Investigation of battery active nickel oxides Final report

Identification and characterization of battery active compound structures formed on nickel oxide electrode during charging and dischargin

Cosine and Sine Operators Related with Orthogonal Polynomial Sets on the Intervall [-1,1]

The quantization of phase is still an open problem. In the approach of Susskind and Glogower so called cosine and sine operators play a fundamental role. Their eigenstates in the Fock representation are related with the Chebyshev polynomials of the second kind. Here we introduce more general cosine and sine operators whose eigenfunctions in the Fock basis are related in a similar way with arbitrary orthogonal polynomial sets on the intervall [-1,1]. To each polynomial set defined in terms of a weight function there corresponds a pair of cosine and sine operators. Depending on the symmetry of the weight function we distinguish generalized or extended operators. Their eigenstates are used to define cosine and sine representations and probability distributions. We consider also the inverse arccosine and arcsine operators and use their eigenstates to define cosine-phase and sine-phase distributions, respectively. Specific, numerical and graphical results are given for the classical orthogonal polynomials and for particular Fock and coherent states.Comment: 1 tex-file (24 pages), 11 figure

Investigation of battery active nickel oxides Fourth quarterly report

Electrochemical analysis of battery active sintered nickel oxides - oxidation state, stand and temperature effect, and charge retentio

Investigation of battery active nickel oxides Third quarterly report

X-ray diffraction of sintered nickel oxide charged electrode, structural effect of initial stand at various temperatures, and comparison with cobalt doped positive

A two-dimensional, two-electron model atom in a laser pulse: exact treatment, single active electron-analysis, time-dependent density functional theory, classical calculations, and non-sequential ionization

Owing to its numerical simplicity, a two-dimensional two-electron model atom, with each electron moving in one direction, is an ideal system to study non-perturbatively a fully correlated atom exposed to a laser field. Frequently made assumptions, such as the ``single active electron''- approach and calculational approximations, e.g. time dependent density functional theory or (semi-) classical techniques, can be tested. In this paper we examine the multiphoton short pulse-regime. We observe ``non-sequential'' ionization, i.e.\ double ionization at lower field strengths as expected from a sequential, single active electron-point of view. Since we find non-sequential ionization also in purely classical simulations, we are able to clarify the mechanism behind this effect in terms of single particle trajectories. PACS Number(s): 32.80.RmComment: 10 pages, 16 figures (gzipped postscript), see also http://www.physik.tu-darmstadt.de/tqe

Ejection Energy of Photoelectrons in Strong Field Ionization

We show that zero ejection energy of the photoelectrons is classically impossible for hydrogen-like ions, even when field ionization occurs adiabatically. To prove this we transform the basic equations to those describing two 2D anharmonic oscillators. The same method yields an alternative way to derive the anomalous critical field of hydrogen-like ions. The analytical results are confirmed and illustrated by numerical simulations. PACS Number: 32.80.RmComment: 7 pages, REVTeX, postscript file including the figures is available at http://www.physik.th-darmstadt.de/tqe/dieter/publist.html or via anonymous ftp from ftp://tqe.iap.physik.th-darmstadt.de/pub/dieter/publ_I_pra_pre.ps, accepted for publication in Phys. Rev.

Gene identification for the cblD defect of vitamin B12 metabolism

Background Vitamin B12 (cobalamin) is an essential cofactor in several metabolic pathways. Intracellular conversion of cobalamin to its two coenzymes, adenosylcobalamin in mitochondria and methylcobalamin in the cytoplasm, is necessary for the homeostasis of methylmalonic acid and homocysteine. Nine defects of intracellular cobalamin metabolism have been defined by means of somatic complementation analysis. One of these defects, the cblD defect, can cause isolated methylmalonic aciduria, isolated homocystinuria, or both. Affected persons present with multisystem clinical abnormalities, including developmental, hematologic, neurologic, and metabolic findings. The gene responsible for the cblD defect has not been identified. Methods We studied seven patients with the cblD defect, and skin fibroblasts from each were investigated in cell culture. Microcell-mediated chromosome transfer and refined genetic mapping were used to localize the responsible gene. This gene was transfected into cblD fibroblasts to test for the rescue of adenosylcobalamin and methylcobalamin synthesis. Results The cblD gene was localized to human chromosome 2q23.2, and a candidate gene, designated MMADHC (methylmalonic aciduria, cblD type, and homocystinuria), was identified in this region. Transfection of wild-type MMADHC rescued the cellular phenotype, and the functional importance of mutant alleles was shown by means of transfection with mutant constructs. The predicted MMADHC protein has sequence homology with a bacterial ATP-binding cassette transporter and contains a putative cobalamin binding motif and a putative mitochondrial targeting sequence. Conclusions Mutations in a gene we designated MMADHC are responsible for the cblD defect in vitamin B12 metabolism. Various mutations are associated with each of the three biochemical phenotypes of the disorder

Weak-localization corrections to the conductivity of double quantum wells

The weak-localization contribution \delta\sigma(B) to the conductivity of a tunnel-coupled double-layer electron system is evaluated and its behavior in weak magnetic fields B perpendicular or parallel to the layers is examined. In a perpendicular field B, \delta \sigma(B) increases and remains dependent on tunneling as long as the magnetic field is smaller than \hbar/e D \tau_t, where D is the in-plane diffusion coefficient and \tau_t the interlayer tunneling time. If \tau_t is smaller than the inelastic scattering time, a parallel magnetic field also leads to a considerable increase of the concuctivity starting with a B**2 law and saturating at fields higher than \hbar/e Z (D \tau_t)**(1/2), where Z is the interlayer distance. In the limit of coherent tunneling, when \tau_t is comparable to elastic scattering time, \delta \sigma(B) differs from that of a single-layer system due to ensuing modifications of the diffusion coefficient. A possibility to probe the weak-localization effect in double-layer systems by the dependence of the conductivity on the gate-controlled level splitting is discussed.Comment: Text 18 pages in Latex/Revtex format, 4 Postscript figures. J. Phys.: CM,in pres

Magnetic field generation in Higgs inflation model

We study the generation of magnetic field in Higgs-inflation models where the Standard Model Higgs boson has a large coupling to the Ricci scalar. We couple the Higgs field to the Electromagnetic fields via a non- renormalizable dimension six operator suppressed by the Planck scale in the Jordan frame. We show that during Higgs inflation magnetic fields with present value $10^{-6}$ Gauss and comoving coherence length of $100 kpc$ can be generated in the Einstein frame. The problem of large back-reaction which is generic in the usual inflation models of magneto-genesis is avoided as the back-reaction is suppressed by the large Higgs-curvature coupling.Comment: 10 pages, RevTeX

Dynamic equation for quantum Hall bilayers with spontaneous interlayer coherence: The low-density limit

The bilayer systems exhibit the Bose-Einstein condensation of excitons that emerge due to Coulomb pairing of electrons belonging to one layer with the holes belonging to the other layer. Here we present the microscopic derivation of the dynamic equation for the condensate wave function at a low density of electron-hole ($e-h$) pairs in a strong magnetic field perpendicular to the layers and an electric field directed along the layers. From this equation we obtain the dispersion law for collective excitations of the condensate and calculate the electric charge of the vortex in the exciton condensate. The critical interlayer spacing, the excess of which leads to a collapse of the superfluid state, is estimated. In bilayer systems with curved conducting layers, the effective mass of the $e-h$ pair becomes the function of the $e-h$ pair coordinates, the regions arise, where the energy of the $e-h$ pair is lowered (exciton traps), and lastly $e-h$ pairs can gain the polarization in the basal plane. This polarization leads to the appearance of quantized vortices even at zero temperature.Comment: 8 page