13,646 research outputs found
Aqueous Phase C-H Bond Oxidation Reaction of Arylalkanes Catalyzed by a Water-Soluble Cationic Ru(III) Complex [(pymox-Me\u3csub\u3e2\u3c/sub\u3e)\u3csub\u3e2\u3c/sub\u3eRuCl\u3csub\u3e2\u3c/sub\u3e]\u3csup\u3e+\u3c/sup\u3eBF\u3csub\u3e4\u3c/sub\u3e\u3csup\u3e-\u3c/sup\u3e
The cationic complex [(pymox-Me2)RuCl2]+BF4− was found to be a highly effective catalyst for the C−H bond oxidation reaction of arylalkanes in water. For example, the treatment of ethylbenzene (1.0 mmol) with t-BuOOH (3.0 mmol) and 1.0 mol % of the Ru catalyst in water (3 mL) cleanly produced PhCOCH3 at room temperature. Both a large kinetic isotope effect (kH/kD = 14) and a relatively large Hammett value (ρ = −1.1) suggest a solvent-caged oxygen rebounding mechanism via a Ru(IV)-oxo intermediate species
Event-triggered proportional-derivative control for nonlinear network systems with a novel event-triggering scheme: Differential of triggered state consideration
This article proposes event-triggered proportional-derivative control for a class of nonlinear network control systems. For derivative action of the proposed proportional-derivative control, a novel event-triggering scheme is devised together with the control that considers a differential of a triggered state. The class of the nonlinear network systems is represented as a Lur'e system to consider various nonlinear cases. Time varying transmission delay is considered which can be defined by lower and upper delay bounds. The proposed proportional-derivative control is designed by Lyapunov-Krasovskii stability analysis, and the design condition is presented by linear matrix inequalities. The proposed event-triggered proportional-derivative control and event-triggering condition are verified with numerical simulation. ? 2017 The Author(s).111Ysciescopu
A data-driven analysis on the impact of high-speed rails on land prices in Taiwan
10.3390/APP10103357Applied Sciences (Switzerland)1010335
Orientational Melting in Carbon Nanotube Ropes
Using Monte Carlo simulations, we investigate the possibility of an
orientational melting transition within a "rope" of (10,10) carbon nanotubes.
When twisting nanotubes bundle up during the synthesis, orientational
dislocations or twistons arise from the competition between the anisotropic
inter-tube interactions, which tend to align neighboring tubes, and the torsion
rigidity that tends to keep individual tubes straight. We map the energetics of
a rope containing twistons onto a lattice gas model and find that the onset of
a free "diffusion" of twistons, corresponding to orientational melting, occurs
at T_OM > 160 K.Comment: 4 page LaTeX file with 3 figures (10 PostScript files
SPH Simulations of Galactic Gaseous Disk with Bar: Distribution and Kinematic Structure of Molecular Clouds toward the Galactic Center
We have performed Smoothed Particle Hydrodynamic (SPH) simulations to study
the response of molecular clouds in the Galactic disk to a rotating bar and
their subsequent evolution in the Galactic Center (GC) region. The Galactic
potential in our models is contributed by three axisymmetric components
(massive halo, exponential disk, compact bulge) and a non-axisymmetric bar.
These components are assumed to be invariant in time in the frame corotating
with the bar. Some noticeable features such as an elliptical outer ring, spiral
arms, a gas-depletion region, and a central concentration have been developed
due to the influence of the bar. The rotating bar induces non-circular motions
of the SPH particles, but hydrodynamic collisions tend to suppress the random
components of the velocity. The velocity field of the SPH particles is
consistent with the kinematics of molecular clouds observed in HCN (1-0)
transition; these clouds are thought to be very dense clouds. However, the l-v
diagram of the clouds traced by CO is quite different from that of our SPH
simulation, being more similar to that obtained from simulations using
collisionless particles. The diagram of a mixture of collisional and
collisionless particles gives better reproduction of the kinematic structures
of the GC clouds observed in the CO line. The fact that the kinematics of HCN
clouds can be reproduced by the SPH particles suggests that the dense clouds in
the GC are formed via cloud collisions induced by rotating bar.Comment: 31 pages, 10 pigures, accepted for publication in Ap
Condensation phase transitions of symmetric conserved-mass aggregation model on complex networks
We investigate condensation phase transitions of symmetric conserved-mass
aggregation (SCA) model on random networks (RNs) and scale-free networks (SFNs)
with degree distribution . In SCA model, masses diffuse
with unite rate, and unit mass chips off from mass with rate . The
dynamics conserves total mass density . In the steady state, on RNs and
SFNs with for , we numerically show that SCA
model undergoes the same type condensation transitions as those on regular
lattices. However the critical line depends on network
structures. On SFNs with , the fluid phase of exponential mass
distribution completely disappears and no phase transitions occurs. Instead,
the condensation with exponentially decaying background mass distribution
always takes place for any non-zero density. For the existence of the condensed
phase for at the zero density limit, we investigate one
lamb-lion problem on RNs and SFNs. We numerically show that a lamb survives
indefinitely with finite survival probability on RNs and SFNs with ,
and dies out exponentially on SFNs with . The finite life time
of a lamb on SFNs with ensures the existence of the
condensation at the zero density limit on SFNs with at which
direct numerical simulations are practically impossible. At ,
we numerically confirm that complete condensation takes place for any on RNs. Together with the recent study on SFNs, the complete condensation
always occurs on both RNs and SFNs in zero range process with constant hopping
rate.Comment: 6 pages, 6 figure
3D-Printed Microfluidic Device for the Detection of Pathogenic Bacteria Using Size-based Separation in Helical Channel with Trapezoid Cross-Section
A facile method has been developed to detect pathogenic bacteria using magnetic nanoparticle clusters (MNCs) and a 3D-printed helical microchannel. Antibody-functionalized MNCs were used to capture E. coli (EC) bacteria in milk, and the free MNCs and MNC-EC complexes were separated from the milk using a permanent magnet. The free MNCs and MNC-EC complexes were dispersed in a buffer solution, then the solution was injected into a helical microchannel device with or without a sheath flow. The MNC-EC complexes were separated from the free MNCs via the Dean drag force and lift force, and the separation was facilitated in the presence of a sheath flow. The concentration of the E. coli bacteria was determined using a light absorption spectrometer, and the limit of detection was found to be 10 cfu/mL in buffer solution and 100 cfu/mL in milk.open119188sciescopu
Biodegradable Nitrogen-Doped Carbon Nanodots for Non-Invasive Photoacoustic Imaging and Photothermal Therapy
Multifunctional nanoparticles have been widely investigated for biomedical applications, such as imaging, therapy, and drug delivery. Especially, photoactive nanoparticles have received great attention as theranostic agents because of their heat-generating abilities after exposure to laser irradiation. However, photostability and safety issues have been the technical hurdles for further clinical applications. Here, we designed nitrogen (N)-doped carbon nanodots (N-CNDs) that have strong absorption in the near-infrared region, high photostability, and excellent biodegradability. Optimized N-CNDs can be utilized not only as a new photoacoustic (PA) imaging agent but also as a superior photothermal therapy (PTT) agent in vivo because of their strong optical absorption at a specific wavelength. We used N-CNDs to perform in vivo/ex vivo noninvasive PA imaging of sentinel lymph nodes via local delivery and performed PTT for cancer ablation therapy. Finally, biodegradation and renal clearance were confirmed by performing whole-body PA monitoring and a degradation test
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