Contactless and Spatially Resolved Determination of Current−Voltage Curves in Perovskite Solar Cells via Photoluminescence

Early prediction of spatially resolved performance of perovskite solar cells (PSCs) is essential for process monitoring, control and fault diagnosis, and upscaling of this emerging technology. Herein, a fast, nonde structive, contactless imaging-based approach is developed to visualize the spatial distribution of possible light current density−voltage (pseudo-J−V) curves on finished and partly finished cells. This allows for the extraction of other critical spatially resolved properties including implied open-circuit voltage and pseudo-fill factor. The technique is applied to systematically investigate various degradation behaviors on PSCs including thermal stability, light soaking, and ambient air exposure. Finally, it is used to predict pseudo-J−V curves of various perovskite films with different compositions. These results demonstrate the significant value of this fast imaging technique for the research and development of PSCs ranging from material selection, process optimization, to degradation study.This work was supported by the Australian Renewable Energy Agency (ARENA) through research grants RND017 and 2020/RND001. The authors acknowledge the support from the Australian National Fabrication Facility (ANFF), ACT Node, The Australian National University. H.T.N. acknowledges fellowship support from the Australian Centre for Advanced Photovoltaics (ACAP)