulose. In the work, the environmental impacts of bacterial cellulose (BC)- and nanofibrillated cellulose (NFC)-reinforced epoxy composites were evaluated using life cycle assessment (LCA). Neat polylactide (PLA) and 30% randomly oriented glass fibre-reinforced polypropylene (GF/PP) composites were used as benchmark materials for comparison. Our cradle-to-gate LCA showed that BC- and NFC-reinforced epoxy composites have higher global warming potential (GWP) and abiotic depletion potential of fossil fuels (ADf) compared to neat PLA and GF/PP even though the specific tensile moduli of the nanocellulose-reinforced epoxy composites were higher than neat PLA and GF/PP. However, when the use phase and the end-of-life of nanocellulose-reinforced epoxy composites were considered, the “green credentials” of nanocellulose-reinforced epoxy composites were comparable to that of neat PLA and GF/PP composites. Our life cycle scenario analysis showed that the cradle-to-grave GWP and ADf of BC- and NFC-reinforced epoxy composites could be lower than neat PLA when the composites contains more than 60 vol.-% nanocellulose. Our LCA model suggests that nanocellulose-reinforced epoxy composites with high nanocellulose loading is desired to produce materials with “greener credentials” than the best performing commercially available bio-derived polymer

The fluidization behaviour of ignimbrite at high temperature and with mechanical agitation

Experiments were carried out to study the fluidization behaviour of ignimbrite at high temperature and while being mechanically agitated. Geldart group C behaviour occurs up to 565 degreesC when the material is subjected to increasing gas flow ( without agitation) from the loosely packed state. In contrast, even gentle mechanical agitation inhibits channelling and results in group-A type behaviour with homogeneous (non-bubbling) expansions of up to 30 - 40%. Bed collapse tests exhibit group-C behaviour at room temperature, group-A behaviour at 200 - 565 degreesC, and transitional behaviour at 55 degreesC. Both elevated temperature and mechanical agitation greatly increase the fluidizability of ignimbrite. It is inferred that a combination of high temperature and shear during transport will promote Geldart group A behaviour in pyroclastic flows

Life cycle assessment of integrated waste management systems for alternative legacy scenarios of the London Olympic Park.

This paper presents the results of the life cycle assessment (LCA) of 10 integrated waste management systems (IWMSs) for 3 potential post-event site design scenarios of the London Olympic Park. The aim of the LCA study is to evaluate direct and indirect emissions resulting from various treatment options of municipal solid waste (MSW) annually generated on site together with avoided emissions resulting from energy, materials and nutrients recovery. IWMSs are modelled using GaBi v6.0 Product Sustainability software and results are presented based on the CML (v.Nov-10) characterisation method. The results show that IWMSs with advanced thermal treatment (ATT) and incineration with energy recovery have the lowest Global Warming Potential (GWP) than IWMSs where landfill is the primary waste treatment process. This is due to higher direct emissions and lower avoided emissions from the landfill process compared to the emissions from the thermal treatment processes. LCA results demonstrate that significant environmental savings are achieved through substitution of virgin materials with recycled ones. The results of the sensitivity analysis carried out for IWMS 1 shows that increasing recycling rate by 5%, 10% and 15% compared to the baseline scenario can reduce GWP by 8%, 17% and 25% respectively. Sensitivity analysis also shows how changes in waste composition affect the overall result of the system. The outcomes of such assessments provide decision-makers with fundamental information regarding the environmental impacts of different waste treatment options necessary for sustainable waste management planning

New quadrature-based moment method for the mixing of inert polydisperse fluidized powders in commercial CFD codes

To describe the behavior of polydisperse multiphase systems in an Eulerian framework, we solved the population balance equation (PBE), letting it account only for particle size dependencies. To integrate the PBE within a commercial computational fluid dynamics code, we formulated and implemented a novel version of the quadrature method of moments (QMOM). This no longer assumes that the particles move with the same velocity, allowing the latter to be size-dependent. To verify and test the model, we simulated the mixing of inert polydisperse fluidized suspensions initially segregated, validating the results experimentally. Because the accuracy of QMOM increases with the number of moments tracked, we ran three classes of simulations, preserving the first four, six, and eight integer moments of the particle density function. We found that in some cases the numerics corrupts the higher-order moments and a corrective algorithm, designed to restore the validity of the moment set, has to be implemented

Life cycle assessment of shale gas in the UK

The remarkable US growth of shale gas and the associated decrease in the US natural gas prices has catalysed an increasing interest of shale gas resource exploration in other areas of the world. Commercial drilling operations have not yet commenced, but exploration is taking place in some European countries, including the UK. Major environmental concerns, regarding the amount and the handling method of the emissions associated with hydraulic fracturing, the disposal of waste water and the low well productivity, have pushed some countries to ban exploration and trials. We contextualized the shale gas extraction to the UK condition where the estimate of recoverable gas has made the debate on shale gas highly interesting. We used the methodology of Life Cycle Assessment (LCA) and estimated the environmental burden of shale gas production, processing and distribution at low pressure to the consumer. In this paper we have reported the detailed hot spot analysis of the impact of shale gas on the watersheds

Defining a quantitative framework for evaluation and optimisation of the environmental impacts of mega-event projects

This paper presents a novel quantitative methodology for the evaluation and optimisation of the environmental impacts of the whole life cycle of a mega-event project: construction and staging the event and post-event site redevelopment and operation. Within the proposed framework, a mathematical model has been developed that takes into account greenhouse gas (GHG) emissions resulting from use of transportation fuel, energy, water and construction materials used at all stages of the mega-event project. The model is applied to a case study - the London Olympic Park. Three potential post-event site design scenarios of the Park have been developed: Business as Usual (BAU), Commercial World (CW) and High Rise High Density (HRHD). A quantitative summary of results demonstrates that the highest GHG emissions associated with the actual event are almost negligible compared to those associated with the legacy phase. The highest share of emissions in the legacy phase is attributed to embodied emissions from construction materials (almost 50% for the BAU and HRHD scenarios) and emissions resulting from the transportation of residents, visitors and employees to/from the site (almost 60% for the CW scenario). The BAU scenario is the one with the lowest GHG emissions compared to the other scenarios. The results also demonstrate how post-event site design scenarios can be optimised to minimise the GHG emissions. The overall outcomes illustrate how the proposed framework can be used to support decision making process for mega-event projects planning

The environmental impacts and the carbon intensity of geothermal energy: A case study on the Hellisheiði plant

Geothermal energy, alongside other low-carbon and renewable energies, is set to play a key role in decarbonising the power generation industry to meet the Paris Agreement goal. Thus far the majority of Life Cycle Assessment (LCA) studies focused on enhanced geothermal plants. However, conventional geothermal plants that harness hydrothermal reservoirs dominate the production of electricity from geothermal energy worldwide. This article focuses on Hellisheiði, a combined heat and power double flash geothermal plant located in Iceland, with an installed capacity of 303.3 MW of electricity and 133 MW of hot water. The study has a twofold goal: (i) identify hot spots in the life cycle and, where possible, suggest improvements, and (ii) understand the potential of geothermal energy to decarbonise the power generation industry. First, a detailed LCA study has been performed on Hellisheiði, with cradle-to-grave system boundaries and detailed site-specific data obtained from the literature. The analysis identifies consumption of diesel for drilling and use of steel for wells casing and construction of the power plant as the main hot spots. Second, carbon intensities of electricity production for various possible configurations of the Hellisheiði power plant (including single flash, and power-only production) have been compared with those of other geothermal plants and other energy sources. Different allocation procedures have been used to allocate impacts between electricity and hot water where necessary, and Monte Carlo simulations have been used to estimate uncertainties of Hellisheiði's carbon intensities. The comparison shows that the carbon intensity of Hellisheiði is in the range of 15–24 g CO2-eq./kWh, which is similar to those of binary cycle geothermal plants, solar (photovoltaic) and hydropower, lower than other geothermal technologies and fossil-based technologies, and higher than nuclear and onshore wind

Social hotspots life cycle assessment: A case study on social risks of an antimicrobial keyboard cover

This article explores the application of social life cycle assessment (S-LCA) to products or technologies in their earliest developing phase. Indeed, it would be beneficial to have an overview of the social risks generated by novel products and understand what their potential supply chain would be like. To this end, this study presents a S-LCA study for identifying hotspots linked to a novel product: an antimicrobial keyboard cover integrating gold nanoparticles. Firstly, countries which could supply Europe with the input materials required in the system were identified, then by following the S-LCA methodology working hours and working functional hours were estimated. Ultimately, social risks were calculated by combining working functional hours with social risk levels and weights, concerning the relative importance of each category and sub-category. The analysis helped to determine which countries could supply the materials needed and hence become part of the potential supply chain of antimicrobial keyboard covers integrating gold nanoparticles. Furthermore, it led to the identification of main social hotspots linked to each material used. In general, results show that the stakeholders most at risk of adverse social impacts across different sectors and countries are workers. Indeed, they may be affected on both their rights and work conditions, health and safety. The process of gold mining highlights the difference in terms of social risks between more developed countries, such as Australia and Sweden, and developing countries, such as South Africa. The production of chemicals presents a homogeneity in terms of risk hours associated to the considered European countries

Data on the environmental impacts of the Hellisheiði geothermal plant and on the carbon intensity of geothermal energy and other energy technologies

This data article is related to the research article “The environmental impacts and the carbon intensity of geothermal energy: A case study on the Hellisheiði plant”. The article reports numerical values of the results of the Life Cycle Assessment (LCA) study, which are reported only graphically and in an aggregated form in the main article. Data include normalised impacts, unaggregated environmental impacts of each life-cycle phase and activity in the foreground system, and results of Monte Carlo simulations. The article also includes data on the carbon intensity of other geothermal studies and alternative energy technologies, which were used for comparison in the associated research article